Abstract
A graphene coating deposited onto a copper substrate was irradiated with helium and argon ions with an energy of 100 keV. The effect produced by the radiation fluence on the structure of a graphene coating was studied by Raman light scattering. The processes of defect formation in a graphene coating was modeled at different ion irradiation parameters by the Monte Carlo method in the approximation of binary collisions. It has been shown that the transition to the displacement per atom parameter provides the possibility to compare defect formation processes in a two-dimensional target at different irradiation parameters. It is demonstrated in this study that the accumulation of point defects occurs in a graphene coating under irradiation until the displacement per atom parameter becomes close to \(5\times 10^{-4}\), after which the defect domains are joined with further coating structure destruction at a displacement per atom parameter ranged within \(5\times 10^{-3}{-}10^{-2}\).
Similar content being viewed by others
REFERENCES
F. Banhart, J. Kotakoski, and A. V. Krasheninnikov, ACS Nano 5, 26 (2011).
M. Garcia-Hernandez and J. Coleman, 2D Mater. 3 (2016).
Y. Du, D. Li, L. Liu, and G. Gai, Polymers 10, 114 (2018).
L. Liu, M. Qing, Y. Wang, and S. Chen, J. Mater. Sci. Technol. 31, 599 (2015).
D. K. Minnebaev, Yu. V. Balakshin, A. V. Nazarov, I. D. Kharitonov, E. V. Zaitsev, A. D. Zabolotskiy, V. S. Chernysh, and A. A. Shemukhin, Nucl. Instrum. Methods Phys. Res., Sect. B 460, 189 (2019).
M. X. Navarro, R. R. Delgado, M. G. Lagally, G. L. Kulcinski, and J. F. Santarius, Fusion Sci. Technol. 72, 713 (2017).
L. Tapasztu, G. Dobrik, P. Nemes-Incze, G. Vertesy, P. Lambin, and L. P. Biru, Phys. Rev. B 78, 233407 (2008).
J. C. Meyer, C. Kisielowski, R. Erni, M. D. Rossell, M. F. Crommie, and A. Zettl, Nano Lett. 8, 3582 (2008).
M. H. Gass, U. Bangert, A. L. Bleloch, P. Wang, R. R. Nair, and A. K. Geim, Nat. Nanotechnol. 3, 676 (2008).
J.-H. Chen, W. G. Cullen, C. Jang, M. S. Fuhrer, and E. D. Williams, Phys. Rev. Lett. 102, 236805 (2009).
A. V. Krasheninnikov and K. Nordlund, J. Appl. Phys. 107, 071301 (2010).
O. Lehtinen, J. Kotakoski, et al., Phys. Rev. B 81, 153401 (2010).
Yu. V. Balakshin, A. A. Shemukhin, A. V. Nazarov, A. V. Kozhemiako, and V. S. Chernysh, Tech. Phys. 63, 1861 (2018).
J. F. Ziegler, M. D. Ziegler, and J. P. Biersack, Nucl. Instrum. Methods Phys. Res., Sect. B 268, 1818 (2010).
K. V. Karabeshkin, P. A. Karaseov, and A. I. Titov, Semiconductors 47, 242 (2013).
I. Calizo, I. Bejenari, M. Rahman, G. Liu, and A. A. Balandin, J. Appl. Phys. 106, 043509 (2009).
I. I. Kondrashov, M. G. Rybin, E. A. Obraztsova, and E. D. Obraztsova, Phys. Status Solidi B 256, 1800688 (2019).
M. Pawlyta, J. N. Rouzaud, and S. Duber, Carbon 84, 479 (2015).
G. Gawlik, P. Ciepielewski, and J. Baranowski, Nucl. Instrum. Methods Phys. Res., Sect. B 406, 683 (2017).
A. Eckmann et al., Nano Lett. 12, 3925 (2012).
A. Jorio et al., Phys. Status Solidi B 247, 2980 (2010).
G. Gawlik, P. Ciepielewski, J. Baranowski, and J. Jagielski, Surf. Coat. Tech. 306A, 119 (2016).
G. Gawlik, P. Ciepielewski, J. Baranowski, and J. Jagielski, Nucl. Instrum. Methods Phys. Res., Sect. B 408, 228 (2017).
G. Compagnini, F. Giannazzo, S. Sonde, V. Raineri, and E. Rimini, Carbon 47, 3201 (2009).
M. Tripathi, A. V. Markevich, R. Boettger, S. Facsko, E. Besley, J. Kotakoski, and T. Susi, ACS Nano 12, 4641 (2018).
M. Nastasi, J. W. Mayer, and Y. Wang, Ion Beam Analysis: Fundamentals and Applications (CRC, London, 2015).
Y. Yamamura and H. Tawara, NIFS–DATA 23 (1995).
Sputtering by Particle Bombardment, Ed. by R. Behrisch and K. Wittmaack (Springer, Berlin, 1981).
http://www.knowledgedoor.com/2/elements_ handbook/.
Yu. V. Balakshin, A. V. Kozhemiako, A. P. Evseev, D. K. Minnebaev, and E. M. Elsehly, Moscow Univ. Phys. Bull. 75, 218 (2020).
M. Lucchese et al., Carbon 48, 1592 (2010).
ACKNOWLEDGMENTS
This study was performed on the equipment of the Accelerating Complex of the Lomonosov Moscow State University.
Funding
This study was financially supported by the Russian Scientific Foundation (grant no. 20-72-10118).
Author information
Authors and Affiliations
Corresponding author
Ethics declarations
The authors declare that they have no conflicts of interest.
Additional information
Translated by E. Glushachenkova
About this article
Cite this article
Balakshin, Y.V., Minnebaev, D.K., Vorobyeva, E.A. et al. Stages of Defect Formation in a Graphene Coating on a Copper Substrate under Irradiation with Helium and Argon Ions. Moscow Univ. Phys. 77, 498–503 (2022). https://doi.org/10.3103/S0027134922030067
Received:
Revised:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.3103/S0027134922030067