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Dispersion polymerization of N-vinyl-2-pyrrolydone using fluorine-based surfactants in supercritical carbon dioxide

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Abstract

We carried out a dispersion polymerization of N-vinyl-2-pyrrolydone using fluorine-based surfactants, which included poly(heptadecafluorodecyl acrylate) (PHDFDA) or poly(heptadecafluorodecyl methacrylate) (PHDFDMA) in supercritical carbon dioxide (scCO2). An FE-SEM and an image analyzer were used to characterize particle morphology, size, and size distribution of the resulting polymer taking into account effect of the surfactant, initiator, and monomer concentrations.

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Authors and Affiliations

  1. School of Chemical and Biological Engineering and Institute of Chemical Processes, Seoul National University, 559 Gwanangno, Gwanak-gu, Seoul, 151-744, Korea

    Jungin Shin & Hwayong Kim

  2. R&D Institute, Miwon Specialty Chemical Co., Ltd., 405-3, Moknae-dong, Ansan-si, Gyeonggi, 425-100, Korea

    Won Bae

Authors
  1. Jungin Shin
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  2. Won Bae
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  3. Hwayong Kim
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Correspondence to Hwayong Kim.

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Shin, J., Bae, W. & Kim, H. Dispersion polymerization of N-vinyl-2-pyrrolydone using fluorine-based surfactants in supercritical carbon dioxide. Korean J. Chem. Eng. 27, 1021–1027 (2010). https://doi.org/10.1007/s11814-010-0137-3

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  • DOI: https://doi.org/10.1007/s11814-010-0137-3

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