Skip to main content
Log in

Adsorption of phenol by carbon sorbents based on oxidized coals

  • Published:
Solid Fuel Chemistry Aims and scope Submit manuscript

Abstract

The adsorption of phenol by carbon sorbents obtained by the carbonization (800°C, 1 h) of coals of different ranks in the presence of potassium hydroxide, which was introduced by mechanochemical treatment at a KOH/coal weight ratio of 1.0 g/g, was studied. The specific surface areas and micropore volumes of the obtained samples varied within the limits of 900–1400 m2 and 0.26–0.47 cm3/g, respectively. The kinetics of phenol adsorption from solutions with an initial phenol concentration of 0.1–3.0 mg/mL at 20°C was studied. The effectiveness of the adsorption of phenol, the order of reaction, and the rate-limiting stage were determined.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. Isaeva, L.N., Tamarkina, Yu.V., Bovan, D.V., and Kucherenko, V.A., J. Siberian Federal Univ. Chem., 2009, no. 2, p. 25.

    Google Scholar 

  2. Isaeva, L.N., Simonova, V.V., Tamarkina, Yu.V., et al., Khim. Tekhnol., 2009, no. 12 (144), p. 122.

    Google Scholar 

  3. Lur’e, Yu.Yu. and Rybnikova, A.I., Khimicheskii analiz proizvodstv stochnykh vod (Chemical Analysis of Industrial Wastewater), Moscow: Khimiya, 1974.

    Google Scholar 

  4. Koganovskii, A.M., Klimenko, N.A., Levchenko, T.M., and Roda, I.G., Adsorbtsiya organicheskikh veshchestv iz vody (Adsorption of Organic Substances from Water), Leningrad: Khimiya, 1990.

    Google Scholar 

  5. Sing, K.S.W., Everett, D.H., Haul, R.A.W., et al., Pure Appl. Chem., 1985, vol. 57, no. 4, p. 603.

    Article  CAS  Google Scholar 

  6. Brunauer, S., Deming, L.S., Deming, W.S., and Teller, E., J. Am. Chem. Soc., 1940, no. 62, p. 1723.

    Google Scholar 

  7. Gregg, S. and Sink, K., Adsorption, Surface Area, and Porosity, New York: Academic, 1982.

    Google Scholar 

  8. Koganovskii, A.M., Levchenko, T.M., and Kirichenko, V.A., Adsorbtsiya rastvorennykh veshchestv (Adsorption of Dissolved Substances), Kiev: Naukova Dumka, 1977.

    Google Scholar 

  9. Frolov, Yu.G., Kurs kolloidnoi khimii. Poverkhnostnye yavleniya i dispersnye sistemy (Course in Colloid Chemistry: Surface Phenomena and Disperse Systems), Moscow: OOO Izdat. Dom Al’yans, 2009.

    Google Scholar 

  10. Karnaukhov, A.P., Adsorbtsiya. Tekstura poristykh i dispersnykh materialov (Adsorption: The Texture of Porous and Dispersed Materials), Novosibirsk: Nauka, 1999.

    Google Scholar 

  11. Smirnov, A.D., Sorbtsionnaya ochistka vody (Sorption Purification of Water), Leningrad: Khimiya, 1982.

    Google Scholar 

  12. Adsorption from Solution on the Solid/Liquid Interface, Parfitt, G. and Rochester, C., Eds., London: Academic, 1983.

    Google Scholar 

  13. Kel’tsev, N.V., Osnovy adsorbtsionnoi tekhniki (Basics of Adsorption Instrumentation), Moscow: Khimiya, 1976.

    Google Scholar 

  14. Kennedy, J.L., Vijaya, J.J., Kayalvizhi, K., and Sekaran, G., Chem. Eng. J., 2007, vol. 132, p. 279.

    Article  CAS  Google Scholar 

  15. Liu, Q.-S., Zheng, T., Wang, P., Jiang, J.-P., and Li, N., Chem. Eng. J., 2010, vol. 157, p. D. 348.

    Article  Google Scholar 

  16. Lorenc-Grabowska, E., Gryglewicz, G., and Diez, M.A., Fuel, 2012. http://dx.doi.org/10.1016/j.fuel.2012.11.056.

    Google Scholar 

  17. Fierro, V., Torne-Fernandez, V., Vontane, D., and Celzard, A., Micropor Mesopor Mater, 2008, vol. 111, p. D. 276.

    Article  Google Scholar 

  18. Stellacci, P., Liberti, L., Notarnicola, M., and Bishop, P.L., Chem. Eng. J., 2009, vol. 149, p. 11.

    Article  CAS  Google Scholar 

  19. Soldatkina, L.M. and Sagaidak, E.V., Khim. Tekhnol. Vody, 2010, vol. 32, no. 4, p. 388.

    CAS  Google Scholar 

  20. Koganovskii, A.M., Klimenko, N.A., Levchenko, T.M., et al., Ochistka i ispol’zovanie stochnykh vod v promyshlennom snabzhenii (Purification and Utilization of Wastewater in Industrial Water Supply), Moscow: Khimiya, 1983.

    Google Scholar 

  21. Rudenko, V.M., Tarasevich, Yu.I., and Ivanova, Z.G., Khim. Tekhnol. Vody, 1993, vol. 15, nos. 11–12, p. 715.

    CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to N. I. Fedorova.

Additional information

Original Russian Text © N.I. Fedorova, T.S. Manina, Z.R. Ismagilov, 2015, published in Khimiya Tverdogo Topliva, 2015, No. 1, pp. 33–38.

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Fedorova, N.I., Manina, T.S. & Ismagilov, Z.R. Adsorption of phenol by carbon sorbents based on oxidized coals. Solid Fuel Chem. 49, 30–35 (2015). https://doi.org/10.3103/S0361521915010048

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.3103/S0361521915010048

Keywords

Navigation