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Reactions of 4-diphenylphosphino benzoic acid with organotin oxides and -oxy-hydroxide

  • Ramakirushnan Suriya Narayanan
  • Pakkirisamy Thilagar
  • Joydev Acharya
  • Pawan Kumar
  • Doddapuneni Krishna Rao
  • Vadapalli Chandrasekhar
  • Anukul Jana
Regular Article

Abstract

The reactions of p-diphenylphosphinobenzoic acid (LCOOH) with various organotin precursors have been carried out. Accordingly, the reaction of \([n\hbox {-BuSn(O)}(\hbox {OH}]_{\mathrm{n}}\) with LCOOH afforded the hexameric compound, \([n\hbox {-BuSn(O)O}_{2}\hbox {C}\)\(\hbox {C}_{6}\hbox {H}_{4}\)\(p\hbox {-PPh}_{2}]_{6}\) (1). On the other hand, the reaction of LCOOH with \([n\hbox {-Bu}_{2}\hbox {SnO}]_{\mathrm{n}}\) gave the tetrameric compound \([\{{n}\hbox {-Bu}_{2}\hbox {SnO}_{2}\hbox {C}\)\(\hbox {C}_{6}\hbox {H}_{4}\)\(p\hbox {-PPh}_{2}\}_{2}\hbox {O}]_{2}\) (2). The 1-D coordination polymers \([\hbox {R}_{3}\hbox {SnO}_{2}\hbox {C}\)\(\hbox {C}_{6}\hbox {H}_{4}\)\(p\hbox {-}\hbox {P(O)Ph}_{2}]_{\mathrm{n}}\), \([\hbox {R} = n\hbox {-Bu}\) (3), \(\hbox {R} = \hbox {Ph}\) (4)] were prepared in the reaction of \([n\hbox {-Bu}_{3}\hbox {Sn}]_{2}\hbox {O}\) or \([\hbox {Ph}_{3}\hbox {Sn}]_{2}\hbox {O}\) with LCOOH. The compounds 14 were structurally characterized by multinuclear NMR spectroscopic and single crystal X-ray diffraction studies.

Graphical Abstract

SYNOPSIS The reactions of p-diphenylphosphinobenzoic acid with various organotin precursors have been shown to afford hexameric compound 1, tetrameric compound 2 and 1-D polymeric compounds 3 and 4. The compounds 14 were structurally characterized by multinuclear NMR spectroscopic and single crystal X-ray diffraction methods.

Keywords

Organostannoxane multisite coordination ligand organotin compounds 1-D coordination polymer 

Notes

Acknowledgements

This work is supported by the Tata Institute of Fundamental Research Hyderabad, Hyderabad, Telangana, India. VC is thankful to the Department of Science and Technology for a J. C. Bose fellowship.

Supplementary material

12039_2018_1493_MOESM1_ESM.pdf (199 kb)
Supplementary material 1 (pdf 199 KB)

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Copyright information

© Indian Academy of Sciences 2018

Authors and Affiliations

  1. 1.Tata Institute of Fundamental Research Hyderabad, GopanpallyHyderabadIndia
  2. 2.Department of Inorganic and Physical ChemistryIndian Institute of ScienceBangaloreIndia
  3. 3.Department of ChemistryIndian Institute of Technology KanpurKanpurIndia

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