Skip to main content
SpringerLink
Log in

Towards Green Titration: Downscaling the Sequential Injection Analysis Lab-at-valve Titration System with the Stepwise Addition of a Titrant

  • Notes
  • Published:
Analytical Sciences Aims and scope Submit manuscript

Abstract

A downscaling in true titration based on a simple sequential injection analysis-lab-at-valve (SIA-LAV) has been proposed. A titrant solution was stepwise aspirated into a titration LAV chamber and a titration curve was obtained by monitoring the change in the solution color spectroscopically. This fully-automated SIA-LAV system required less volume of the sample/reagents, only a micro-liter scale, compared to the conventional method. The system was investigated with complexometric titration and acid-base titration. Application of the developed technique to some real samples has been demonstrated.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. IUPAC, “Compendium of Chemical Terminology (the “GoldBook”)”, ed. A. D. McNaught and A. Wilkinson, 2nd ed., 1997, Blackwell Scientific Publications, Oxford.

  2. M. da la Guardia and S. Garrigues, “Challenges in Green Analytical Chemistry”, 2011, Royal Society of Chemistry.

    Book  Google Scholar 

  3. M. de la Guardia and S. Garrigues, “Handbook of Green Analytical Chemistry” 2012, John Wiley & Sons, Ltd.

    Book  Google Scholar 

  4. A. U. Ramsing, J. Růžička, and E. H. Hansen, Anal. Chim. Acta, 1981, 729, 1.

    Article  Google Scholar 

  5. J. F. van Staden and H. du Plessis, Anal. Commun., 1997, 34, 147.

    Article  Google Scholar 

  6. S. K. Hartwell, W. Wongwilai, S. Grudpan, and S. Lapanantnoppakhun, Talanta, 2011, 84, 1396.

    Article  PubMed  Google Scholar 

  7. J. Jakmunee, L. Patimapornlert, S. Suteerapataranon, N. Lenghor, and K. Grudpan, Talanta, 2005, 65, 789.

    Article  CAS  PubMed  Google Scholar 

  8. H. Tanaka, P. K. Dasgupta, and J. Huang, Anal. Chem., 2000, 72, 4713.

    Article  CAS  PubMed  Google Scholar 

  9. L. A. Siqueira, I. S. Nunes, P. L. Almeida Junior, W. S. Lyra, R. A. N. Andrade, M. C. U. Araújo, L. F. Almeida, and R. A. C. Lima, Microchem. J., 2017, 133, 593.

    Article  CAS  Google Scholar 

  10. M. K. Sasaki, D. L. Rocha, F. R. P. Rocha, and E. A. G. Zagatto, Anal. Chim. Acta, 2016, 902, 123.

    Article  CAS  PubMed  Google Scholar 

  11. K. Ponhong, S. K. Hartwell, and K. Grudpan, Talanta, 2011, 85, 804.

    Article  CAS  PubMed  Google Scholar 

  12. R. Burakham, J. Jakmunee, and K. Grudpan, Anal. Sci., 2006, 22, 137.

    Article  CAS  PubMed  Google Scholar 

  13. R. Burakham, S. Lapanantnoppakhun, J. Jakmunee, and K. Grudpan, Talanta, 2005, 68, 416.

    Article  CAS  PubMed  Google Scholar 

  14. S. K. Hartwell, B. Srisawang, P. Kongtawelert, J. Jakmunee, and K. Grudpan, Talanta, 2005, 66, 521.

    Article  CAS  PubMed  Google Scholar 

  15. APHA, “Standard Methodsfor the Examination of Water and Wastewater”, 1995, 19th ed., American Public Health Association, Washington, D.C.

    Google Scholar 

Download references

Acknowledgments

The authors acknowledge the Commision on Higher Education for the supports to S. Chanpaka and TRF Distinguished Research Professor Award Grant to K. Grudpan. P. Paengnakorn was supported by Chiang Mai University through Center of Excellence for Innovation in Analytical Science and Technology.

Author information

Authors and Affiliations

  1. Science and Technology Research Institute, Chiang Mai University, Chiang Mai, 50200, Thailand

    Pathinan Paengnakorn, Wasin Wongwilai & Kate Grudpan

  2. Biomedical Engineering Institute, Chiang Mai University, Chiang Mai, 50200, Thailand

    Pathinan Paengnakorn

  3. Department of Chemistry, Faculty of Science, Chiang Mai University, Chiang Mai, 50200, Thailand

    Saiphon Chanpaka, Kanchana Watla-Iad & Kate Grudpan

  4. Presently at Department of General Science, Faculty of Science and Engineering, Kasetsart University Chalermphrakiat Sakon Nakhon Province Campus, Sakhon Nakhon, 47000, Thailand

    Saiphon Chanpaka

  5. Presently at School of Science, Mae Fah Luang University, Chiang Rai, 57100, Thailand

    Kanchana Watla-Iad

  6. Science and Technology Research Institute, Chiang Mai University, Chiang Mai, 50200, Thailand

    Wasin Wongwilai

Authors
  1. Pathinan Paengnakorn
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Saiphon Chanpaka
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Kanchana Watla-Iad
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Wasin Wongwilai
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. Kate Grudpan
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Kate Grudpan.

Electronic supplementary material

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Paengnakorn, P., Chanpaka, S., Watla-Iad, K. et al. Towards Green Titration: Downscaling the Sequential Injection Analysis Lab-at-valve Titration System with the Stepwise Addition of a Titrant. ANAL. SCI. 35, 219–221 (2019). https://doi.org/10.2116/analsci.18N018

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.2116/analsci.18N018

Keywords

Search

Navigation