Abstract
An efficient mediated electrosynthesis of the spherical (85 nm) nanocomposite material Pd@p(MVCA8+-co-St) was carried out in an aqueous medium. Ultrasmall palladium nanoparticles (3—8 nm) are stabilized in nanocapsules of water-soluble nanoparticles of the copolymer p(MVCA8+-co-St) consisting of tetraviologen calix[4]resorcinol (MVCA8+) with styrene (St). The role of the mediator is played by viologen units of a polymer nanoparticle at potentials of the MV2+/MV∙+ redox couple. The high catalytic activity of the nanocomposite material in the reduction of nitrophenol with sodium borohydride is shown.
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Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 1, pp. 0125—0132, January, 2016.
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Yanilkin, V.V., Nastapova, N.V., Sultanova, E.D. et al. Electrochemical synthesis of nanocomposite of palladium nanoparticles with polymer viologen-containing nanocapsule. Russ Chem Bull 65, 125–132 (2016). https://doi.org/10.1007/s11172-016-1274-6
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DOI: https://doi.org/10.1007/s11172-016-1274-6