Abstract
This work reports the preparation of the mononuclear derivative [Pd(C6H4CH2NH2) L](ClO4) (L = dppp). The centrosymmetric mononuclear palladium complex obtained by the reaction of palladium(II) acetate with benzylamine in toluene produced the acetate cyclopalladated dimer of benzylamine. Metathesis reaction of this acetate-bridged cyclopalladated complex with NaCl in water and acetone gave N,C-orthopalladated [Pd(C6H4CH2NH2)(µ-Cl)]2 complex, which reacts with NaClO4/dppp to give the mononuclear derivative. The ortho-palladation complex was characterized by various spectroscopic techniques such as elemental analysis, IR, 1H, 31P, and 13C NMR. The structures of N,C-metalated complex 3 were determined by X-ray diffraction study.
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The authors are grateful to University of Ilam and Ministry of Science, Research and Technology of Iran for funding.
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Appendix A: supplementary data
Appendix A: supplementary data
CCDC 922381 contain the supplementary crystallographic data for the compounds 3. These data can be obtained free of charge via http://www.ccdc.cam.ac.uk/conts/retrieving.html, or from the Cambridge Crystallographic Data Centre, 12 Union Road, Cambridge CB2 1EZ, UK; fax: (+44) 1223-336-033; or e-mail: deposit@ccdc.cam.ac.uk.
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Naghipour, A., Sabounchei, S.J., Sayadi, M. et al. [Benzylamine-K2-C,N]1,2-Bis (Diphenylphosphino)-Propane-k2-P,P] Palladium}Perchlorate, Mononuclear Complex of Ortho-Palladated Derived from Benzylamine. Iran J Sci Technol Trans Sci 41, 129–133 (2017). https://doi.org/10.1007/s40995-017-0210-4
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DOI: https://doi.org/10.1007/s40995-017-0210-4