Abstract
Novel two-dimensional graphitic carbon nitride (g-C3N4)/BiOCl nanosheets with excellent photodegradation activity towards rhodamine B (RhB) under visible light irradiation have been successfully synthesized by a sonication-assisted deposition–precipitation route. The composite nanosheets exhibited good dispersity and abundant contact interfaces, which led to the formation of p–n heterojunctions. Hybridization of g-C3N4 in the composites resulted in an extended absorption range and inhibited the recombination of the photoinduced charge carriers. Therefore, the two-dimensional heterostructure of the present compounds contributed to enhance their photocatalytic performances. In addition, the indirect photosensitization effect of RhB also influenced the photodegradation activity of BiOCl.
Similar content being viewed by others
References
A. Fujishima, K. Honda, Nature 238, 37 (1972)
X. Bai, L. Wang, R. Zong, Y. Zhu, J. Phys. Chem. C 117, 9952 (2013)
S.Q. Yan, C.G. Long, J. Mater. Sci. 27, 12079 (2016)
C. Yang, G. Gao, Z. Guo, L. Song, J. Chi, S. Gan, Appl. Surf. Sci. 400, 365 (2017)
Z. Ni, Y. Sun, Y. Zhang, F. Dong, Appl. Surf. Sci 365, 314 (2016)
Y. Zhang, Y. Zhang, B. Fu, M. Hong, M. Xiang, Z. Liu, H. Liu, S. Liu, J. Mater. Sci. 26, 3179 (2015)
D. Wang, J. Zhang, L. Guo, X. Dong, H. Shen, F. Fu, Mater. Res. Bull. 83, 387 (2016)
X. Zhang, S. Yu, Y. Liu, Q. Zhang, Y. Zhou, Appl. Surf. Sci. 396, 652 (2017)
Q. Xing, Z. Han, S. Zhao, J. Mater. Sci. 28, 295 (2017)
K.T. Liu, J. Li, J.B. Xu, F.L. Xu, L. Wang, L. Bian, J. Mater. Sci. 28 5609 (2017)
X. Meng, Z. Zhang, Appl. Surf. Sci. 392, 169 (2017)
S. Devesa, M.P. Graça, L.C. Costa, Mater. Res. Bull. 78, 128 (2016)
J. Li, J. Mater. Sci. 27, 9798 (2016)
L. Song, Y. Pang, Y. Zheng, C. Chen, L. Ge, J. Alloys Compd. 710, 375 (2017)
H. Ma, M. Zhao, Y. Fu, C. Ma, X. Dong, X. Zhang, J. Mater. Sci. 27, 4598 (2016)
C. Liu, B. Chai, J. Mater. Sci. 26, 2296 (2015)
N. Liang, J. Zai, M. Xu, Q. Zhu, X. Wei, X. Qian, J. Mater. Chem. 2, 4208 (2014)
H. Cheng, B. Huang, Y. Liu, Z. Wang, X. Qin, X. Zhang, Y. Dai, Chem. Commun. 48, 9729 (2012)
G. Liu, L. Wang, H.G. Yang, H.M. Cheng, G.Q. Lu, J. Mater. Chem. 20, 831 (2010)
F. Duo, Y. Wang, X. Mao, X. Zhang, Y. Wang, C. Fan, Appl. Surf. Sci. 340, 35 (2015)
G. Zhu, M. Hojamberdiev, K.I. Katsumata, N. Matsushita, K. Okada, P. Liu, J. Zhou, Y. Liu, Adv. Powder Technol. 25, 1292 (2014)
C. Cao, L. Xiao, C. Chen, Q. Cao, Appl. Surf. Sci. 357, 1171 (2015)
C. Tan, G. Zhu, M. Hojamberdiev, K. Okada, J. Liang, X. Luo, P. Liu, Y. Liu, Appl. Catal. B 152–153, 425 (2014)
Y. Chen, G. Zhu, Y. Liu, J. Gao, C. Wang, R. Zhu, P. Liu, J. Mater. Sci. 28, 2859 (2017)
S. Shi, M.A. Gondal, A.A. Al-Saadi, R. Fajgar, J. Kupcik, X. Chang, K. Shen, Q. Xu, Z.S. Seddigi, J. Colloid Interf. Sci. 416, 212 (2014)
F. Chang, Y. Xie, J. Zhang, J. Chen, C. Li, J. Wang, J. Luo, B. Deng, X. Hu, RSC Adv. 4, 28519 (2014)
Q. Li, X. Zhao, J. Yang, C.J. Jia, Z. Jin, W. Fan, Nanoscale 7, 18971 (2015)
Y. Yang, F. Zhou, S. Zhan, Y. Liu, Y. Yin, J. Inorg. Organomet. Polym Mater. 26, 91 (2016)
X. Lu, K. Xu, P. Chen, K. Jia, S. Liu, C. Wu, J. Mater. Chem. A 2, 18924 (2014)
J. Jiang, K. Zhao, X. Xiao, L. Zhang, J. Am. Chem. Soc. 134, 4473 (2012)
H. Cheng, B. Huang, P. Wang, Z. Wang, Z. Lou, J. Wang, X. Qin, X. Zhang, Y. Dai, Chem. Commun. 47, 7054 (2011)
Z. Yang, J. Li, F. Cheng, Z. Chen, X. Dong, J. Alloys Compd. 634, 215 (2015)
L. Armelao, G. Bottaro, C. Maccato, E. Tondello, Dalton Trans. 41, 5480 (2012)
L. Ye, J. Liu, Z. Jiang, T. Peng, L. Zan, Appl. Catal. B 142–143, 1 (2013)
S. Wang, C. Li, T. Wang, P. Zhang, A. Li, J. Gong, J. Mater. Chem. 2, 2885 (2014)
Q. Xiang, J. Yu, M. Jaroniec, J. Phys. Chem. C 115, 7355 (2011)
S. Yang, Y. Gong, J. Zhang, L. Zhan, L. Ma, Z. Fang, R. Vajtai, X. Wang, P.M. Ajayan, Adv. Mater. 25, 2452 (2013)
G. Zhang, J. Zhang, M. Zhang, X. Wang, J. Mater. Chem. 22, 8083 (2012)
J. Liu, T. Zhang, Z. Wang, G. Dawson, W. Chen, J. Mater. Chem. 21, 14398 (2011)
D. Feng, Z. Zhou, M. Bo, Polym. Degrad. Stab. 50, 65 (1995)
L.F. Chen, X.D. Zhang, H.W. Liang, M. Kong, Q.F. Guan, P. Chen, Z.Y. Wu, S.H. Yu, ACS Nano 6, 7092 (2012)
C. Chang, L. Zhu, S. Wang, X. Chu, L. Yue, ACS Appl. Mater. Interfaces 6, 5083 (2014)
Y. Sun, W. Zhang, T. Xiong, Z. Zhao, F. Dong, R. Wang, W.K. Ho, J. Colloid Interf. Sci. 418, 317 (2014)
Acknowledgements
The research is sponsored by the Research Fund for the Doctoral Program of Higher Education of China (RFDP, No. 20110007110009) and Science Foundation of China University of Petroleum, Beijing.
Author information
Authors and Affiliations
Corresponding author
Electronic supplementary material
Below is the link to the electronic supplementary material.
Rights and permissions
About this article
Cite this article
Song, L., Zheng, Y. & Chen, C. Sonication-assisted deposition–precipitation synthesis of graphitic C3N4/BiOCl heterostructured photocatalysts with enhanced rhodamine B photodegradation activity. J Mater Sci: Mater Electron 28, 15861–15869 (2017). https://doi.org/10.1007/s10854-017-7480-7
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10854-017-7480-7