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Synthesis and characterization of nanocomposite MCM-48-PEHA-DEA and its application as CO2 adsorbent

  • Separation Technology, Thermodynamics
  • Published:
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Abstract

Three nanocomposites containing MCM-48-35PEHA-15DEA (35 and 15 as weight percent of amine addition), MCM-48-30PEHA-20DEA and MCM-48-25PEHA-25DEA of mesoporous silica MCM-48 modified by the mixture of pentaethylenehexamine (PEHA) and diethanolamine (DEA) have been synthesized and used to study the adsorption of carbon dioxide (CO2). They are characterized by low angle x-ray diffraction (XRD), Fourier transform infrared (FT-IR) and Brunauer-Emmet-Teller (BET) analysis. MCM-48-35PEHA-15DEA (as optimized adsorbent) shows CO2 adsorption capacity of 0.51 (m·mol CO2/g-adsorbent) at 1 bar and 298 K, much higher than CO2 adsorption capacity on polyethyleneimine, pyrrolidinepropyl and polymerized aminopropyl loaded MCM-48.

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References

  1. Intergovernmental Panel on Climate Change (IPCC), Climate Change 1995: The Science of Climate Change, Cambridge University Press (1996).

  2. E. Bryant, Climate Process and Change, Cambridge University Press, Cambridge, UK (1997).

    Book  Google Scholar 

  3. T. Yokoyama, In Separations Technology, Queensland, Australia (2006).

  4. D. Aaron and C. Tsouris, Sep. Sci. Technol., 40, 321 (2005).

    Article  CAS  Google Scholar 

  5. E. S. Kikkinides, R. T. Yang and S. H. Cho, Ind. Eng. Chem. Res., 32, 2714 (1993).

    Article  CAS  Google Scholar 

  6. S. H. Hyun, J. K. Song, B. I. Kwak, J. H. Kim and S. A. Hong, J. Mater. Sci., 34, 309 (1999).

    Article  Google Scholar 

  7. P. J. E. Harlick and A. Sayari, Ind. Eng. Chem. Res., 46, 446 (2007).

    Article  CAS  Google Scholar 

  8. R. J. Hook, Ind. Eng. Chem. Res., 36, 1779 (1997).

    Article  CAS  Google Scholar 

  9. C. S. Tan and J. E. Chen, Sep. Purif. Technol., 49, 174 (2006).

    Article  CAS  Google Scholar 

  10. H.M. Krutka, S. J. Sjostrom and C. J. Bustard, Paper #08-A—Mega-AWMA., 173 (2008).

  11. K. T. Chue, J. N. Kim, Y. J. Yoo, S.H. Cho and R. T. Yang, Ind. Eng. Chem. Res., 34, 591 (1995).

    Article  CAS  Google Scholar 

  12. M. Katoh, T. Yoshikawa, T. Tomonari, K. Katayama and T. Tomida, J. Colloid Interface Sci., 226, 145 (2000).

    Article  CAS  Google Scholar 

  13. T. Mimura, H. Simayoshi, T. Suda, M. Iijima and S. Mituoka, Energy Convers. Manage., Suppl. S., 57, 38 (1997).

    Google Scholar 

  14. C. L. Leci, Energy Convers. Manage., Suppl. S., 57, 38 (1997).

    Google Scholar 

  15. J. E. Critchfield, W.Y. Su, T. J. Kenney and P. E. Holub, US Patent, 5,861,051 (1996).

  16. M. Anbia and S. A. Hariri, Desalination, 261, 61 (2010).

    Article  CAS  Google Scholar 

  17. M. Anbia and M. Lashgari, Chem. Eng. J., 150, 555 (2009).

    Article  CAS  Google Scholar 

  18. M. Anbia and S. E. Moradi, Appl. Surf. Sci., 255, 5041 (2009).

    Article  CAS  Google Scholar 

  19. M. Anbia and S. E. Moradi, Chem. Eng. J., 148, 452 (2009).

    Article  CAS  Google Scholar 

  20. M. Anbia, N. Mohammadi and K. Mohammadi, J. Hazard. Mater., 176, 965 (2010).

    Article  CAS  Google Scholar 

  21. S. C. Shen, X. Chen and S. Kawi, Langmuir., 20, 9130 (2004).

    Article  CAS  Google Scholar 

  22. A. Macario, A. Katovic, G. Giordano, F. Iucolano and D. Caputo, Micropor. Mesopor. Mater., 81, 139 (2005).

    Article  CAS  Google Scholar 

  23. A.L. Chaffee, S.W. Delaney and G. Knowles, Abstr. Pap. 223 rd ACS Nat., Meeting P (2002).

  24. H. Y. Huang, R. T. Yang, D. Chinn and C. L. Munson, Ind. Eng. Chem. Res., 42, 2427 (2003).

    Article  CAS  Google Scholar 

  25. A. C. C. Chang, S. S. C. Chuang, M. Gray and Y. Soong, Energy Fuels, 17, 468 (2003).

    Article  CAS  Google Scholar 

  26. S. Kim, J. Ida, V.V. Guliants and Y. S. Lin, J. Phys. Chem., B 109, 6287 (2005).

    Article  CAS  Google Scholar 

  27. M. Anbia and N. Mohammadi, J. Porous. Mater., 18, 13 (2011).

    Article  CAS  Google Scholar 

  28. V. Alfredsson and M.W. Anderson, Chem. Mater., 8, 1141 (1996).

    Article  CAS  Google Scholar 

  29. L. Mercier and T. Pinnavaia, J. Environ. Sci. Technol., 32, 2749 (1998).

    Article  CAS  Google Scholar 

  30. H. Yoshitake, T. Yokoi and T. Tatsumi, Chem. Mater., 14, 4603 (2002).

    Article  CAS  Google Scholar 

  31. X. Xu, C. Song, J. M. Anderson, G. B. Miller and A.W. Scaroni, Energy Fuels, 16, 1463 (2002).

    Article  CAS  Google Scholar 

  32. C. P. Jaroniec, M. Kruk, M. Jaroniec and A. Sayari, J. Phys. Chem., B, 102, 5503 (1998).

    Article  CAS  Google Scholar 

  33. R. A. Pierotti, J. Rouquerol and T. Siemieniewska, J. Pure Appl. Chem., 57, 603 (1985).

    Article  Google Scholar 

  34. O. Leal, C. Bolivar, C. Ovalles, J. J. Garcia and Y. Espidel, Inorg. Chim. Acta, 240, 183 (1995).

    Article  CAS  Google Scholar 

  35. S. Satyapal, T. Filburn and J. Trela, Energy Fuels, 15, 250 (2001).

    Article  CAS  Google Scholar 

  36. M.B. Yue, L. B. Sun, Y. Cao, Z. J. Wang, Y. Wang, Q. Yu and J. H. Zhu, Micropor. Mesopor. Mater., 114, 74 (2008).

    Article  CAS  Google Scholar 

  37. S. Kim, J. Ida, V.V. Guliants and J.Y. S. Lin, J. Phys. Chem. B., 109, 6287 (2005).

    Article  CAS  Google Scholar 

  38. W. J. Son, G. S. Choi and W. S. Ahn, Micropor. Mesopor. Mater., 113, 31 (2008).

    Article  CAS  Google Scholar 

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Authors and Affiliations

  1. Research Laboratory of Nanoporous Materials, Faculty of Chemistry, Iran University of Science and Technology, Farjam Street, Narmak, Tehran, 16846, Iran

    Mansoor Anbia, Vahid Hoseini & Sakineh Mandegarzad

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  1. Mansoor Anbia
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  2. Vahid Hoseini
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  3. Sakineh Mandegarzad
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Correspondence to Mansoor Anbia.

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Anbia, M., Hoseini, V. & Mandegarzad, S. Synthesis and characterization of nanocomposite MCM-48-PEHA-DEA and its application as CO2 adsorbent. Korean J. Chem. Eng. 29, 1776–1781 (2012). https://doi.org/10.1007/s11814-012-0090-4

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  • DOI: https://doi.org/10.1007/s11814-012-0090-4

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