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Uranyl Luminescence Quenching in the Presence of Organic Reagents Based on 2,2'-Bipyridyldicarboxylic Acid

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Abstract

The absorption and luminescence spectra and the luminescence decay kinetics of uranyl ions (UO22+) in the presence of organic reagents based on 2,2'-bipyridyldicarboxamides with various substituents have been studied. The quantum yields and luminescence lifetimes of uranyl nitrate hexahydrate and uranyl complexes with organic ligands in acetonitrile solutions have been determined. The mechanism of energy transfer in uranyl complexes is proposed.

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ACKNOWLEDGMENTS

This work was supported by Russian Science Foundation grant number 21-73-20138.

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Authors and Affiliations

  1. Department of General Physics, Faculty of Physics, Moscow State University, 119991, Moscow, Russia

    A. N. Kupaeva & S. V. Patsaeva

  2. Department of Organic Chemistry, Faculty of Chemistry, Moscow State University, 119991, Moscow, Russia

    A. V. Kharcheva & A. V. Ivanov

  3. Department of Radiochemistry, Faculty of Chemistry, Moscow State University, 119991, Moscow, Russia

    N. E. Borisova

Authors
  1. A. N. Kupaeva
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  2. A. V. Kharcheva
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  3. A. V. Ivanov
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  4. N. E. Borisova
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  5. S. V. Patsaeva
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Correspondence to A. N. Kupaeva or A. V. Kharcheva.

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Kupaeva, A.N., Kharcheva, A.V., Ivanov, A.V. et al. Uranyl Luminescence Quenching in the Presence of Organic Reagents Based on 2,2'-Bipyridyldicarboxylic Acid. Moscow Univ. Phys. 76 (Suppl 1), S13–S17 (2021). https://doi.org/10.3103/S0027134922010064

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