Abstract
The results of the statistical processing of data on the determination of the apparent (ρa) and pycnometric (ρp) densities and the accessible (open) porosity (P a) of samples cut out in parallel (||) and perpendicularly (⊥) to the axis of extrusion of the workpieces of fine-grained graphites (>90% of coke filler particles of size<90 μm) are reported. It is shown that, for graphites based on uncalcined petroleum coke and medium- and high-temperature coal tar pitch, ρ ⊥a > ρ ||a by 1.2% (0.019 g/cm3) and P ⊥a < P ||a by 3.3% (0.9% in the absolute value) or by 1.3% (0.024 g/cm3) and (0.92%), respectively, for the same graphite with high-temperature pitch. The capabilities of mercury porosimetry in the study of the porous structure of graphites and other carbon materials are demonstrated.
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References
Chalykh, E.F., Tekhnologiya uglegrafitovykh materialov (Coal–Graphite Material Technology), Moscow: Metallurgizdat, 1963.
Proc. Fourth Conf. on Carbon, Oxford, 1960.
Chalykh, E.F., Tekhnologiya i oborudovanie elektrodnykh i elektrougol’nykh predpriyatii (Technology and Equipment of Electrode and Electric Carbon Plants), Moscow: Metallurgiya, 1972.
Svoistva konstruktsionnykh materialov na osnove ugleroda: Spravochnik (Properties of Construction Materials Based on Carbon: A Handbook), Sosedov, V.P, Ed., Moscow: Metallurgiya, 1975.
Rogailin, M.I. and Chalykh, E.F., Spravochnik po uglegrafitovym materialam (Handbook on Coal–Graphite Materials), Moscow: Khimiya, 1974.
Marmer, E.N., @Uglegrafitovye materialy (spravochnik)@ (Coal–Graphite Materials: A Handbook), Moscow: Metallurgiya, 1973.
Vyatkin, S.E., Deev, A.N., Nagornyi, V.G., et al., Yadernyi grafit (Nuclear Graphite), Moscow: Atomizdat, 1967.
Butyrin, G.M., Bakman, A.S., and Demin, A.V., Abstracts of Papers, 23rd Bienn. Conf. on Carbon, Penn State, 1997. vol. 2, p. 218.
Butyrin, G.M., Vysokoporistye uglerodnye materialy (Highly Porous Carbon Materials), Moscow: Khimiya, 1976.
Butyrin, G.M., Zimina, L.A., Lushnikov, G.A., et al., Khim. Tverd. Topl. (Moscow), 1979. no. 6, p. 124.
Butyrin, G.M., Demin, A.V., Kosinskii, K.A., et al., Konstruktsionnye materialy na osnove ugleroda (Construction Materials Based on Carbon), Moscow: Metallurgiya, 1975. no. 10, p. 169.
Zimina, L.A. and Butyrin, G.M., Tsvetn. Met., 1978. no. 8, p. 54.
Chernyavets, A.N., Butyrin, G.M., and Mironov, I.A., Tsvetn. Met., 2000. no. 4, p. 107.
Butyrin, G.M. and Zimina, L.A., Tsvetn. Met., 1981. no. 4, p. 52.
Deev, A.N., Shestopal, N.P., Butyugin, V.K., et al., in Konstruktsionnye materialy na osnove grafita (Construction Materials Based on Graphite), Moscow: Metallurgiya, 1969. no. 4, p. 15.
Butyrin, G.M., Rogailin, M.I., and Chalykh, E.F., Khim. Tverd. Topl. (Moscow), 1971. no. 1, p. 131.
Rogailin, M.I., Butyrin, G.M., and Chalych, E.F., Proc. Int. Symp. IUPAC Pore Structure and Properties of Materials, Prague: Academia, 1974. part 3, p. A-103.
Lobastov, N.A., Deev, A.N., and Bagrov, G.N., in Konstruktsionnye materialy na osnove ugleroda (Construction Materials Based on Carbon), Moscow: Metallurgiya, no. 8, p. 37.
Tolkovyi terminologicheskii slovar’. Uglerodnye materialy (Terminological Dictionary: Carbon Materials), Kotosonov, A.S, Ed., Moscow: FGUP NIIgrafit, 2010.
Pekal’n, T.N., Virgil’ev, Yu.S., and Mikhin, Yu.I., in Konstruktsionnye materialy na osnove grafita (Construction Materials Based on Graphite), Moscow: Metallurgiya, 1967. no. 3, p. 11.
Tyrina, L.Ya., Nikolaev, A.I., Sigarev, A.M., et al., in Konstruktsionnye materialy na osnove grafita (Construction Materials Based on Graphite), Moscow: Metallurgiya, 1967. no. 3, p. 20.
Lobastov, N.A., Deev, A.N., and Bagrov, G.N., in Konstruktsionnye materialy na osnove grafita. Sb. ¹ 5 (TRANSLATION), Moscow: Metallurgiya, 1970. p. 27.
Lobastov, N.A. and Avdeenko, M.A., in Konstruktsionnye materialy na osnove ugleroda (Construction Materials Based on Carbon), Moscow: Metallurgiya, 1983. no. 17, p. 42.
Butyrin, G.M., Elektronnaya Tekhnika. Seriya “Materialy” (Electronic Technology: Materials Series) Kaluga: NIIMET, 1975. no. 7, p. 123.
Bubnenkov, I.A., Shevyakov, V.P., Shipkov, N.N., et al., Tsvetn. Met., 1992. no. 7, p. 37.
Bubnenkov, I.A., Shevyakov, V.P., Shipkov, N.N., et al., Tsvetn. Met., 1995. no. 12, p. 34.
Ostrovskaya, T.A., Butyrin, G.M., Kharitonov, A.V., et al., in Razrabotka i issledovanie konstruktsionnykh uglerodnykh materialov (Development and Characterization of Carbon Construction Materials), Moscow: Metallurgiya, 1975. p. 101.
Vargaftik, N.B., Spravochnik po teplofizicheskim svoistvam gazov i zhidkostei (Handbook on the Thermophysical Properties of Gases and Liquids), Moscow: Nauka, 1972.
Butyrin, G.M., Polozhikhin, A.I., Zimina, L.A., et al., in Uglegrafitovye materialy (Coal–Graphite Materials), Moscow: NIIgrafit, 1991. p. 138.
Butyrin, G.M., Demin, A.V., and Rogailin, M.I., Proc. Eur. Conf. Spacecraft Structures, Materials, and Mechanical Testing, Noordwijk, 2000 (ESA SP-468, March 2001), p. 541.
Washburn, E.W., Proc. N.A.S. Physics, 1921. vol. 7, p. 115.
Gregg, S. and Sing, K., Adsorption, Surface Area and Porosity, London: Academic, 1967.
Rogailin, M.I., Goryuchie gazy. Tr. IGI (Combustible Gases: Proc. IGI), Moscow: Izd. Akad. Nauk SSSR, 1962. no. 18, p. 54.
Chemistry and Physics of Carbon, Walker, P.L., Jr., Ed., New York: Marcel Dekker, 1965.
Butyrin, G.M., Metodika opredeleniya koeffitsienta gazopronitsaemosti uglerodnykh materialov (Procedure for the Determination of the Gas Permeability Coefficients of Carbon Materials), MI 4807-129-86, Moscow: GUP NIIgrafit, 1986.
Semenov, M.E. and Fedoseev, S.D., Konstruktsionnye materialy na osnove grafita (Construction Materials Based on Graphite), Moscow: Metallurgiya, 1969. no. 4, p. 76.
Kotosonova, V.Ya. and Lushnikov, G.A., Konstruktsionnye materialy na osnove grafita (Construction Materials Based on Graphite), Moscow: Metallurgiya, 1970. no. 5, p. 198.
Bagrov, G.N., Avdeenko, M.A., and Gilyazetdinova, V.S., Konstruktsionnye materialy na osnove grafita (Construction Materials Based on Graphite), Moscow: Metallurgiya, 1967. no. 3, p. 191.
Rogachev, S.G., Averina, M.V., Tsarev, V.Ya., et al., Konstruktsionnye materialy na osnove grafita (Construction Materials Based on Graphite), Moscow: Metallurgiya, 1971. no. 6, p. 28.
Kulikov, Yu.G., Avdeenko, M.A., and Lobastov, N.A., Konstruktsionnye materialy na osnove ugleroda (Construction Materials Based on Carbon), Moscow: Metallurgiya, 1975. no. 10, p. 6.
Lushnikov, G.A., Anufriev, Yu.P., and Kuzina, V.I., Konstruktsionnye materialy na osnove ugleroda (Construction Materials Based on Carbon), Moscow: Metallurgiya, 1976. no. 11, p. 110.
Lutkov, A.I., Dymov, B.K., and Volga, V.I., Konstruktsionnye materialy na osnove grafita (Construction Materials Based on Graphite), Moscow: Metallurgiya, 1969. no. 4, p. 59.
Levintovich, I.Ya., Kotosonov, A.S., and Butyrin, G.M., Neorgan. Mater., 1991. vol. 27, no. 12, p. 2546.
Vinokurov, Yu.N., Rogailin, M.I., and Butyrin, G.M., Khim. Tverd. Topl. (Moscow), 1981. no. 6, p. 134.
Rogailin, M.I., Kovalevskii, N.N., Farberov, I.L., and Butyrin, G.M., Khim. Tverd. Topl. (Moscow), 1972. no. 4, p. 132.
Ford, A.R., Morganite Carbon Ltd., Carbon and Its Uses, 1968. no. 12, p. 4.
Barabanov, V.N., Anufriev, Yu.P., and Dergunov, N.N., Konstruktsionnye materialy na osnove grafita (Construction Materials Based on Graphite), Moscow: Metallurgiya, 1971. no. 6, p. 35.
Lukina, E.Yu., Dymov, B.K., Demin, A.V., et al., Konstruktsionnye materialy na osnove grafita (Construction Materials Based on Graphite), Moscow: Metallurgiya, 1969. no. 4, p. 55.
Dymov, B.K., Lutkov, A.I., Volga, V.I., et al., Konstruktsionnye materialy na osnove grafita (Construction Materials Based on Graphite), Moscow: Metallurgiya, 1971. no. 6, p. 45.
Spravochnaya kniga korrektora i redaktora (Handbook of a Corrector and Editor), Mil’chin, A.E, Ed., Moscow: Kniga, 1974.
Strelov, K.K., Teoreticheskie osnovy tekhnologii ogneupornykh materialov (Theoretical Fundamentals of Refractory Materials Technology), Moscow: Metallurgiya, 1985.
Khakimova, D.K., Krasil’shchikova, A.G., Kovalenko, V.V., et al., in Uglerodnye materialy (Carbon Materials), Moscow: Metallurgiya, 1989. p. 80.
Barabanov, V.N., Belov, G.V., Dmitriev, I.A., et al., in Struktura i svoistva uglerodnykh materialov (Structure and Properties of Carbon Materials), Moscow: Metallurgiya, 1984. p. 37.
Novak, Yu.V., Kulikov, Yu.G., and Matyushchenko, G.N., Konstruktsionnye materialy na osnove ugleroda (Construction Materials Based on Carbon), Moscow: Metallurgiya, 1978. no. 13, p. 32.
Sosedov, V.P., Matyushchenko, G.N., and Avdeenko, M.A., in Tam zhe. Sb. ¹ 10 (TRANSLATION), Moscow: Metallurgiya, 1975. no. 10, p. 42.
Lutkov, A.I., Vyatkin, S.E., Dymov, B.K., et al., in Konstruktsionnye materialy na osnove ugleroda (Construction Materials Based on Carbon), Moscow: Metallurgiya, 1966. p. 88.
Bakman, A.S., Butyrin, G.M., and Shipkov, N.N., Tsvetn. Met., 1990. no. 4, p. 61.
Virgil’ev, Yu.S., Lyshov, L.L., and Pechik, V.K., Khim. Tverd. Topl. (Moscow), 1989. no. 4, p. 126.
Lutkov, A.I., Mikhailov, V.N., and Lavrukhin, P.F., Konstruktsionnye materialy na osnove ugleroda (Construction Materials Based on Carbon), Moscow: Metallurgiya, 1977. no. 12, p. 64.
Zinchenko, L.A., Dmitriev, I.A., and Buchnev, L.M., Uglerodnye konstruktsionnye materialy (Carbon Construction Materials), Moscow: Metallurgiya, 1984. p. 92.
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Original Russian Text © G.M. Butyrin, 2015, published in Khimiya Tverdogo Topliva, 2015, No. 5, pp. 40–53.
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Butyrin, G.M. Density, porous structure, and gas-dynamic characteristics of finely grained graphites (a review). Solid Fuel Chem. 49, 304–318 (2015). https://doi.org/10.3103/S0361521915050055
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DOI: https://doi.org/10.3103/S0361521915050055