Abstract
Solution-combustion synthesis (SCS) of nanoparticles was characterized by the temperature effect (ΔT ad) calculated upon neglect by the temperature dependence of heat capacity. Thus calculated ΔT ad values were found to be a linear function of the inverse radius of metal ions. Our calculations have shown that SCS reactions may yield not only oxides but also hydroxides and carbonates. Suggested was a simple formula for evaluating the ΔT ad values attained in SCS of complex oxides.
Similar content being viewed by others
References
Kingsley, J.J. and Patil, K.C., A novel combustion process for the synthesis of fine particle a-alumina and related oxide materials, Mater. Lett., 1988, vol. 6, nos. 11–12, pp. 427–432.
Mukasyan, A.S., Epstein, P., and Dinka, P., Solution combustion synthesis of nanomaterials, Proc. Combust. Inst., 2007, vol. 31, pp. 1789–1795.
Zhuravlev, V.D., Bamburov, V.G., Beketov, A.R., Perelyaeva, L.A., Baklanova, I.V., Sivtsova, O.V., Vasil’ev, V.G., Vladimirova, E.V., Shevchenko, V.G., and Grigorov, I.G., Solution combustion synthesis of a-Al2O3 using urea, Ceram. Int., 2013, vol. 39, no. 2, pp. 1379–1384.
Sherikar, B.N. and Umarji, A.M., Synthesis of γ-alumina by solution combustiom method using mixed fuel approach (urea + glycine fuel), Int. J. Res. Eng. Technol., 2013, IC-RICE Conference Issue, pp. 434–438.
Krishna, R.H., Nagabhushana, B.M., Sherikar, B.N., Murthy, N.S., Shivakumara, C., and Thomas, T., Luminescence enhancement in monoclinic CaAl2O4: Eu2+,Cr3+ nanophosphor by fuel-blend combustion synthesis, Chem. Eng. J., 2015, vol. 267, pp. 317–323.
Bhaduri, S., Bhaduri, S.B., and Prisbrey, K.A., Autoignition synthesis of nanocrystalline MgAl2O4 and related nanocomposites, J. Mater. Res., 1999, vol. 14, no. 9, pp. 3571–3580.
Mukasyan, A.S., Epstein, P., and Dinka, P., Solution combustion synthesis of nanomaterials, Proc. Combust. Inst., 2007, vol. 31, pp. 1789–1795.
Chakraborty, A., Basu, R.N., and Maiti, H.S., Lowtemperature sintering of La(Ca)CrO3 prepared by an autoignition process, Mater. Lett., 2000, vol. 45, nos. 3–4, pp. 162–166.
Azegami, K., Yoshinaka, M., Hirota, K., and Yamaguchi, O., Formation and sintering of LaCrO3 prepared by the hydrazine method, Mater. Res. Bull., 1998, vol. 33, no. 2, pp. 341–348.
Colomer, M.T., Fumo, D., Jurado, J.R. and Segadres, A., Non-stoichiometric La1–x NiO3–d perovskites produced by combustion synthesis, J. Mater. Chem., 1999, vol. 9, no. 10, pp 2505–2510.
Zhang, Ch., Li, Sh., Liu, X., Zhao, X., He, D., Qiu, H., Yu, Q., Wang, Sh., and Jiang, L., Low temperature synthesis of Yb doped SrCeO3 powders by gel combustion process, Int. J. Hydrogen Energ., 2013, vol. 38, no. 29, pp. 12921–12926.
Jadhav, S.T., Dubal, S.U., Jamale A.P., Patil, S.P., Bhosale, C.H., Puri, V.R., and Jadhav, L.D., Structural, morphological and electrical studies of BaCe0.8Y0.2O3–d synthesized by solution combustion method, Ionics, 2015, vol. 21, no. 5, pp. 1295–1300.
Silva, A.L.A., Conceição, L., Rocco, A.M., and Souza, M.M.V.M., Synthesis of Sr-doped LaMnO3 and LaCrO3 powders by combustion method: Structural characterization and thermodynamic evaluation, Cerâmica, 2012, vol. 58, no. 348, pp. 521–528.
Ianos, R., An efficient solution for the single-step synthesis of 4CaO–Al2O3–Fe2O3 powders, J. Mater. Res., 2009, vol. 24, no. 1, pp. 245–252.
Patil, K.C., Uruna, S.T. and Minami, S.T., Combustion synthesis: an update, Curr. Opin. Solid State Mater. Sci., 2002, vol. 6, no. 6, pp. 507–512.
Alves, A.K, Bergmann, C.P., and Berutti, F.A., Novel Synthesis and Characterization of Nanostructured Materials: Engineering Materials, Berlin–Heidelberg: Springer, 2013.
Khaliullin, Sh.M., Zhuravlev, V.D., Bamburov, V.G., and Ermakova, L.V., Combustion synthesis of submicron CaZrO3, Phys. Atomic Nuclei, 2015, vol. 78, no. 12, pp. 1382–1388.
Khaliullin, Sh.M., Bamburov, V.G., Russkikh, O.V., Ostroushko, A.A., and Zhuravlev, V.D., CaZrO3 synthesis in combustion reactions with glycine, Dokl. Chem., 2015, vol., 461, pt. 2, pp. 93–95.
Khaliullin, Sh.M., Zhuravlev, V.D., Russkikh, O.V., Ostroushko, A.A., and Bamburov, V.G., Solution-combustion synthesis and eletroconductivity of CaZrO3, Int. J. Self-Propag. High-Temp Synth., 2015, vol. 24, no. 2, pp. 83–88.
Naumov, G.B., Ryzhkov, B.N., and Khodakovsky, I.L., Spravochnik termodinamicheskikh velichin (Thermodynamic Quantities: A Handbook), Moscow: Atomizdat, 1971.
Veryatin, U.D., Masherov, V.P., Ryabsev, N.G., Tarasov, V.I., Rogozkin, B.D., and Korobov, I.V., Termodinamicheskie svoystva neorganicheskikh veshchestv: Spravochnik (Thermodynamic Properties of Inorganic Compounds: A Handbook), Moscow: Atomizdat, 1965.
Dean, J.A., Lange’s Handbook of Chemistry, New York: McGraw-Hill, 1999.
Rossini, F.D., Wagman, D.D., Evans, W.H., Levine, S., and Jaffe, I., Selected Values of Chemical Thermodynamic Properties, Washington: National Bureau of Standards, 1952.
Shreir, L.L., Corrosion: Corrosion Control, Newnes–Butterworths, vol. 2, 1979.
CRC Handbook of Chemistry and Physics, Haynes, W.M., Ed., DVD Version, 2013.
Moiseev, G.K., Vatolin, N.A., Marchuk, L.A., and Il’inykh, N.I., Temperaturnye zavisimosti privedennoi energii Gibbsa nekotorykh neorganicheskikh veshchestv (Temperature Dependence of Reduced Gibbs Energies for Some Inorganic Compounds), Yekaterinburg: Izd. UrO RAN, 1997.
Karapet’yants, M.Kh., Khimicheskaya termodinamika (Chemical Thermodynamics), Moscow: Khimiya, 1975.
Krestov, G.A., Termodinamika ionnykh prosessov v rastvorakh (Thermodynamics of Ionic Processes in Solution), Leningrad: Khimiya, 1984.
Karapet’yants, M.Kh. and Drakin, S.I., Obshchaya i neorganicheskaya khimiya (General and Inorganic Chemistry), Moscow: Khimiya, 1981.
Jacobson, N.S., Thermodynamic Properties of Some Metal Oxide–Zirconia Systems, Cleveland, OH: NASA Levis Research Center, 1989.
Author information
Authors and Affiliations
Corresponding author
Additional information
The article is published in the original.
About this article
Cite this article
Khaliullin, S.M., Zhuravlev, V.D. & Bamburov, V.G. Solution-combustion synthesis of oxide nanoparticles from nitrate solutions containing glycine and urea: Thermodynamic aspects. Int. J Self-Propag. High-Temp. Synth. 25, 139–148 (2016). https://doi.org/10.3103/S1061386216030031
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.3103/S1061386216030031