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Ferroelectric Phase Transitions in Non-Stoichiometric Sodium-Bismuth Titanate Ceramics

  • Proceedings of the XXI National Conference on Magnetoelectrics Physics
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Bulletin of the Russian Academy of Sciences: Physics Aims and scope

Abstract

Features are studied of the phase formation, structural parameters, microstructure, and dielectric and ferroelectric properties of non-stoichiometric (Na0.5 + xBi0.5)TiO3 ceramics with x = 0–0.1. The investigated samples exhibit ferroelectric phase-transition behavior as anomalies and peaks in dielectric permittivity near 400 and 600 K, respectively. Study of the second harmonic generation shows that phase transitions near 400 K exhibit relaxor-type behavior, indicating there are polar regions in the nonpolar matrix. An increase in the Na/Bi ratio in the initial compositions improves the dielectric and ferroelectric properties of the ceramics.

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References

  1. Zhang, S.J., Xia, R., and Shrout, R.T., J. Electroceram., 2007, vol. 19, p.251.

    Article  Google Scholar 

  2. Takenaka, T., Nagata, H., and Hiruma, Y., Jpn. J. Appl. Phys., 2008, vol. 47, p. 3787.

    Article  ADS  Google Scholar 

  3. Panda, P.K., J. Mater. Sci., 2009, vol. 44, p. 5049.

    Article  ADS  Google Scholar 

  4. Gupta, V., Sharma, M., and Thakur, N., J. Intell. Mater. Syst. Struct., 2010, vol. 21, p. 1227.

    Article  Google Scholar 

  5. Rodel, J., et al., J. Eur. Ceram. Soc., 2015, vol. 35, p. 1659.

    Article  Google Scholar 

  6. Smolenskii, G.A., et al., Fiz. Tverd. Tela, 1961, vol. 2, p. 2651.

    Google Scholar 

  7. Vakhrushev, S.B., et al., Ferroelectrics, 1985, vol. 63, p.153.

    Article  Google Scholar 

  8. Jones, G.O. and Thomas, P.A., Acta Crystallogr. Sect. B, 2002, vol. 58, p.168.

    Article  Google Scholar 

  9. Dorcet, V., Trolliard, G., and Boullay, P., Chem. Mater., 2008, vol. 20, p. 5061.

    Article  Google Scholar 

  10. Tan, X., et al., J. Am. Ceram. Soc., 2011, vol. 94, p. 4091.

    Article  Google Scholar 

  11. Sung, Y.S., et al., Appl. Phys. Lett., 2010, vol. 96, p. 022901.

    Article  ADS  Google Scholar 

  12. Shvartsman, V.V. and Lupascu, D.C., J. Am. Ceram. Soc., 2012, vol. 95, p.1.

    Article  Google Scholar 

  13. Li, M., et al., Chem. Mater., 2015, vol. 27, p.629.

    Article  Google Scholar 

  14. Kleemann, W., Int. J. Mod. Phys. B, 1993, vol. 7, p. 2469.

    Article  ADS  Google Scholar 

Download references

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Authors and Affiliations

  1. Karpov Research Institute of Physical Chemistry, Moscow, 105064, Russia

    E. D. Politova, A. V. Mosunov, N. V. Golubko, G. M. Kaleva, N. V. Sadovskaya & S. Yu. Stefanovich

  2. Moscow State University, Moscow, 119991, Russia

    D. A. Strebkov & S. Yu. Stefanovich

Authors
  1. E. D. Politova
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  2. D. A. Strebkov
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  3. A. V. Mosunov
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  4. N. V. Golubko
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  5. G. M. Kaleva
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  6. N. V. Sadovskaya
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  7. S. Yu. Stefanovich
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Corresponding author

Correspondence to E. D. Politova.

Additional information

Original Russian Text © E.D. Politova, D.A. Strebkov, A.V. Mosunov, N.V. Golubko, G.M. Kaleva, N.V. Sadovskaya, S.Yu. Stefanovich, 2018, published in Izvestiya Rossiiskoi Akademii Nauk, Seriya Fizicheskaya, 2018, Vol. 82, No. 3, pp. 312–315.

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Politova, E.D., Strebkov, D.A., Mosunov, A.V. et al. Ferroelectric Phase Transitions in Non-Stoichiometric Sodium-Bismuth Titanate Ceramics. Bull. Russ. Acad. Sci. Phys. 82, 269–272 (2018). https://doi.org/10.3103/S106287381803019X

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  • DOI: https://doi.org/10.3103/S106287381803019X

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