The effects of the structure of the macrocyclic ligand and nature of the lanthanide on the spectral and luminescence properties of Nd(III), Yb(III), and Lu(III) complexes with substituted porphyrins and corroles were examined. These complexes display both lanthanide 4f emission and ligand fluorescence despite the presence of paramagnetic ions.
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This work was carried out with the financial support of the National Academy of Sciences of Ukraine (Project No. 0114U001963). The authors express their gratitude to the project leader, Prof. G. L. Kamalov, for support and assistance in carrying out this study and preparing this article.
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Translated from Teoreticheskaya i Éksperimental’naya Khimiya, Vol. 51, No. 4, pp. 219-224, July-August, 2015.
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Semenishyn, N.N., Smola, S.S., Efryushina, N.P. et al. Spectral and Luminescence Properties of Lanthanide(III) Complexes with Porphyrins and Corroles with Varied Structure. Theor Exp Chem 51, 224–229 (2015). https://doi.org/10.1007/s11237-015-9420-z
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DOI: https://doi.org/10.1007/s11237-015-9420-z