Skip to main content
SpringerLink
Log in

Relaxation Processes upon Thermal Ignition in a Flow-Type Reactor

  • Published:
Bulletin of the Russian Academy of Sciences: Physics Aims and scope

Abstract

The possibility of determining the kinetic parameters of a reaction proceeding in a reactor with a fixed catalyst bed under critical conditions of ignition is demonstrated. The device of the measuring reactor and the consequences of ignition are described in detail. The proposed approach can be applied to corresponding variants of Fischer–Tropsch synthesis for hydrocarbons, along with other types of synthesis that employ fixed catalyst beds and high energies of activation. It is an easy way of determining the activity of catalysts.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1.
Fig. 2.
Fig. 3.
Fig. 4.

Similar content being viewed by others

REFERENCES

  1. Mordkovich, V.Z., Sineva, L.V., Kul’chanskaya, E.V., and Asalieva, E.Yu., Katal.Prom-sti, 2015, vol. 15, no. 5, p. 23.

    Google Scholar 

  2. Slivinskii, E.V., Kliger, G.A., Kuz’min, A.E., et al., Ross. Khim. Zh., 2003, vol. 47, no. 6, p. 12.

    Google Scholar 

  3. Frank-Kamenetskii, D.A., Diffuziya i teploperedacha v khimicheskoi kinetike (Diffusion and Heat Transfer in Chemical Kinetics), Moscow: Nauka, 1967.

  4. Kagan, Yu.B., Rozovskii, A.Ya., Slin’ko, M.Z., and Ponomarenko, A.T., Kinet. Katal., 1964, vol. 5, no. 5, p. 920.

    Google Scholar 

  5. Kagan, Yu.B., Rozovskii, A.Ya., Slin’ko, M.Z., and Ponomarenko, A.T., Kinet. Katal., 1964, vol. 5, no. 6, p. 1111.

    Google Scholar 

  6. Kagan, Yu.B., Ponomarenko, A.T., and Rozovskii, A.Ya., Kinet. Katal., 1966, vol. 7, no. 4, p. 679.

    Google Scholar 

  7. Kagan, Yu.B., Ponomarenko, A.T., Rozovskii, A.Ya., et al., Neftekhimiya, 1965, vol. 5, no. 1, p. 82.

    Google Scholar 

  8. Kipnis, M.A., Kinet. Katal., 2017, vol. 17, no. 4, p. 266.

    Google Scholar 

Download references

ACKNOWLEDGMENTS

The authors are grateful to Yu.B. Kagan, M.G. Slin’ko, and Profs. A.N. Bashkirov, A.Y. Rozovskii, and C.M. Loktev for their cooperation in studying the kinetics of the synthesis of higher alcohols from CO and hydrogen in the 1960s and subsequent years, and for helping develop the approach presented in this work. We also thank the team of technicians who actively participated in our experiments under the direction of I.A. Antoshchuk.

Author information

Authors and Affiliations

  1. Enikolopov Institute of Synthetic Polymeric Materials, Russian Academy of Sciences, 117393, Moscow, Russia

    A. T. Ponomarenko & V. G. Shevchenko

Authors
  1. A. T. Ponomarenko
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. V. G. Shevchenko
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to A. T. Ponomarenko.

Additional information

Translated by V. Selikhanovich

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Ponomarenko, A.T., Shevchenko, V.G. Relaxation Processes upon Thermal Ignition in a Flow-Type Reactor. Bull. Russ. Acad. Sci. Phys. 84, 1058–1061 (2020). https://doi.org/10.3103/S1062873820090269

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.3103/S1062873820090269

Search

Navigation