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Gel-chromatographic separation of boron-gluconate electrolyte for obtaining nano-crystalline Co–W coatings: Composition and electrochemical activity of components. Part I. Gel-chromatographic study of electrolyte, separation and composition of components

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Abstract

Studies of boron-gluconate electrolyte for obtaining nanocrystalline Co–W coatings and its separation by molecular weights of the components is carried out by gel filtration. It is shown that boric acid (as a buffer agent) and sodium chloride (as the agent increasing conductivity) after being introduced into the electrolyte form certain gluconate complexes in the solution. The boron-gluconate complex has a larger molecular weight. Three fractions with different molecular weights including the fractions that contain Co-boron-gluconate and W-boron-gluconate complexes were obtained. It is shown that the formation of certain macromolecular complexes is a slow process, the consequence of which is the dependence of the bulk properties of the electrolyte on time.

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References

  1. Tsyntsaru, N., Cesiulis, H., Donten, M., et al., Surf. Eng. Appl. Electrochem., 2012, vol. 48, no. 6, pp. 491–520.

    Article  Google Scholar 

  2. Eliaz, N. and Gileadi, E., Mod. Aspects Electrochem., 2008, vol. 42, pp. 191–301.

    Google Scholar 

  3. Brenner, A., Electrodeposition of Alloys. Principle and Practice, New York Academic, 1963.

    Google Scholar 

  4. Podlaha, E.J. and Landolt, D., J. Electrochem. Soc., 1996, vol. 143, pp. 885–893.

    Article  Google Scholar 

  5. Podlaha, E.J. and Landolt, D., J. Electrochem. Soc., 1996, vol. 143, pp. 893–899.

    Article  Google Scholar 

  6. Podlaha, E.J. and Landolt, D., J. Electrochem. Soc., 1997, vol. 144, pp. 1672–1680.

    Article  Google Scholar 

  7. Donten, M., Stojek, Z., and Osteryoung, J.G., J. Electrochem. Soc., 1993, vol. 140, pp. 3417–3424.

    Article  Google Scholar 

  8. Donten, M. and Stojek, Z., J. Appl. Electrochem., 1996, vol. 26, pp. 665–672.

    Article  Google Scholar 

  9. Donten, M., Stojek, Z., and Cesiulis, H., J. Electrochem. Soc., 2003, vol. 150, pp. C95–C98.

  10. Ibrahim, M.A.M., Abd El Rehim, S.S., and Moussa, S.O., J. Appl. Electrochem., 2003, vol. 33, pp. 627–633.

    Article  Google Scholar 

  11. Capel, H., Shipway, P.H., and Harris, S.J., Wear, 2003, vol. 255, pp. 917–923.

    Article  Google Scholar 

  12. Weston, D.P., Harris, S.J., Shipway, P.H., et al., Electrochim. Acta, 2010, vol. 55, pp. 5695–5708.

    Article  Google Scholar 

  13. Weston, D.P., Harris, S.J., Capel, H., et al., Trans. Inst. Met. Finish., 2010, vol. 88, pp. 47–56.

    Article  Google Scholar 

  14. Tsyntsaru, N., Belevsky, S., Dikusar, A., et al., Trans. Inst. Met. Finish., 2008, vol. 86, pp. 301–307.

    Article  Google Scholar 

  15. Tsyntsaru, N., Cesiulis, H., Budreika, A., et al., Surf. Coat. Technol., 2012, vol. 206, pp. 4262–4269.

    Article  Google Scholar 

  16. Tsyntsaru, N., Dikusar, A., Cesiulis, H., et al., Powder Metall. Met. Ceram., 2009, vol. 48, pp. 419–428.

    Article  Google Scholar 

  17. Belevskii, S.S., Cesiulis, H., Tsyntsaru, N.I., and Dikusar, A.I., Surf. Eng. Appl. Electrochem., 2010, vol. 46, pp. 570–578.

    Article  Google Scholar 

  18. Vasauskas, V., Padgurskas, J., Rukuiza, R., et al., Mechanika, 2008, vol. 72, no. 4, pp. 21–27.

    Google Scholar 

  19. Admon, U., Dariel, M.P., Gundbaum, E., and Lodder, J.C., J. Appl. Phys., 1987, vol. 62, pp. 1943–1948.

    Article  Google Scholar 

  20. Park, D.Y. and Ko, J.M., J. Korean Electrochem. Soc., 2003, vol. 6, pp. 236–241.

    Article  Google Scholar 

  21. Sasikumar, D. and Ganesan, S., Dig. J. Nanomater. Biostruct., 2010, vol. 5, pp. 236–241.

    Google Scholar 

  22. Tsyntsaru, N., Cesiulis, H., Pellicer, E., et al., Electrochim. Acta, 2013, vol. 104, pp. 94–103.

    Article  Google Scholar 

  23. Weston, D.P., Gill, S.P.A., Fay, M., et al., Surf. Coat. Technol., 2013, vol. 226, pp. 75–83.

    Article  Google Scholar 

  24. Gotelyak, A.V., Danil’chuk, V.V., Dikusar, A.I., and Silkin, S.A., Izv. Vyssh. Uchebn. Zaved., Khim. Khim. Tekhnol., 2014, vol. 57, no. 6, pp. 78–82.

    Google Scholar 

  25. Tsyntsaru, N., Cesiulis, H., Pelliser E., et al., Electrochim. Acta, 2013, vol. 104, pp. 94–103.

    Article  Google Scholar 

  26. Llopis, E., Ramires, J.A., and Cervilla, A., Transition Met. Chem. (NY), 1986, vol. 11, pp. 489–494.

    Article  Google Scholar 

  27. Survila, A., Moskus, Z., and Kanapeckaite, S., Electrochim. Acta, 2000, vol. 46, pp. 571–577.

    Article  Google Scholar 

  28. Belevskii, S.S., Yushchenko, S.P., and Dikusar, A.I., Surf. Eng. Appl. Electrochem., 2012, vol. 48, no. 1, pp. 97–98.

    Article  Google Scholar 

  29. Shulman, A.I., Belevskii, S.S., Yushchenko, S.P., and Dikusar, A.I., Surf. Eng. Appl. Electrochem., 2014, vol. 50, no. 1, pp. 9–17.

    Article  Google Scholar 

  30. Belevskii, S.S., Kosova, A.P., Yushchenko, S.P., et al., Surf. Eng. Appl. Electrochem., 2011, vol. 47, no. 1, pp. 4–8.

    Article  Google Scholar 

  31. Silkin, S.A., Gotelyak, A.V., Tsyntsaru, N.I., and Dikusar, A.I., Surf. Eng. Appl. Electrochem., 2015, vol. 51, no. 3, pp. 228–234.

    Article  Google Scholar 

  32. Berkh, O., Burstein, L., Shacham, Y., and Gileadi, E., J. Electrochem. Soc., 2011, vol. 158, no. 6, pp. F85–F91.

    Google Scholar 

  33. Osterman, L.A., Khromatografiya belkov i nukleinovykh kislot (Chromatography of Proteins and Nucleic Acids), Moscow Nauka, 1985.

    Google Scholar 

  34. Hillebrand, W.F., Lundell, G.E.F., Bright, H.A., and Hoffman, J.I., Applied Inorganic Analysis, New York: Wiley, 1953, 2nd ed.

    Google Scholar 

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Authors and Affiliations

  1. Institute of Applied Physics of the Academy of Sciences of Moldova, ul. Academiei 5, Chisinau, MD-2028, Moldova

    S. S. Belevskii, V. A. Buravets, S. P. Yushchenko & A. I. Dikusar

  2. Shevchenko Pridnestrov’e State University, ul. 25 Oktyabrya 128, Tiraspol, Moldova

    S. P. Yushchenko & A. I. Dikusar

  3. QUEST SRL, Floreshty, Moldova

    I. M. Zgardan

Authors
  1. S. S. Belevskii
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  2. V. A. Buravets
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  3. S. P. Yushchenko
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  4. I. M. Zgardan
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  5. A. I. Dikusar
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Corresponding author

Correspondence to A. I. Dikusar.

Additional information

Original Russian Text © S.S. Belevskii, V.A. Buravets, S.P. Yushchenko, I.M. Zgardan, A.I. Dikusar, 2016, published in Elektronnaya Obrabotka Materialov, 2016, No. 4, pp. 38–43.

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Belevskii, S.S., Buravets, V.A., Yushchenko, S.P. et al. Gel-chromatographic separation of boron-gluconate electrolyte for obtaining nano-crystalline Co–W coatings: Composition and electrochemical activity of components. Part I. Gel-chromatographic study of electrolyte, separation and composition of components. Surf. Engin. Appl.Electrochem. 52, 350–355 (2016). https://doi.org/10.3103/S1068375516040049

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  • DOI: https://doi.org/10.3103/S1068375516040049

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