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Phosphomethylated Polyethyleneimine-immobilized Chelating Resin: Role of Phosphomethylation Rate on Solid-Phase Extraction of Trace Elements

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Abstract

Chelating resins immobilizing phosphomethylated polyethyleneimine (PM-PEI) with different phosphomethylation (PM) rates were prepared by using different amounts of both phosphonic acid and paraformaldehyde in the phosphomethylation of PEI immobilized on a methacrylate resin as a base resin. The extraction of many elements improved with increasing PM rate; REEs, Be, Fe, Mo, Ti, and V were quantitatively extracted at pH 2. The elution of the elements tended to become difficult with increasing PM rate. When a PM-PEI resin with a PM rate of 0.26 was used, REEs and Be could be eluted using 0.2 mol L−1 EDTA solution adjusted to a pH of 7 and 3 mol L−1 nitric acid, respectively, although the elution of Fe, Mo, Ti, and V was insufficient. The PM-PEI resin could be reused at least 10 times to recover REEs and Be without the influence of any other elements. The PM-PEI resin could be applied to a recovery test using artificial seawater spiked with REEs, except for Sc, Tm, Yb, and Lu, and the separation of the REEs in NIST SRM 1515 Apple Leaves.

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Acknowledgments

The authors are grateful to Ms. Eri Koori for her support for elemental analysis. This work was partly supported by a Grantin-Aid for Scientific Research from the Japan Society for the Promotion of Science (No. 16K00611).

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Authors and Affiliations

  1. Graduate School of Science and Engineering for Research, University of Toyama, Toyama, 930-8555, Japan

    Shigehiro Kagaya, Ryo Ikeda, Takehiro Kajiwara, Makoto Gemmei-Ide & Yoshinori Inoue

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  1. Shigehiro Kagaya
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  2. Ryo Ikeda
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  3. Takehiro Kajiwara
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  4. Makoto Gemmei-Ide
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  5. Yoshinori Inoue
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Correspondence to Shigehiro Kagaya.

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Kagaya, S., Ikeda, R., Kajiwara, T. et al. Phosphomethylated Polyethyleneimine-immobilized Chelating Resin: Role of Phosphomethylation Rate on Solid-Phase Extraction of Trace Elements. ANAL. SCI. 35, 413–419 (2019). https://doi.org/10.2116/analsci.18P462

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  • DOI: https://doi.org/10.2116/analsci.18P462

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