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Calculation of 2p 4(3 P)nl(l=s, d) Rydberg spectra of the fluorine isoelectronic sequence

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Zeitschrift für Physik D Atoms, Molecules and Clusters

Abstract

The basic structure parameters of 2p 4(3 P)ns and 2p 4(3 P)nd (J=1/2, 3/2 and 5/2) Rydberg spectra for the fluorine isoelectronic sequence from FI to NiXX, as functions of effective nuclear charge, are calculated by using the eigenchannel quantum-defect theory. The results can be interpreted in terms of the variations of electrostatic and spin-orbit interactions along the sequence. A vast amount of basic atomic data can be obtained with these parameters as input. Some numerical examples are given, in which our results are in perfect agreement with experimental.

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Authors and Affiliations

  1. Department of Fundamental Science, Zhengzhou Institute of Electronic Technology, P.O. Box 1030, 450004, Zhengzhou, People's Republic of China

    X. -Z. Qian

  2. Institute of Atomic and Molecular Physics, Jilin University, 130023, Changchun, People's Republic of China

    X. -Z. Qian & Z. -W. Wang

Authors
  1. X. -Z. Qian
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  2. Z. -W. Wang
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Qian, X.Z., Wang, Z.W. Calculation of 2p 4(3 P)nl(l=s, d) Rydberg spectra of the fluorine isoelectronic sequence. Z Phys D - Atoms, Molecules and Clusters 36, 93–99 (1996). https://doi.org/10.1007/BF01426622

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  • DOI: https://doi.org/10.1007/BF01426622

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