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Aluminum oxynitride by SHS under high pressure of nitrogen gas

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Abstract

Aluminum oxynitride (γ-AlON) powders were prepared from low-caloric Al–Al2O3 mixtures by SHS under high pressure of nitrogen gas in the presence of heat-generating agent, Mg(ClO4)2, as a booster. The preparation procedure was characterized and optimized with respect to Al/Al2O3 ratio, amount of heatgenerating additive, and nitrogen gas pressure. The morphology of synthesized γ-AlON powders was found to depend on Al powder brand. Compared to γ-AlON powders obtained in chemical furnace, we managed to prepare less sintered arenaceous cakes that could be easily disintegrated into target γ-AlON powder. SHSproduced powders may find their application in production of optical ceramics.

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References

  1. McCauley, J.W., Patel, P., Chen, M., Gilde, G., Strassburger, E., Paliwal, B., Ramesh, K.T., and Dandekar, D.P., AlON: A brief history of its emergence and evolution, J. Eur. Ceram. Soc., 2009, vol. 29, no. 2, pp. 223–236. doi 10.1016/j.jeurceramsoc.2008.03.046

    Article  Google Scholar 

  2. Zheng, J. and Forslund, B., Carbothermal synthesis of aluminum oxynitride (AlON) powder: Influence of starting materials and synthesis parameters, J. Eur. Ceram. Soc., 1995, vol. 15, no. 11, pp. 1087–1100. doi 10.1016/0955-2219(95)00078-9

    Article  Google Scholar 

  3. Li, Y.W., Li, N., and Yuan, R.Z., Effect of raw materials on carbothermal reduction synthesis of γ-aluminum oxynitride spinel powder, J. Mater. Sci., 1999, vol. 34, no. 11, pp. 2547–2552. doi 10.1023/A:1004636312836

    Article  Google Scholar 

  4. Yuan, X., Liu, X., Zhang, F., and Wang, S., Synthesis of γ-AlON powders by a combinational method of carbothermal reduction and solid-state reaction, J. Am. Ceram. Soc., 2010, vol. 93, no. 1, pp. 22–24. doi 10.1111/j.1551-2916.2009.03380.x

    Article  Google Scholar 

  5. Gromov, A., Ilyin, A., Ditts, A., and Vereshchagin, V., Combustion of Al–Al2O3 mixtures in air, J. Eur. Ceram. Soc., 2005, vol. 25, no. 9, pp. 1575–1579.

    Article  Google Scholar 

  6. Galakhov, A.V., Zelenskii, V.A., Vinogradov, L.V., Antipov, V.I., and Alymov, M.I., Synthesis of aluminum oxynitride from starter organic compounds, Refract. Ind. Ceram., 2012, vol. 53, no. 4, pp. 269–271. doi 10.1007/s11148-012-9505-3

    Article  Google Scholar 

  7. Borovinskaya, I.P., Ignat’eva, T.I., Semenova, V.N., and Chemagina, E.A., SHS of aluminum oxynitride in chemical furnace, Int. J. Self-Propag. High-Temp. Synth., 2015, vol. 24, no. 3, pp. 142–147. doi 10.3103/S1061386215030036

    Article  Google Scholar 

  8. Borovinskaya, I.P, Akopdzhanyan, T.G., Ignat’eva, T.I., and Chemagina, E.A., Structure and phase formation of combustion products during γ-AlON synthesis under nitrogen pressure, Izv. Vyssh. Uchebn. Zaved., Poroshk. Metall. Funkts. Pokrytiya, 2016, no. 3 (in press).

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Correspondence to T. G. Akopdzhanyan.

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Akopdzhanyan, T.G., Borovinskaya, I.P. & Chemagina, E.A. Aluminum oxynitride by SHS under high pressure of nitrogen gas. Int. J Self-Propag. High-Temp. Synth. 26, 110–114 (2017). https://doi.org/10.3103/S1061386217020029

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  • DOI: https://doi.org/10.3103/S1061386217020029

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