Skip to main content
Log in

Sonication-assisted deposition–precipitation synthesis of graphitic C3N4/BiOCl heterostructured photocatalysts with enhanced rhodamine B photodegradation activity

  • Published:
Journal of Materials Science: Materials in Electronics Aims and scope Submit manuscript

Abstract

Novel two-dimensional graphitic carbon nitride (g-C3N4)/BiOCl nanosheets with excellent photodegradation activity towards rhodamine B (RhB) under visible light irradiation have been successfully synthesized by a sonication-assisted deposition–precipitation route. The composite nanosheets exhibited good dispersity and abundant contact interfaces, which led to the formation of p–n heterojunctions. Hybridization of g-C3N4 in the composites resulted in an extended absorption range and inhibited the recombination of the photoinduced charge carriers. Therefore, the two-dimensional heterostructure of the present compounds contributed to enhance their photocatalytic performances. In addition, the indirect photosensitization effect of RhB also influenced the photodegradation activity of BiOCl.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8
Fig. 9
Fig. 10

Similar content being viewed by others

References

  1. A. Fujishima, K. Honda, Nature 238, 37 (1972)

    Article  Google Scholar 

  2. X. Bai, L. Wang, R. Zong, Y. Zhu, J. Phys. Chem. C 117, 9952 (2013)

    Article  Google Scholar 

  3. S.Q. Yan, C.G. Long, J. Mater. Sci. 27, 12079 (2016)

    Google Scholar 

  4. C. Yang, G. Gao, Z. Guo, L. Song, J. Chi, S. Gan, Appl. Surf. Sci. 400, 365 (2017)

    Article  Google Scholar 

  5. Z. Ni, Y. Sun, Y. Zhang, F. Dong, Appl. Surf. Sci 365, 314 (2016)

    Article  Google Scholar 

  6. Y. Zhang, Y. Zhang, B. Fu, M. Hong, M. Xiang, Z. Liu, H. Liu, S. Liu, J. Mater. Sci. 26, 3179 (2015)

    Google Scholar 

  7. D. Wang, J. Zhang, L. Guo, X. Dong, H. Shen, F. Fu, Mater. Res. Bull. 83, 387 (2016)

    Article  Google Scholar 

  8. X. Zhang, S. Yu, Y. Liu, Q. Zhang, Y. Zhou, Appl. Surf. Sci. 396, 652 (2017)

    Article  Google Scholar 

  9. Q. Xing, Z. Han, S. Zhao, J. Mater. Sci. 28, 295 (2017)

    Google Scholar 

  10. K.T. Liu, J. Li, J.B. Xu, F.L. Xu, L. Wang, L. Bian, J. Mater. Sci. 28 5609 (2017)

    Google Scholar 

  11. X. Meng, Z. Zhang, Appl. Surf. Sci. 392, 169 (2017)

    Article  Google Scholar 

  12. S. Devesa, M.P. Graça, L.C. Costa, Mater. Res. Bull. 78, 128 (2016)

    Article  Google Scholar 

  13. J. Li, J. Mater. Sci. 27, 9798 (2016)

    Google Scholar 

  14. L. Song, Y. Pang, Y. Zheng, C. Chen, L. Ge, J. Alloys Compd. 710, 375 (2017)

    Article  Google Scholar 

  15. H. Ma, M. Zhao, Y. Fu, C. Ma, X. Dong, X. Zhang, J. Mater. Sci. 27, 4598 (2016)

    Google Scholar 

  16. C. Liu, B. Chai, J. Mater. Sci. 26, 2296 (2015)

    Google Scholar 

  17. N. Liang, J. Zai, M. Xu, Q. Zhu, X. Wei, X. Qian, J. Mater. Chem. 2, 4208 (2014)

    Article  Google Scholar 

  18. H. Cheng, B. Huang, Y. Liu, Z. Wang, X. Qin, X. Zhang, Y. Dai, Chem. Commun. 48, 9729 (2012)

    Article  Google Scholar 

  19. G. Liu, L. Wang, H.G. Yang, H.M. Cheng, G.Q. Lu, J. Mater. Chem. 20, 831 (2010)

    Article  Google Scholar 

  20. F. Duo, Y. Wang, X. Mao, X. Zhang, Y. Wang, C. Fan, Appl. Surf. Sci. 340, 35 (2015)

    Article  Google Scholar 

  21. G. Zhu, M. Hojamberdiev, K.I. Katsumata, N. Matsushita, K. Okada, P. Liu, J. Zhou, Y. Liu, Adv. Powder Technol. 25, 1292 (2014)

    Article  Google Scholar 

  22. C. Cao, L. Xiao, C. Chen, Q. Cao, Appl. Surf. Sci. 357, 1171 (2015)

    Article  Google Scholar 

  23. C. Tan, G. Zhu, M. Hojamberdiev, K. Okada, J. Liang, X. Luo, P. Liu, Y. Liu, Appl. Catal. B 152–153, 425 (2014)

    Article  Google Scholar 

  24. Y. Chen, G. Zhu, Y. Liu, J. Gao, C. Wang, R. Zhu, P. Liu, J. Mater. Sci. 28, 2859 (2017)

    Google Scholar 

  25. S. Shi, M.A. Gondal, A.A. Al-Saadi, R. Fajgar, J. Kupcik, X. Chang, K. Shen, Q. Xu, Z.S. Seddigi, J. Colloid Interf. Sci. 416, 212 (2014)

    Article  Google Scholar 

  26. F. Chang, Y. Xie, J. Zhang, J. Chen, C. Li, J. Wang, J. Luo, B. Deng, X. Hu, RSC Adv. 4, 28519 (2014)

    Article  Google Scholar 

  27. Q. Li, X. Zhao, J. Yang, C.J. Jia, Z. Jin, W. Fan, Nanoscale 7, 18971 (2015)

    Article  Google Scholar 

  28. Y. Yang, F. Zhou, S. Zhan, Y. Liu, Y. Yin, J. Inorg. Organomet. Polym Mater. 26, 91 (2016)

    Article  Google Scholar 

  29. X. Lu, K. Xu, P. Chen, K. Jia, S. Liu, C. Wu, J. Mater. Chem. A 2, 18924 (2014)

    Article  Google Scholar 

  30. J. Jiang, K. Zhao, X. Xiao, L. Zhang, J. Am. Chem. Soc. 134, 4473 (2012)

    Article  Google Scholar 

  31. H. Cheng, B. Huang, P. Wang, Z. Wang, Z. Lou, J. Wang, X. Qin, X. Zhang, Y. Dai, Chem. Commun. 47, 7054 (2011)

    Article  Google Scholar 

  32. Z. Yang, J. Li, F. Cheng, Z. Chen, X. Dong, J. Alloys Compd. 634, 215 (2015)

    Article  Google Scholar 

  33. L. Armelao, G. Bottaro, C. Maccato, E. Tondello, Dalton Trans. 41, 5480 (2012)

    Article  Google Scholar 

  34. L. Ye, J. Liu, Z. Jiang, T. Peng, L. Zan, Appl. Catal. B 142–143, 1 (2013)

    Google Scholar 

  35. S. Wang, C. Li, T. Wang, P. Zhang, A. Li, J. Gong, J. Mater. Chem. 2, 2885 (2014)

    Article  Google Scholar 

  36. Q. Xiang, J. Yu, M. Jaroniec, J. Phys. Chem. C 115, 7355 (2011)

    Article  Google Scholar 

  37. S. Yang, Y. Gong, J. Zhang, L. Zhan, L. Ma, Z. Fang, R. Vajtai, X. Wang, P.M. Ajayan, Adv. Mater. 25, 2452 (2013)

    Article  Google Scholar 

  38. G. Zhang, J. Zhang, M. Zhang, X. Wang, J. Mater. Chem. 22, 8083 (2012)

    Article  Google Scholar 

  39. J. Liu, T. Zhang, Z. Wang, G. Dawson, W. Chen, J. Mater. Chem. 21, 14398 (2011)

    Article  Google Scholar 

  40. D. Feng, Z. Zhou, M. Bo, Polym. Degrad. Stab. 50, 65 (1995)

    Article  Google Scholar 

  41. L.F. Chen, X.D. Zhang, H.W. Liang, M. Kong, Q.F. Guan, P. Chen, Z.Y. Wu, S.H. Yu, ACS Nano 6, 7092 (2012)

    Article  Google Scholar 

  42. C. Chang, L. Zhu, S. Wang, X. Chu, L. Yue, ACS Appl. Mater. Interfaces 6, 5083 (2014)

    Article  Google Scholar 

  43. Y. Sun, W. Zhang, T. Xiong, Z. Zhao, F. Dong, R. Wang, W.K. Ho, J. Colloid Interf. Sci. 418, 317 (2014)

    Article  Google Scholar 

Download references

Acknowledgements

The research is sponsored by the Research Fund for the Doctoral Program of Higher Education of China (RFDP, No. 20110007110009) and Science Foundation of China University of Petroleum, Beijing.

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Yanjun Zheng.

Electronic supplementary material

Below is the link to the electronic supplementary material.

Supplementary material 1 (DOCX 1642 KB)

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Song, L., Zheng, Y. & Chen, C. Sonication-assisted deposition–precipitation synthesis of graphitic C3N4/BiOCl heterostructured photocatalysts with enhanced rhodamine B photodegradation activity. J Mater Sci: Mater Electron 28, 15861–15869 (2017). https://doi.org/10.1007/s10854-017-7480-7

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10854-017-7480-7

Navigation