Abstract
This work presents a study of the chemical structure, morphology, electromagnetic absorption and electric conductivity of thin films. The electrochemical synthesis of polypyrrole/surfactant (PPy/SDS) films doped with iodine is carried out by glow discharge plasma in aqueous solution, at different reaction times. The morphology shows agglomerations of particles dispersed in the surface. Infrared spectroscopic analysis shows absorption on the wavenumbers 2915, 2362 and 2082 cm-1 corresponding to chemical groups C-H, C=O and R/N=C=S, respectively. The electromagnetic absorption had higher response sensitivity between 340 to 800 nm in the visible region, and the electric conductivity of samples oscillated between 5.0×10−6 and 2.0×10−5 S/cm. The thickness films significantly increased when doping with iodine, reaching values up to 50 μm.
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Hemant K. Chitte, Narendra V. Bht, Vasant E. Walunj and N. Shinde 2011 Journal of Sensor Technology 1 47–56.
Maria Omastova, Miroslava Trchova, Jana Kovarova and Jaroslav Stejskal 2003 Synthetic Metal 138 447–455.
J. Ouyang and Y. Li 1997 Polymer 38 3997.
S.P. Armes 1987 Synthetic Metal 20 365.
T. F. Otero and J. M. García de Otazo, “Polypyrrole oxidation: Kinetic coefficients, activation energy and conformational energy,” Synth. Met., vol. 159, no. 7–8, pp. 681–688, Apr. 2009.
A. Fridman, Plasma Chemistry. Cambridge University Press, 2008.
M. Shen and A. T. Bell, Plasma Polymerization, vol. 108, no. 5. Elsevier Science, 1979.
DeArmitt C. and Armes S.P. Langmuir 9 652–654.
J. Y. Lee, D. Y. Kim and C. Y. Kim 1995 Synthetic Metal 74 103.
Y. Kudoh 1996 Synthetic Metal 79 17.
D. Kumar and R. Sharma, “Advances in conductive polymers”. European polumer journal, vol. 34, no. 8, pp. 1053–1060, 1998.
M. Castillo-Ortega, I. Santos-Sauceda, J. Encinas, D. Rodriguez-Felix, T. delCastillo-Castro, F. Rodriguez-Felix, J. Valenzuela-García, L. Quiroz-Castillo, and P. Herrera-Franco, “Adsorption and desorption of a gold-iodide complex onto cellulose acetate membrane coated with polyaniline or polypyrrole: a comparative study”. Journal of materials science, vol. 46, no. 23, pp. 7466{7474, 2011.
Sirilak A., KAwee S., Sarintorn L.,” Effect of surfactant o conductivity of Poly(pyrrole-co-formyl pyrrole) via Emulsion Polymerization”Journal f Metals and minerals, Vol.24 No.2 pp. 29–34, 2014.
C. I. Montoya, “Effect of the incorporation on the electrical propierities of coatings of polypyrrole deposited on stainless steel,” Sci. Tech. Sci. Tech. Año XIII, vol. 36, no. 36, pp. 19–24, 2007
G. Maia, M. Roberto Torresi, A. Edson Ticianelli and C. J. Phys. Chem. 100 15910–15916.
Saravana Kumar, A., Hameed Hussain, J., Expanding the pass percentage in semester examination, International Journal of Pure and Applied Mathematics, V116, I-15 Special Issue, PP-45–48, 2017
R. M Silverstein, G.C. Bassler and T.C. Morill, “Spectroscopic identification of organic compounds” D Sawicky (Ed.), 5th ed, Wiley New York, 1991.
N. Suhada, M. Tahiruddin and R. Daik, “Synthesis and characterization of anionic surfactants doped polypyrrole”Scholars Research Library Der Pharma Chemica, 2015, 7(6):159–162.
R. Dorf, R. C. Dorf, and J. A. Svoboda, “Electric circuits: introduction to analysis and desing”. Marcombo, 2000.
Archana S and Jaya Shanthi R., “Shynthesi and characterization of Poly(p-phenilenediamine) in the presence of sodium dodecyl sulfate”, Research Journal of Chemical Sciences. Vol.4(2), 60–67, 2014.
L.M Gomez,G.J: Cruz, M.G. Olayo, M. Gonzalez-Torres, F. Gonzalez-Salgado, O.G. LopezGarcia “Analysis of crosslinking in polypyrrole particles synthesized by plasma”. Polym. Bull. Springer, 2014.
F. Gonzalez-Salgado, M.G. Olayo, G. Garcia-Rosales L.M Gomez, M. Gonzalez-Torres, G.J Cruz, “Electromagnetic absorption and conductivity of organometallic TiOx-Py plasma compounds”. Polym. Bull. Springer, 2016.
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de la Cruz, T.H., Tenorio, C.H., Castañeda, M.V. et al. Effects produced by sodium dodecyl sulfate (SDS) surfactant on polypyrrole film electrochemically synthesized and doped with glow discharge plasma. MRS Advances 3, 3839–3846 (2018). https://doi.org/10.1557/adv.2018.611
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DOI: https://doi.org/10.1557/adv.2018.611