Skip to main content
Log in

Effect of a semiconductor filler and aluminum nanoparticles on the surface structures and dielectric properties of PVDF + TlInS2〈Al〉 composite materials

  • Published:
Surface Engineering and Applied Electrochemistry Aims and scope Submit manuscript

Abstract

The results of a study of the temperature and frequency dependences of the dielectric permeability and dielectric loss of PVDF + TlInS2 and PVDF + TlInS2 + Al composites at frequencies of 10–105 Hz and temperatures of 20–150°C and the effect of 50-nm aluminum nanoparticles on the dielectric properties of PVDF + x vol % TlInS2 composite materials are described. It is revealed that an increase in the percentage of the TlInS2 filler in the matrix leads to an increase in the dielectric permeability and dielectric loss of these materials. An increase in the amount of the PVDF + x vol % TlInS2 + y vol % Al composites is also observed with an increase in the aluminum nanoparticle content in the composite; this effect leads to a change in the Maxwell–Wagner space-charge polarization. Under the effect of aluminum nanoparticles, the pattern of the frequency dispersion of the dielectric loss of the studied composites changes significantly.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. Shik, A., Ruda, H.E., and Sargent, E.H., Photoelectric phenomena in polymer-based composites, J. Appl. Phys., 2000, vol. 88, no. 6, pp. 3448–3453.

    Article  Google Scholar 

  2. Hashimov, A.M., Hasanli, Sh.M., Mehdizadeh, R.N., Azizova, Sh.M., and Bayramov, Kh.B., Nonlinear resistor based on a polymer-ceramic composition, Tech. Phys., 2007, vol. 52, no. 8, pp. 1086–1088.

    Article  Google Scholar 

  3. Alexandrova, E.L., Lebedev, E.A., Konstantinova, N.N., and Aleshin, A.N., Switching effects in composite films based on the conjugated polymer polyfluorene and ZnO nanoparticles, Phys. Solid State, 2010, vol. 52, no. 2, pp. 422–425.

    Article  Google Scholar 

  4. Lushcheikin, G.A., New polymer-containing piezoelectric materials, Phys. Solid State, 2006, vol. 48, no. 6, pp. 1023–1025.

    Article  Google Scholar 

  5. Godzhaev, E.M., Magerramov, A.M., Osmanova, S.S., and Nuriev, M.A., Charged state of polymer composites containing TlInS2 semiconductor, EOM, 2013, vol. 49, no. 4, pp. 1–5.

    Google Scholar 

  6. Godzhaev, E.M., Nabiev, N.S., Zeinalov, Sh.A., Osmanova, S.S., Allakhyarov, E.A., and Gasanova, A.G., A study of the fluorescence spectra and dielectric properties of HDPE + x vol % TlGaSe2 composites, Surf. Eng. Appl. Electrochem., 2013, vol. 49, no. 3, pp. 194–198.

    Article  Google Scholar 

  7. Yablokov, M.Yu., Kechek’yan, A.S., Gil’man, A.B., and Ozerin, A.N., The eelectret properties of polypropylene composites, Nanotekhnika, 2011, no. 2, pp. 86–88.

    Google Scholar 

  8. Hippel, A.R., Dielectrics and Waves, New York: Wiley, 1954.

    Google Scholar 

  9. Muradyan, V.E., Sokolov, E.A., Babenko, S.D., and Moravsky, A.P., Microwave dielectric properties of composites modified by carbon nanostructures, Tech. Phys. Russ. J. Appl. Phys., 2010, vol. 55, no. 2, pp. 242–246.

    Google Scholar 

  10. Eyubova, N.A., Kuliev, M.M., Ismayilova, R.S., and Abdullaev, A.P., Derivatographic Studies of polyethylene containing a dispersed semiconductor, Surf. Eng. Appl. Electrochem., 2011, vol. 47, no. 3, pp. 253–255.

    Article  Google Scholar 

  11. Godzhaev, E.M., Magerramov, A.M., Safarova, S.I., Nuriev, M.A., and Ragimov, R.S., Dielectric properties of polymer composites with TlInSe2 semiconductor filler, Surf. Eng. Appl. Electrochem., 2008, vol. 44, no. 6, pp. 480–483.

    Article  Google Scholar 

  12. Kuliev, M.M. and Ismaiilova, R.S., Electric properties of composites filled with disperse oxides, Surf. Eng. Appl. Electrochem., 2009, vol. 45, no. 4, p. 297.

    Article  Google Scholar 

  13. Tupik, A.V. and Garmashov, S.I., Dielectric losses in statistical mixtures, Phys. Solid State, 2011, vol. 53, no. 6, pp. 1194–1197.

    Article  Google Scholar 

  14. Ushakov, N.M., Ul’zutuev, A.N., and Kosobudskii, I.D., Thermodielectric properties of polymer composites based on CuO-covered Cu particles in high-pressure polyethylene, Tech. Phys. Russ. J. Appl. Phys., 2008, vol. 53, no. 12, pp. 1597–1601.

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to E. M. Godzhaev.

Additional information

Original Russian Text © E.M. Godzhaev, A.N. Mirzoeva, Sh.A. Zeinalov, S.S. Osmanova, 2016, published in Elektronnaya Obrabotka Materialov, 2016, No. 2, pp. 1–7.

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Godzhaev, E.M., Mirzoeva, A.N., Zeinalov, S.A. et al. Effect of a semiconductor filler and aluminum nanoparticles on the surface structures and dielectric properties of PVDF + TlInS2〈Al〉 composite materials. Surf. Engin. Appl.Electrochem. 52, 127–133 (2016). https://doi.org/10.3103/S106837551602006X

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.3103/S106837551602006X

Keywords

Navigation