Abstract
The method of recovery of contaminating components from sweepings of the aluminum production for their further return into the electrolyzer is proposed. To concentrate the material, the following processing flowsheet is proposed: milling–classification–reverse flotation–thickening. For the most complete removal of silicon and iron oxides during the flotation of sweepings, the Flotigam 7266 flotation reagent produced by Clariant (Germany), which is a mixture of primary fatty alkyl amines, is used. To remove carbon particles, the combination of pine oil in a mixture with kerosene is used. Flotation is performed using a FML 0.3 flotation machine. The initial material, chamber product, and tails are analyzed for the content of carbon and aluminum, iron, and silicon oxides using X-ray spectral (XSA), X-ray phase (XPA), and chemical analyses. It is established that processing the total material mass does not make it possible to acquire a product with an acceptable content of silicon and iron oxides. Based on the XPA of various fractions of the initial material, it is proposed to process the material fractions containing the minimal amount of contaminating substances (carbon and silicon and iron oxides). Two fractions are selected for processing using the flotation method by the XRS results of various material fractions:–0.071 mm and +5.0 mm. When processing the first of them, the chamber product of the acceptable quality is acquired. A product with a high content of alumina and fluorinated components at low carbon and iron oxide concentrations but a considerable amount of silicon oxide is acquired from a coarse electrolyte-containing fraction (+5.0 mm). The further use of this product is possible to fabricate aluminum–silicon alloys.
Similar content being viewed by others
References
Wong, David S., Tjahyono, Nursiani I., and Hyland, Margaret M., The nature of particles and fines in potroomdust, in: TMS Light Metals. 2014, Trondheim, Norway: Wiley. 2014, pp. 553–558.
Wong, David S., Tjahyono, Nursiani I., and Hyland, Margaret M., Visualizing the sources of potroom dust in aluminium smelters, TMS Light Metals. 2012, Trondheim. Norway: Wiley. 2012, pp. 833–838.
Jassim, Ali Al-Mejali, Geir, Martin Haarberg, Nasr, Bensalah, Ben-Aissa, Benkahla, and Hans, Petter., The role of key impurity elements on the performance of aluminum electrolysis—current efficiency and metal quality, TMS Light Metals. 2016, Trondheim, Norway: Wiley. 2016, pp. 389–394.
Zel’berg, B.I., Ragozin, L.V., Barantsev, A.G. Yasevich, O.I., Grigoryev, V.G., and Baranov, A.N., Spravochnik metallurga. Proizvodstvo aluminia i splavov na ego osnove (Steel Worker’s Guide. Aluminum and Aluminum Alloys Production on Its Base), St. Petersburg: MANEB. 2013.
Kulikov, B.P. and Istomin, S.P., Pererabotka otkhodov alyuminievogo proizvodstva (Processing of Wastes of Aluminum Production), Krasnoyarsk: KlassikTsentr. 2004.
Kondrat’ev, V.V., Afanas’ev, A.D., Rzhechitskii, A.E., Rzhechitskii, E.P., Pankov, S.D., and Ivanov, N.A., RF Patent 2429198, 2010.
Baranov, A.N., Gavrilenko, L.V., Morenko, A.V., Gavrilenko, A.A., Timkina, E.V., and Yukushevich, P.A., Production of calcium fluoride from solid and liquid wastes of aluminum production process, J. SibFU. Techn. Technol., 2015, vol. 8, no. 4, pp. 468–474.
Mann, V., Pingin, V., Zherdev, A., Bogdanov, Y., Pavlov, S., and Somov, V., SPL recycling and re-processing, TMS Light Metals. 2017, Trondheim, Norway: Wiley. 2017, pp. 571–578.
Black, P.J. and Cooper, B.J., Sustainable practices in spent potliner—an industrial ecology approach, TMS Light Metals. 2016, Trondheim, Norway: Wiley. 2016, pp. 461–466.
Birry, L., Leclerc, S., and Poirie, S., The LCL&L process: A sustainable solution for the treatment and recycling of spent potlining, TMS Light Metals. 2016, Trondheim, Norway: Wiley. 2016, pp. 467–472.
Gaustad, G., Olivetti, E., and Kirchain, R., Improving aluminum recycling: A survey of sorting and impurity removal technologies, Res., Conserv. Recycl., 2012, vol. 58, pp. 79–87.
Shinzato, M. C. and Hypolito, R., Solid waste from aluminum recycling process: characterization and reuse of its economically valuable constituents. Waste Manag., 2005, vol. 25, no. 1, pp. 37–46.
Bell, N., Andersen, J. N., and Lam, H. K. H., US Patent 4113832. 1978.
Roberts, E. J., Bunk, S., and Angevine, P. A., US Patent 4053375. 1977.
Abdrakhimov, V. Z., Use of aluminum-containing waste in production of ceramic materials for various purposes. Refract. Ind. Ceram., 2013, vol. 54, no. 1, pp. 7–16.
Filippov, S.V., Volyansky, V.V., and Gavrilenko, L.V., Processing of sludge and dust of gas purification by flotation to obtain fluorine-alumina concentrate. in: The first international congress “Non-Ferrous Metals of Siberia- 2009”, Krasnoyarsk: Verso. 2009, pp. 324–326.
Filippov, L.O., Filippova, I.V., and Severov, V.V., The use of collectors mixture in the reverse cationic flotation of magnetite ore: The role of Fe-bearing silicates, Miner. Eng., 2010, vol. 23, no. 2, pp. 91–98.
Filippov, L.O., Severov, V.V., and Filippova, I.V., An overview of the beneficiation of iron ores via reverse cationic flotation, Int. J. Miner. Process., 2014, vol. 127, pp. 62–69.
Avdokhin, V.M. and Gubin, S.L., Reverse magnetite concentrate flotation by cation collectors, Gorn. Analit. Bull., 2006, no. 5, pp. 324–331.
Gzogyan, T.N. and Gubin, S.L., Effect of the physicalchemical factors on flotation perfection of magnetite concentrates, J. Mining Sci., 2008, vol. 44, no. 1, pp. 108–114.
Vasyunina, N.V., Vasyunina, I.P., Mikhalev, Y.G., and Vinogradov, A.M., Behavior of secondary alumina during heating, Russ. J. Non-Ferrous Met., 2010, no. 6, pp. 447–450.
Ponomarev, A.I., Metody khimicheskogo analiza silikatnykh i karbonatnykh gornykh porod (Methods of Chemical Analysis of Silicate and Carbonate Rocks), Moscow: AN SSSR. 1961.
Alekseev, V.N., Kolichestvennyi analiz (Quantitative Analysis), Moscow: Khimiya. 1972.
Abdrakhimov, V.Z. and Abdrakhimova, E.S., Study of phase composition of ceramic materials based on nonferrous metallurgy, chemical, and petrochemical industry aluminum-containing waste, Refract. Industr. Ceram., 2015, vol. 56, no. 1, pp. 5–10.
Author information
Authors and Affiliations
Corresponding author
Additional information
Original Russian Text © N.V. Vasyunina, S.V. Belousov, I.V. Dubova, A.V. Morenko, K.E. Druzhinin, 2018, published in Izvestiya Vysshikh Uchebnykh Zavedenii, Tsvetnaya Metallurgiya, 2018, No. 2, pp. 4–12.
About this article
Cite this article
Vasyunina, N.V., Belousov, S.V., Dubova, I.V. et al. Recovery of Silicon and Iron Oxides from Alumina-Containing Sweepings of Aluminum Production. Russ. J. Non-ferrous Metals 59, 230–236 (2018). https://doi.org/10.3103/S1067821218030148
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.3103/S1067821218030148