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Selective Separation and Recovery of Pt(IV) from Pd(II) through an Imidazolium-ionic-liquid-based Supported Liquid Membrane

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Abstract

A supported liquid membrane (SLM) system for the selective separation of platinum(IV) from palladium(II) has been developed. The SLM was prepared using imidazolium-based IL 1-octy-3-methylimidazolium bis(trifluoromethanesulfonyl)- imide. The initial flux and separation factor of Pt(IV) from Pd(II) were found to significantly depend on the composition of the receiving solution. Based on the performance, a 0.1 mol dm-3 NaClO4 solution was selected as a suitable receiving solution. Membrane transport experiments showed that 93% of Pt(IV) can be selectively transported into the receiving solution, whereas most Pd(II) remains in the feed solution.

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Acknowledgments

This work was supported by a Grant-in-Aid for Scientific Research (No. JP16K06830) from the Ministry of Education, Science, Sports, and Culture of Japan and the Environment Research and Technology Development Fund (ERTDF, Grant

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Authors and Affiliations

  1. Department of Applied Chemistry, Graduate School of Engineering, Fukuoka, 819-0395, Japan

    Wataru Yoshida, Fukiko Kubota, Riho Kono & Masahiro Goto

  2. Center for Future Chemistry, Kyushu University, 744 Motooka, Fukuoka, 819-0395, Japan

    Masahiro Goto

Authors
  1. Wataru Yoshida
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  2. Fukiko Kubota
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  3. Riho Kono
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  4. Masahiro Goto
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Correspondence to Masahiro Goto.

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Yoshida, W., Kubota, F., Kono, R. et al. Selective Separation and Recovery of Pt(IV) from Pd(II) through an Imidazolium-ionic-liquid-based Supported Liquid Membrane. ANAL. SCI. 35, 343–346 (2019). https://doi.org/10.2116/analsci.18N020

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  • DOI: https://doi.org/10.2116/analsci.18N020

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