Summary
-
1.
A study was made of the mass polymerization and rate of hydrolysis of various vinyl esters; the glass temperatures of their polymers were determined.
-
2.
The effect of the structure of the acyl group on the initial rate of polymerization and on the kinetics of the hydrolysis of these esters was determined.
-
3.
It was shown that the effect of the size and structure of side groups of polymers on their glass temperatures is similar in character for vinyl esters. acrvlic esters. and methacrvlic esters.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
Literature cited
A. A. Vansheidt and L. F. Chelpanova, J. Gen. Chem. 20, 226 (1950).
S. N. Ushakov, I. A. Arbuzov, and E. N. Rostovskii, J. Appl. Chem. 20, 1013 (1947).
W. Port, J. Hansen, E. Jordan, T. Deitz and D. Swern, J. pol. Sci. 7, 207 (1951).
L. Craig, R. Kleinschmidt, E. Miller, J. Wilkinson, R. Davis and C. Montross and W. Port, Ind. Eng. Chem. 47, 1702 (1955).
G. Ham and E. Ringwald, J. pol. Sci, 8, 91 (1952).
G. Smets and A. Hertoghe, Makromol. Chem. 17, 189 (1956).
F. Reid, D. Codding and T. Bovey, J. pol. Sci. 18, 417 (1955).
G. Schulz and E. Harborth, Makromol. Chem. 1, 106 (1947).
H. Melville, Nature 158, 553 (1946).
A. N. Pravednikov, Questions of Chemical Kinetics, Catalysis, and Reactivity, Izd. AN SSSR, Moscow, 1955, p. 320.
M. Polanj and Z. Szabo, Trans Faraday Soc, 30, 508 (1934).
A. Kravchenko and V. Penzova, J. Gen. Chem. 20, 2076 (1950).
I. A. Kablukov, E. I. Gapon, and M. A. Grindel', Physical and Colloid Chemistry, Agriculture Press, Moscow, 1942, p. 156.
A. I. Brodskii, Chemistry of Isotopes, Izd. AN SSSR, Moscow, 1952, p. 248.
P. P. Kobeko, Amorphous Substances, Izd. AN SSSR, Moscow and Leningrad, 1952, p. 179.
C. Rehberg and C. Fisher, Ind. Eng. Chem. 40, 1429 (1948).
P. P. Kobeko and N. M. Kummatskaia, Collected Papers in Honor of the 70th Birthday of Academician A. F. Ioffe, Izd. AN SSSR, Moscow, 1950, p. 242.
E. N. Rostovskii and A. N. Barinova, J. Appl. Chem. 27, 1101 (1954)
A. F. Dokukina, M. M. Koton, K. N. Kriukova, O. K. Mineeva, and V. A. Poribok, J. Gen. Chem. 30, 190 (1956).
A. I. Marei, Chemistry and Physical Chemistry of Macromolecular Compounds, Izd. AN SSSR, Moscow, 1952, p. 274.
R. Wiley, J. pol. Sci. 2, 10 (1947).
R. Wiley, G. Brauer, J. pol. Sci 3, 455 (1948).
H. Kaufmann, A. Sacher, T. Alfrey, J. Fankuchen, J. Am. Chem. Soc. 70, 9147 (1948).
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Rostovskii, E.N., Ushakov, S.N. & Barinova, A.N. Properties of some vinyl esters Communication 1. Polymerization and rate of hydrolysis of monomers. Russ Chem Bull 7, 52–55 (1958). https://doi.org/10.1007/BF01170861
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF01170861