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Voltammetric Determination of Lead and Copper in Wine by Modified Glassy Carbon Electrode

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Abstract

This paper describes the determination of Pb and Cu with a Nafion-modified glassy carbon electrode and MnCo2O4 nanoparticles as working electrode for anodic stripping voltammetry. Pb and Cu were accumulated in HCl/KCl (0.1 mol dm–3) at a potential of–1.4 V (vs. Ag/AgCl electrode) for 480 s, followed by a linear sweep anodic stripping voltammetry (ASV) scan from–1.0 to +0.5 V. Under optimum conditions, the calibration curves were linear in the range of 0.01–8 and 0.01–5 mg dm–3 for Pb and Cu, respectively. Effect of sample dilution, accumulation time and potential were optimized. A study of interfering substances was performed. A significant increase in current was obtained at the modified electrode in comparison with the bare glassy carbon electrode. The modified electrode was successfully applied for determination of Pb and Cu in wine samples after a simple preparation procedure. Pb and Cu content in wine was used for estimation of the target hazard quotient (THQ) values for minimal and maximal levels of the metals.

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Acknowledgments

This work was performed within the framework supported by the Ministry of Education, Science and Technological Development of the Republic of Serbia. Contract number: 451- 03-68/2020-14/200168.

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Authors and Affiliations

  1. Department of Pharmacy, Faculty of Medicine, University of Banja Luka, Save Mrkalja 14, 78000, Banja Luka, Bosnien und Herzegowina

    Vesna Antunović

  2. Republic Institute for the Protection of Cultural Monuments of Serbia, Radoslava Grujića 11, 11000, Belgrade, Serbia

    Tatjana Tripković

  3. Department of Analytical Chemistry, University of Belgrade–Faculty of Chemistry, Studentski trg 12-16, 11000, Belgrade, Serbia

    Biljana Tomašević, Rada Baošić & Aleksandar Lolić

  4. Department of Chemistry, Faculty of Natural Sciences and Mathematics, University of Banja Luka, Mladena Stojanovic´a 2, 78000, Banja Luka, Bosnien und Herzegowina

    Dijana Jelić

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  1. Vesna Antunović
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  2. Tatjana Tripković
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  3. Biljana Tomašević
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  4. Rada Baošić
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  6. Aleksandar Lolić
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Correspondence to Aleksandar Lolić.

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Antunović, V., Tripković, T., Tomašević, B. et al. Voltammetric Determination of Lead and Copper in Wine by Modified Glassy Carbon Electrode. ANAL. SCI. 37, 353–358 (2021). https://doi.org/10.2116/analsci.20P302

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  • DOI: https://doi.org/10.2116/analsci.20P302

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