Extended SO2 outgassing from the 2014–2015 Holuhraun lava flow field, Iceland
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The 2014–2015 Holuhraun eruption was the largest fissure eruption in Iceland in the last 200 years. This flood basalt eruption produced ~ 1.6 km3 of lava, forming a lava flow field covering an area of ~ 84 km2. Over the 6-month course of the eruption, ~ 11 Mt of SO2 were released from the eruptive vents as well as from the cooling lava flow field. This work examines the post-eruption SO2 flux emitted by the Holuhraun lava flow field, providing the first study of the extent and relative importance of the outgassing of a lava flow field after emplacement. We use data from a scanning differential optical absorption spectroscopy (DOAS) instrument installed at the eruption site to monitor the flux of SO2. In this study, we propose a new method to estimate the SO2 emissions from the lava flow field, based on the characteristic shape of the scanned column density distribution of a homogenous source close to the ground. Post-eruption outgassing of the lava flow field continued for at least 3 months after the end of the eruption, with SO2 flux between < 1 and 9 kg/s. The lava flow field post-eruption emissions were not a significant contributor to the total SO2 released during the eruption; however, the lava flow field was still an important polluter and caused high concentrations of SO2 at ground level after lava effusion ceased.
KeywordsSO2 Lava DOAS Post-eruption outgassing
This work provides a new approach for measuring SO2 emissions from a lava flow field after emplacement. Several studies have investigated the impacts of the Holuhraun eruption on populations and the environment (e.g. Gislason et al. 2015; Ilyinskaya et al. 2017). Establishing the potential duration and magnitude of post-eruptive SO2 outgassing will increase resilience in vulnerable communities related to the health hazards caused by SO2 after future eruptions. We additionally discuss the physical processes of cooling and fracturing (e.g. Keszthelyi and Denlinger, 1996; Kattenhorn and Schaefer, 2008; Patrick et al. 2004; Wittmann et al. 2017) that contribute to post-emplacement lava outgassing.
Volatile outgassing during and after eruption
Gases dissolved within magma are transferred to the atmosphere by degassing. The term “degassing” is used to describe the process by which a magma loses its volatiles (Burgisser and Degruyter, 2015). This includes exsolution of gas from the melt, gas segregation, and outgassing (e.g. Bottinga and Javoy, 1991; Sparks, 2003; Palma et al. 2008). Following Burgisser and Degruyter (2015) and Palma et al. (2008, 2011), we define “outgassing” only as the release of this gas to the atmosphere.
Swanson and Fabbi (1973) studied volatile loss during isothermal flow of pāhoehoe lava in lava tubes at Mauna Ulu, Kilauea (Hawaii). They observed that the majority of sulphur was released soon after eruption (60% was lost during flow over a distance of 12 km), but lava flows were observed to continue outgassing for at least 2 to 4 h after solidification (Swanson and Fabbi, 1973). In contrast, the Holuhraun lava flow field exhibits a wide range of lava morphologies, varying from pāhoehoe to ‘a’ā (Pedersen et al. 2017) and, as demonstrated by this work, continued to release sulphur volatiles for several months after emplacement.
In another study on Hawaiian flows, Bottinga and Javoy (1991) proposed that lava flows degas volatiles during transportation because their temperature decreases. The resulting supersaturation of volatiles within the lava increases, causing exsolution resulting in bubble formation. Cashman et al. (1994) proposed that volatiles were primarily released from active lava flows by the rise and escape of bubbles already contained within the lava. Sparks and Pinkerton (1978) noted that as lava is degassed, exsolution of gas results in undercooling of the lava. This leads to crystallisation and causes an increase in viscosity and yield strength (Sparks and Pinkerton, 1978). Mechanical processes during the flow of lava then cause the solidified crust to fracture (e.g. Polacci and Papale, 1997; Soule and Cashman, 2004), allowing further gas to be released.
Many studies have investigated the degassing of lava flows as they are actively flowing from the vent; however, little discussion exists about the processes of extended outgassing following lava flow emplacement. The studies of Bottinga and Javoy (1991) and Cashman et al. (1994) both examine the release of gases from flowing lava and are therefore insufficient to explain the continued flux of SO2 from the Holuhraun lava flow field for several months after its emplacement and solidification. We thus, here, consider the physical processes which occur over the longer time period that was captured by our outgassing measurements.
Volcanic SO2 monitoring
SO2 emission measurements have been fundamental to volcano monitoring since the development of the correlation spectrometer (COSPEC) in the 1970s (Moffat and Millan, 1971; Stoiber et al. 1983). Malinconico (1979) observed that increases in SO2 flux at Mt. Etna, Italy, corresponded to increases in volcanic activity, suggesting that SO2 fluctuations can be used to predict eruptions. SO2 flux has since been observed to correlate with volcanic activity (Soufrière Hills, Montserrat; Edmonds et al. 2003), magma extrusion rate (Unzen, Japan; Hirabayashi et al. 1995), seismicity during explosive activity (Merapi, Indonesia; Jousset et al., 2013), and lava lake activity (Villarrica, Chile; Palma et al. 2008, and Erebus, Antarctica; Kyle et al. 1994).
Differential optical absorption spectroscopy (DOAS) was also developed in the 1970s, as a method for measuring atmospheric gases (Platt et al. 1979). It has since been used to measure SO2 emissions of volcanoes worldwide (e.g. Edner et al. 1994; Weibring et al. 1998; McGonigle et al. 2002) and has now superseded COSPEC as the primary volcanic SO2 flux monitoring technique (Galle et al. 2002; Bobrowski et al. 2010). Measurement of volcanic plumes was further enhanced by the development of the SO2 camera (Mori and Burton, 2006; Bluth et al. 2007), providing high temporal resolution SO2 flux measurements and allowing SO2 heterogeneity within the plume to be quantified (Bluth et al. 2007). SO2 measurement techniques have been employed to determine SO2 emissions within volcanic plumes, both during eruptive episodes (e.g. Jousset et al. 2013; Gíslason et al. 2015) and during passive degassing (e.g. McGonigle et al. 2002; Sawyer et al. 2008); however, this work provides the first attempt at using DOAS to measure the SO2 released by an emplaced lava flow field.
The 2014–2015 Holuhraun eruption
The methodology used to derive the SO2 flux from the lava flow field was based on the same principle as is used in COSPEC and MobileDOAS measurements of an elevated gas plume (e.g. Stoiber et al. 1983; Galle et al. 2002). Following this approach, the vertical column density (VCD) of a gas is measured using absorption spectroscopy with the sky as the light source (Platt and Stutz, 2008). By traversing under the plume in a direction approximately perpendicular to the plume propagation, and integrating the obtained vertical column amounts, the total number of molecules in a cross section of the plume may be determined. After multiplication with the plume speed, the total gas emission is calculated (e.g. Edner et al. 1994; Galle et al., 2002; McGonigle et al. 2002; Edmonds et al. 2003; Platt et al. 2015).
In our application, a stationary scanning DOAS instrument (ScanDOAS; Galle et al. 2010) was used to determine the VCD of the low-level haze of gas emitted by the lava flow field. To make this measurement, we assume that the lava flow field produces a gas layer close to the ground with uniform thickness. We also assume that this layer has a width that is equal to the maximum width of the lava flow field, measured in a direction perpendicular to the wind direction, the “effective haze width”. Using this geometry, with a ScanDOAS instrument, we can determine the VCD at the instrument location, and using the known wind direction and shape of the lava flow field, we can derive the effective haze width. The gas flux can then be determined by multiplying the VCD at the instrument site with the effective haze width and with the wind speed.
A ScanDOAS scans the sky from horizon to horizon in a vertical plane approximately perpendicular to the plume propagation, recording radiance spectra of the diffused UV solar radiation received at each angle (Edmonds et al. 2003). The “slant column density” (SCD) of SO2 from each spectrum is calculated by differential optical absorption spectroscopy (DOAS), and the integral of column densities at all angles is then multiplied by the plume speed to obtain the flux of SO2 (e.g. Stoiber et al. 1983; Galle et al. 2002; McGonigle et al. 2002). The instrument typically makes one scan approximately every 5 min, each scan being composed of 26 spectra.
In a variation on this “flat” scan geometry, the scan is made over a conical surface with its tip at the instrument and its base through the gas source. The main advantage of this “conical” geometry is that a wider range of plume directions may be covered by a single instrument (Galle et al. 2010). In this study, a conical geometry with an opening angle of 60o was used. The instrument used in our study is a modification of the standard NOVAC-Mark I instrument (NOVAC: Network for Observation of Volcanic and Atmospheric Change; Galle et al. 2010), with a non-rotating, cylindrical external hood made of quartz, and a UV-sensitive OceanOptics MAYA Pro spectrometer (http://oceanoptics.com/wp-content/uploads/OEM-Data-Sheet-Maya2000Prov3.pdf).
Determination of the SO2 vertical column density at the measurement site
In a standard evaluation of a DOAS spectrum, the spectrum measured through the gas plume is divided by a clean air reference spectrum, typically obtained in a direction with no gas (Galle et al. 2002; Edmonds et al. 2003). In this way, spectral features related to the sky spectra as well as instrumental features are cancelled out and an absorption spectrum of the gas plume is obtained. When scanning through a low-level haze, all spectra, including the reference spectrum, will contain SO2. Our goal was therefore to determine the VCD without having access to a clean air reference spectrum. In this case, the derived slant column was the difference between the slant column of the measured spectrum and the slant column of the reference spectrum by which it was divided. For a flat geometry, this can be achieved by dividing a spectrum taken at α = 60o with a reference spectrum taken at α = 0o. The resulting SCDdiff is equal to VCD/0.5 - VCD/1, which is in turn equal to VCD, and thus provides the required VCD.
Therefore, to obtain the VCD at the instrument location, we multiply the average SCD obtained at angles α = 60° and α = 0° by 0.866. The SCD and VCD are, by convention, expressed in ppm*m (parts per million-metre). To calculate SO2 emission, these are converted to kg/m2 by applying the ideal gas law and multiplying the VCD (in ppm*m) by 2.66 × 10−6.
Field configuration and SO2 flux calculation
ScanDOAS instruments were installed at the Holuhraun eruption site by the Icelandic Meteorological Office and Chalmers University (Gothenburg, Sweden) to measure SO2 emissions during the eruption. Instrument MAYP111126 (cross symbol in Fig. 1) was installed at its location to the east of the lava flow field on 4 March 2015, where it was oriented towards the west and optimally located for viewing of the lava flow field. This occurred after the eruption ended on 27 February, and data from this spectrometer were used to calculate the post-eruptive SO2 flux from the lava flow field.
All scans from instrument MAYP111126, from its installation on 4 March 2015 until 31 May 2015, were examined to identify those with the characteristic trough shape that represented the anticipated view through a low-level haze of SO2 from the lava flow field (Fig. 4c). Each “haze” scan was first re-evaluated between 310 and 325 nm using the NovacProgram software (version 1.82; Galle et al. 2010), including additional spectra in the DOAS fitting process to account for the presence of ozone in the atmosphere and the “Ring effect” (i.e. the “filling-in” of deep absorption features, such as the solar Fraunhofer lines, in a measured atmospheric spectrum, which is caused by inelastic (Raman) scattering of light by air molecules (Grainger and Ring, 1962)). After calculating the column densities, a quality check was applied to ensure that scans retained the characteristic trough shape of the anticipated lava flow field “haze” scans. To ensure a symmetrical trough shape, scans were excluded if slant column densities at + 60° and − 60° differed by more than 20%. To calculate the SO2 flux (in kg/s) recorded by each scan, the measured VCD of SO2 (in kg/m2) was multiplied by the effective width of the SO2 haze (in m) and the haze speed (in m/s), assumed to be equivalent to the wind speed measured at a co-located meteorological station.
Wind speed and direction were recorded every 10 min using a meteorological station installed at the eruption site. Scans were filtered by wind direction, with scans included only when the wind was blowing towards the instrument (± 20°).
Lava flow field radiant heat flux
Uncertainty and error
Individual SO2 flux measurements were calculated as the product of the average vertical column density (VCD), effective haze width, and wind speed. Thus, the total uncertainty on the flux measurement can be obtained by determining the uncertainties of these three independently derived quantities. The uncertainty on the average VCD depends on two factors: the intrinsic uncertainty of the retrieved SCDs at various angles and the uncertainty related to the method used to derive the mean VCD from a set of SCDs in one scan. The typical uncertainty of a DOAS SCD has been characterised for NOVAC instruments by Galle et al. (2010) and is expected to be around 15%. The sources of this uncertainty include added UV radiation by scattering between the plume and the instrument (Mori et al. 2006), uncertainty in the reference absorption cross sections used in the retrieval (Stutz and Platt, 1996), and possible distortions of the sensor response function due to temperature or other environmental effects (Galle et al. 2010).
The method proposed to derive a representative VCD is based on the assumption that a homogenous layer of gas surrounds the instrument. For each scan that contains a set of 26 SCDs taken at steps of 7.2° from horizon to horizon, this assumption results in a trough shape of the distribution of these SCDs. This occurs because the shortest column corresponds to the shortest path through the haze layer, when the scanner looks upwards, and then progressively increases with scan angle, as path length through the haze layer increases (see Fig. 4). Thus, the measurements used in this study were selected by visual inspection of each scan, i.e. only scans with the expected trough-shaped distribution of SCDs were used for analysis. In addition, a numerical filter was applied to use only symmetrical scans, where the columns at + 60° and − 60° differed by less than 20%. A conservative uncertainty related to this method may be 20%, allowing for imperfect scanning geometry, radiative transfer, and natural variability of the columns in the layer. Each VCD thus has a total uncertainty of ~ 35%.
The uncertainty related to the effective haze width depends on the stability of the wind direction and accuracy in the determination of the dimensions of the lava flow field. The wind direction used here was measured by a meteorological station in close proximity to the scanning system, and these data were in good agreement with measurements from another station operated by IMO 20 km further away. This suggests that wind directions close to ground level were relatively stable over a large area, in spite of the presence of a hot lava flow field and a cold glacier. The accuracy of the effective haze width for different wind directions must also be considered. From a map of the extent of the lava flow field, the maximum widths of the lava flow field in directions perpendicular to wind directions in the range 250° to 290° were measured (Fig. 5). This range of wind directions corresponds to the possible directions that would produce a haze above the instrument, which was oriented at 270°. Because our study took place after the eruption had ended, the extent of the lava flow field itself can be considered unchanging. Assuming that the measurements of haze widths from a map can be achieved with an accuracy of 1%, and that wind directions vary (spatially and temporarily) within 20%, the total uncertainty on haze width is of the order of 20%.
Finally, uncertainty related to the haze speed must be determined. It is assumed here that haze speed is equal to wind speed close to the ground. We attribute a value of 20% to this uncertainty, following Galle et al. (2002) and Edmonds et al. (2003). Therefore, the total uncertainty of a single flux measurement is estimated to be, quite conservatively, 45%. The total uncertainty is calculated by summing in “quadrature” the uncertainty of all variables, that is, the relative uncertainty of the flux is equal to the square root of the sum of the squares of the relative uncertainties of the variables, i.e. √(0.352 + 0.22 + 0.22) = 0.45.
Lava flow field SO2 flux
DOAS data from the Holuhraun eruption were processed until the end of May 2015 (Fig. 7), after which SO2 from the lava flow field was below the detection limit of the instrument (5 ppm*m for single spectra). Thus, the lava flow field formed during a 6-month-long eruption continued to release measurable SO2 for 3 months after the eruption ended.
Contribution of Holuhraun lava flow field SO2 emissions
Assuming that the average post-eruption flux of 3 kg/s was emitted constantly throughout the 3 months of this study, an estimated total of 24 kt of SO2 was released during this period. This is equivalent to an additional 0.2% to the total of ~ 11 Mt of SO2 that was released during the eruption. This estimated 24 kt of SO2, released during 3 months, is greater than the 16 kt of SO2 emitted by Icelandic industry in 2013 (Centre on Emission Inventories and Projections, 2015). The SO2 emitted by the lava flow field remained near ground level, resulting in high ground-level concentrations of SO2 near to the eruption site and posing potential health hazards (including respiratory problems and eye irritation; Longo et al. 2008; Ilyinskaya et al. 2017) to people exposed to it. Access was therefore restricted to the area around the lava flow field until 1 June 2015, after a field visit by IMO on 19 May 2015 measured only minor emissions of SO2 from fractures in the lava and from the main eruption crater (IMO, 2015c).
The Holuhraun eruption magma was highly rich in sulphur (Gauthier et al. 2016; Gíslason et al. 2015), resulting in high emissions of SO2 at the vent. It is likely that the magma had a permeable bubble network during ascent allowing volatiles to be released from the magma to form the gas-rich eruption plume (e.g. Burton et al. 2007; Polacci et al. 2008). Therefore, when the lava was erupted, much of its sulphur content had already been released by efficient degassing at the vent, and so only a small proportion of SO2 remained within the lava to be released during and after emplacement. Due to the large size of this flood basalt eruption, this small proportion of SO2 released by the lava flow field was still a large and significant mass of SO2.
The petrologic approach of Thordarson et al. (1996) was used to calculate the portion of erupted lava responsible for outgassing the post-eruptive SO2. Degassed tephra glass contained 377 ppmw sulphur (Bali et al. 2017 Melt inclusion constraints on volatile systematics and degassing history of the 2014-2015 Holuhraun eruption, Iceland, submitted), and degassed lava contained 97 ppmw sulphur (Gauthier et al. 2016). The 24 kt of post-eruptive SO2 are calculated to have been emitted from 4.23 × 1010 kg of the 3.56 × 1012 kg of lava produced by the Holuhraun eruption.
Lava flow field radiant heat flux
Cooling and outgassing of lava flows
Several studies have analysed the cooling and crystallisation of lava bodies (e.g. Keszthelyi and Denlinger, 1996; Wooster et al. 1997; Cashman et al. 1999; Patrick et al. 2004; Kolzenburg et al. 2016). Lava flows cool by thermal radiation and atmospheric convection from the surface and by conduction to the underlying country-rock (Keszthelyi and Denlinger, 1996; Neri, 1998; Patrick et al. 2004). Lava from the Holuhraun eruption had up to 45% vesicles (Lavallée et al. 2015). This high vesicularity is likely to have enhanced the cooling of the flows as lava porosity is considered to affect the rate of cooling, with more vesicular lava cooling more rapidly (Keszthelyi and Denlinger, 1996).
Processes that occur during cooling could contribute to the release of SO2 from the lava flow. As an emplaced lava flow cools and solidifies post-eruption, it thermally contracts (Spry, 1962; Wittmann et al. 2017). Thermal contraction of lava results in the formation of cooling fractures such as brittle cracks and columnar jointing (Ryan and Sammis, 1978; Long and Wood, 1986; Reiter et al. 1987; Grossenbacher and McDuffie, 1995). Continued cooling causes fractures to propagate from the surface into the interior of the flow (Reiter et al. 1987; Aydin and DeGraff, 1988; Kattenhorn and Schaefer, 2008). Not only will fractures and cracks enhance the cooling of the lava flow interior, they will also provide pathways for volatiles to be released from the interior of the flow to the atmosphere (Fuller, 1938; Wilmoth and Walker, 1993).
Extraction of gas from the lava flow should be most efficient where it is highly fractured, which will be where the thermal contraction is greatest. The formation of high permeability pathways through propagation of cooling fractures would account for the fact that SO2 was released from the Holuhraun lava flow field for several months after lava flow emplacement and that over this time, the SO2 flux did not decrease concurrently with the decrease in thermal emission. SO2 flux is not a simple decay correlated with lava cooling, as both volatile availability and fracture propagation produce the SO2 flux. As fractures provide a pathway for gas to escape, outgassing is able to continue as fracture propagation continues to tap volatiles trapped in the cooling flow interior. The episodic nature of fracture propagation (Ryan and Sammis, 1978; DeGraff and Aydin, 1987; Reiter et al. 1987) would explain the fluctuating post-eruption SO2 flux.
Using a petrological method, Thordarson et al. (1996) calculated that of the SO2 released by the 1783–1784 Laki eruption, 20% was released by lava flows during their emplacement and cooling. This is two orders of magnitude larger than our calculated value of 0.2% of SO2 released by the Holuhraun lava flow field in the 3 months following the eruption. The reason for this large discrepancy is that our measurements only began after the eruption had ended. The Holuhraun eruption lasted for 6 months, and therefore, lava flows had been outgassing for up to 6 months before our study even began, and so a significant proportion of the outgassing has not been captured. Outgassing from lava flows is likely to have been greatest during emplacement, when mechanical breakup of the lava crust facilitated gas release (Polacci and Papale, 1997; Soule and Cashman, 2004), and we did not capture syn-emplacement outgassing during our study.
Scanning DOAS instruments were installed at the eruption site of the 2014–2015 Holuhraun eruption to monitor the flux of SO2. Based on a novel approach to measure emissions from the emplaced lava flow field, we found that this lava flow field continued to release SO2 for 3 months after the end of the eruption. During this time, SO2 flux from the lava flow field varied from < 1 to 9 kg/s, and a post-eruption average flux of 3 kg/s was calculated. The post-eruption Holuhraun lava flow field was a significant source of environmental pollution, releasing 24 kt of SO2 in the 3 months after the eruption. This post-eruption lava flow field SO2 flux contributed an additional 0.2% to the ~ 11 Mt total eruption SO2 emissions in the 3 months following the eruption. This emission remained near ground level, posing health hazards, which resulted in access to the area being restricted until 1 June 2015, 3 months after the eruption ended. During solidification, SO2 can be outgassed, we propose, by fracture propagation as high permeability pathways are developed, allowing gas to be released for several months after the end of the eruption. We show that this release is not a simple decay correlated with lava cooling, as both volatile availability and fracture propagation produce a fluctuating SO2 flux.
The installation of the DOAS instruments at Holuhraun were funded by FUTUREVOLC and a Swedish FORMAS grant (2014-1848). We gratefully thank Baldur Bergsson and staff at the Icelandic Meteorological Office for installing and maintaining the equipment. Photos by Baldur Bergsson (Figure 1) and Martin Hensch (Figures 3 and 9) are used with kind permission from the Icelandic Meteorological Office. The NovacProgram software was developed by M. Johansson and Y. Zhang. The authors thank Christoph Kern, Andrew Harris, and an anonymous reviewer for their comments and suggestions which have greatly improved this manuscript.
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