Abstract
Nuclear energy is one option to meet rising electricity demands, although one concern of this technology is the proper capture and storage of radioisotopes produced during fission processes. One of the more difficult radioisotopes is 129I due to its volatility and poor solubility in traditional waste forms such as borosilicate glass. Iodosodalite has been previously proposed as a viable candidate to immobilize iodine due to high iodine loading and good chemical durability. Iodosodalite was traditionally synthesized using solid state and hydrothermal techniques, but this paper discusses an aqueous synthesis approach to optimize and maximize the iodosodalite yield. Products were pressed into pellets and fired with glass binders. Chemical durability and iodine retention results are included.
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B.J. Riley, J.D. Vienna, D.M. Strachan, J.S. McCloy and J.L. Jerden Jr, J. Nucl. Mater. 470, 307 (2016).
B.J. Riley, M.J. Schweiger, D.-S. Kim, W.W. Lukens Jr, B.D. Williams, C. Iovin, C.P. Rodriguez, N.R. Overman, M.E. Bowden, D.R. Dixon, J.V. Crum, J.S. McCloy and A.A. Kruger, J. Nucl. Mater. 452, 178 (2014).
S. Chong, J. Peterson, J. Nam, B. Riley and J. McCloy, J. Am. Ceram. Soc. 100, 2273 (2017).
C. Cao, S. Chong, L. Thirion, J.C. Mauro, J.S. McCloy and A. Goel, J. Mater. Chem. A 5, 14331 (2017).
T. Tomisaka and H.P. Eugster, Mineral. J. 5, 249 (1968).
N.C. Nielsen, H. Bildsøe, H.J. Jakobsen and P. Norby, Zeolites 11, 622 (1991).
A. Stein, G.A. Ozin, P.M. Macdonald, G.D. Stucky and R. Jelinek, J. Amer. Chem. Soc. 114, 5171 (1992).
D. Strachan and H. Babad, Iodide and Iodate Sodalites for the Long-Term Storage of Iodine-129, Rockwell International-Rockwell Hanford Operations, Richland, WA, RHO-SA-83 (1979).
E. Vance, D. Agrawal, B. Scheetz, J. Pepin, S. Atkinson and W. White, Ceramic phases for immobilization of 129 I, Rockwell International Corp., Canoga Park, CA, DOE/ET/41900-9 (ESG-DOE-13354) (1981).
T. Dunn, K. Montgomery and C. Scarfe, Synthesis and Leaching Behavior of Iodosodalite: A Potential Radioiodine Host, Atomic Energy of Canada Ltd., Pinawa, MB, Canada, Technical Record TR-350 (1985).
H. Babad and D.M. Strachan, Method for immobilizing radioactive iodine, USPTO, US4229317 A (1980).
I. Bardez, L. Campayo, D. Rigaud, M. Chartier and A. Calvet in ATALANTE 2008, Montpellier, France, 2008, pp. O4_19.
W.C. Lepry, B.J. Riley, J.V. Crum, C.P. Rodriguez and D.A. Pierce, J. Nucl. Mater. 442, 350 (2013).
K.L. Konan, C. Peyratout, A. Smith, J.P. Bonnet, S. Rossignol and S. Oyetola, J. Colloid Interface Sci. 339, 103 (2009).
B.J. Riley, J.D. Vienna, S.M. Frank, J.O. Kroll, J.A. Peterson, N.L. Canfield, Z. Zhu, J. Zhang, K. Kruska, D.K. Schreiber and J.V. Crum, J. Nucl. Mater. 489, 42 (2017).
B.J. Riley, W.C. Lepry and J.V. Crum, J. Nucl. Mater. 468, 140 (2016).
ASTM, Standard Test Method for Accelerated Leach Test for Diffusive Releases from Solidified Waste and a Computer Program to Model Diffusive, Fractional Leaching from Cylindrical Waste Forms, ASTM C 1308-14, American Society for Testing and Materials International, West Conshohocken, PA (2014).
J. Nam, Aqueous synthesis of iodide sodalite for the immobilization of I-129, Materials Science and Engineering, MS thesis, Washington State University, Pullman, WA (2016).
S. Chong, J. Peterson, B. Riley and J. McCloy in WM2016, Waste Management Phoenix, AZ, 2016, pp. 16153.
N.C. Hyatt, J.A. Hriljac, A. Choudhry, L. Malpass, G.P. Sheppard and E.R. Maddrell, MRS Proc. 807, (2003).
E. Maddrell, A. Gandy and M. Stennett, J. Nucl. Mater. 449, 168 (2014).
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Nam, J., Chong, S., Riley, B.J. et al. Iodosodalite Waste Forms from Low-Temperature Aqueous Process. MRS Advances 3, 1093–1103 (2018). https://doi.org/10.1557/adv.2018.225
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DOI: https://doi.org/10.1557/adv.2018.225