Abstract
This study investigates the adsorption efficiency of goethite nanostructured powder for the simultaneous removal of cobalt and nickel ions. The nanostructured powder sample was synthesized via a chemical precipitation technique and characterized using SEM, FTIR-ATR and XRD techniques. From batch adsorption studies, maximum absorption for Co(II) and Ni(II) ions occurred at an equilibrium contact time of 80 min, with an adsorbent mass of 0.1 g, and at pH=7. Co(II) ions showed greater affinity to the nanoparticles as compared to Ni(II). The maximum quantities adsorbed were recorded as 148.5 mg/g for Co(II) and 110.6 mg/g for Ni(II) ions. The best isotherm model fit for both metal ions was the Freundlich model indicating heterogeneity of the surface binding sites. The pseudo-second order kinetic model was the best-fit model: an indication of a strong chemical adsorption between the adsorbent surface and metal ions. The findings show that the goethite nanostructured powder is a very effective adsorbent material and prominent candidate for the simultaneous removal of cobalt and nickel ions from water.
Similar content being viewed by others
References
H. Parham, B. Zargar and R. Shiralipour., (2012) J. Hazard. Mater 205–206, 94–100.
F. Sandra, B. Meredith, C. Bin, F. B. Jillian and Z. Hengzhong, (2012) RSC Adv. 2, 6768–6772.
R. G. Pushpa, A.G. Annaselvi and P. Subramaniam, (2013) Int. J. Nanomater. Biostruct. 3, 26–30.
S. D. Mamadou, S. D. Jeremiah, S. Nora, S. Anita and S. Richard, Nanotechnology applications for clean water, eds. Nora S., Mamadou D., Jeremiah D., Anita S. and Richard S., (William Andrew Inc, USA, 2009), pp 585–587.
K. T. Dhermendra, J. Behari and S. Prasenjit, (2008)World Appl. Sci. J. 3, 417–433
M. C. Kimberly, L.U. Yunfeng, Z. Tonghua, Z. Jingjing, M. Gary and J. Vijay: Nanotechnology applications for clean water, eds. Savage N., Mamadou D., Jeremiah D., Anita S. and Richard S., (William Andrew Inc., USA, 2009), pp. 350.
J. Lodhia, G. Mandarano, J. Feris, S. F. Cowell, P. MacCallum (2009). Biomed. Imag. Intervention J., 6.
M. G. Sajuna and S. Mohanty (2010). Int. J. of Eng. Sci. Tech., 2, 1–12.
I. Kazuharu and Y. Tsutomu (2002). Trans., 43, 2097–2103
G. Françoise, R. Philippe, L. François, R. Céline and C. Egle (2008). J. Phys. Chem. Solids, 10, 1016–1043.
A. Mariana, E. S. Elsa, and H. R. Elsa (2008). Am. Mineral., 93, 584–590.
Y. Hexiong, L. Ren, T. D. Robert and C. Gelu (2006). Acta Cryst. 62, 250–252
R. M. Cornell and U. Schwertmann (2003). The Iron Oxides: Structure, Properties, Reactions, Occurrences and Uses. WILEY-VCH Verlag GmbH & Co., KGaA, Weinheim, pp. 141–143, 253–296.
M. Mamata, K. Rout, S. K. Gupta, P. Singh, S. Anand, and B. K. Mishra (2010). J Nanopart Res, 12, 681–686.
H. Liu, T. Chen, L. Ray, and H. Frost (2013). Chemosphere xxx xxx–xxx.
H. Hala and H. Yousef (2012). Intl J. Eng. Sci. Technol., 4, 3018–3028
Yen-Hua Chen, Fu-An Li, (2010). J. Colloid Interface Sci., 347, 277–281
V. D. Nguyen, J. Kynicky, P. Ambrozova and V. Adam (2017). Mater., 10, 783
M. Mohapatra, L. Mohapatra, P. Singh, S. Anand and B.K. Mishra (2010). Intl. J. Eng. Sci. Technol., 8, 89–103
P. Apostoli, R. Cornelis, J. Duffus and D. Lison D: (2006) WHO 234, 70–158.
G. H. Lee, S. H. Kim, B. J. Choi and S. H. Huh. (2004) J. Korean Phys. Soc. 45, 1019–1024.
S. Brunauer, P. H. Emmett, E. Teller, (1938). J. Am. Chem. Soc. 60 (2), 309– 319.Ceram. Soc. 83, 1649–1657.
G. Vijayakumar, R. Tamilarasan, and M. Dharmendirakumar (2012). J. Mater. Environ. Sci., 3, 157–170.
E. Yagmur, M. Ozmak, Z. Aktas, (2008) Fuel 87 3278–3285.
M. Mohapatra and S. Anand, (2010) Int. J. Eng. Sci. Tech. 2 127–146.
Y. Zhao, F. Liu, X. Qin, (2017) Chemosphere 180 373–378
H. A. Beyene and A.M. Alemayehu, (2013) Bull. Chem. Soc. Ethiop. 27 35–47
K. Maguie, N. Nsami, K. Daouda, C. Randy, K. Mbadcam, (2017). IRA Int. J. Appl. Sci. 8(1), 18–30.
S. E. Agarry and M. O. Aremu (2012). Br. Biotechnol J. 2(1): 26–4
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Nangah, C.R., Merlain, T.G., Nsami, N.J. et al. Synthesis and Characterization of Goethite Nanostructured powder: Application in the Simultaneous Removal of Co(II) and Ni(II) Ions from Aqueous Solution. MRS Advances 3, 2675–2687 (2018). https://doi.org/10.1557/adv.2018.527
Published:
Issue Date:
DOI: https://doi.org/10.1557/adv.2018.527