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Dynamic memory tuned by frequency in a homologous thermotropic liquid crystal

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Abstract

With scaling of dynamic RAM and NAND memory technologies reaching a limit, there is a need for dynamic memory with high density. In this work, an investigation on existence of dynamic memory feature in a frequency tuned homologous series of thermotropic liquid crystals has been carried out. A homologues series of five thermotropic liquid crystalline compounds comprising of 4-butyl benzoic acid and various alkyloxy benzoic acids are prepared, and all these mesogens exhibit only nematic phase. Liquid crystal dynamic memory storage setup consists of a conducting transparent glass cell with two indium tin oxide coated transparent glass plates acting as electrical electrodes in which the selected thermotropic liquid crystal is filled by capillary action. The temperature dependent dielectric relaxation studies enable to elucidate the relaxation frequency of each of these mesogens in nematic phase. The liquid crystal at different temperatures is excited with the relaxation frequency at various chosen fields, and the dielectric hysteresis is recorded. The magnitude of the hysteresis loop is directly proportional to the memory storage capacity. The main objective of this work is observation of dynamic memory storage in liquid crystals exhibiting nematic phase, at different frequencies in a thermotropic liquid crystal as the ingredient in a conducting polyamide buffed glass cell excited by an external electrical dc stimulus. The variation of the hysteresis loop with varying field; temperature and frequency are also studied and reported in this work.

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The data supporting the findings of this study are available within the article and as supplementary file and any other data can be made available on reasonable request.

References

  1. S. Yu, P.Y. Chen, Emerging memory technologies: recent trends and prospects. IEEE Solid State Circuits Mag. 8, 43–56 (2016)

    Article  Google Scholar 

  2. T. Coughlin, R. Hoyt, J. Handy, Digital storage and memory technology (part 1). Prog. IEEE Technol. Trend Pap. 18, 1–31 (2017)

    Google Scholar 

  3. K. Ishimaru, M. Fujiwara, H. Miyagawa, Y. Aiba, Flash memory and its manufacturing technology for sustainable world. IEEE J. Electron Devices Soc. 10, 737–743 (2021)

    Article  Google Scholar 

  4. D. James, Recent advances in memory technology, in ASMC (Advanced Semicond. Manufacture Conference and Proceedings (2013), pp. 386–395. https://doi.org/10.1109/ASMC.2013.6552766

  5. B.L. Dube, Manufacturing challenges and cost evaluation of new generation 3D memories, in China Semiconductor Technology International Conference 2020, CSTIC 2020 (2020), pp. 18–20. https://doi.org/10.1109/CSTIC49141.2020.9282426

  6. S. Kumar, Correlation between alignment geometries and memory effect in a surface-stabilized ferroelectric liquid crystal. Phys. Rev. E 102, 1–10 (2020)

    Article  Google Scholar 

  7. B. Bai, H. Wang, H. Xin, B. Long, M. Li, Liquid crystalline behaviour of benzoic acid derivatives containing alkoxyazobenzene. Liq. Cryst. 34, 659–665 (2007)

    Article  Google Scholar 

  8. S. Laschat et al., Liquid crystals discotic liquid crystals: from tailor-made synthesis to plastic electronics. Angewandte 46, 4832–4887 (2007). https://doi.org/10.1002/anie.200604203

    Article  Google Scholar 

  9. H.K. Bisoyi, S. Kumar, Liquid-crystal nanoscience: an emerging avenue of soft self-assembly. Chem. Soc. Rev. 40(1), 306–319 (2011). https://doi.org/10.1039/b901793n

    Article  Google Scholar 

  10. M.H. Kishor, M.L.N.M. Mohan, An innovative technique to achieve tunable filtering action by ferroelectric material in infrared region. J. Electron Mater. 49, 2311–2316 (2020)

    Article  ADS  Google Scholar 

  11. H.K. Muchenedi, N. Pongali Sathya Prabu, M.L.N. Madhu Mohan, Fabrication of ferroelectric liquid crystal thermistor. IEEE Trans. Electron Devices 67, 5063–5068 (2020)

    Article  ADS  Google Scholar 

  12. P. Taylor, V.N. Vijayakumar, M.L.N.M. Mohan, Phase transitions: a multinational optical modulation in nematic phase of halogen substituted hydrogen bonded liquid crystals. Phase Trans. 85, 37–41 (2011)

    Google Scholar 

  13. P. Taylor, N.P.S. Prabu, M.L.N.M. Mohan, Phase transitions: a multinational optical shuttering action in nematic phase of SMHBLC: observation of a ribbon-like texture. Phase Trans. 85, 37–41 (2011)

    Google Scholar 

  14. F. Serra, M. Buscaglia, T. Bellini, The emergence of the nematic phase of liquid crystals (LC), used in most LC display. Mater. Today 14, 488–494 (2011)

    Article  Google Scholar 

  15. M.H. Kishor, M.L.N. Madhu Mohan, Realization of memory effect in smectic X* phase. J. Mol. Struct. 1168, 302–308 (2018)

    Article  ADS  Google Scholar 

  16. I. Dozov et al., Fast bistable nematic display using monostable surface switching. Appl. Phys. Lett. 1179, 8–11 (1997)

    Google Scholar 

  17. O. Access, Time-resolved sign-dependent switching in a hybrid aligned nematic liquid crystal cell. New J. Phys. (2008). https://doi.org/10.1088/1367-2630/10/8/083045

    Article  Google Scholar 

  18. C.V. Brown, I.C. Sage, V.C. Hui, Voltage-dependent anchoring of a nematic liquid crystal on a grating surface. Nature 1920, 365–367 (1998)

    Article  ADS  Google Scholar 

  19. C. Uche et al., Modelling zenithal bistability at an isolated edge in nematic liquid crystal cells modelling zenithal bistability at an isolated edge in nematic liquid. Liq. Cryst. 33, 8292 (2007)

    Google Scholar 

  20. A. Jákli, Molecular crystals and liquid crystals science and technology section A. Mol. Cryst. Liq. Cryst. Struct. Opt. Prop. Liq. Crys. Dispers. Polym. 25, 37–41 (1994). https://doi.org/10.1080/10587259408027212

    Article  Google Scholar 

  21. S.C. Jain, D.K. Rout, Electro-optic response of polymer dispersed liquid-crystal films. J. Appl. Phys. 70, 6988–6992 (1991)

    Article  ADS  Google Scholar 

  22. P. Taylor, R. Yamaguchi, S. Sato, Highly transparent memory states in polymer dispersed liquid crystal films. Liq. Cryst. 14, 37–41 (2006). https://doi.org/10.1080/02678299308027800

    Article  Google Scholar 

  23. M. Buscaglia et al., Memory effects in nematics with quenched disorder. Phys. Rev. E 74, 1–8 (2006). https://doi.org/10.1103/PhysRevE.74.011706

    Article  Google Scholar 

  24. V. Gdovinová, N. Tomašoviˇ, P. Kula, P. Kopˇ, Memory effect in nematic phase of liquid crystal doped with magnetic and non-magnetic nanoparticles. J. Mol. Liq. 282, 286–291 (2019)

    Article  Google Scholar 

  25. J. Prakash, A. Chandran, A.M. Biradar, Scientific developments of liquid crystal-based optical memory: a review. Rep. Progress Phys. (2017). https://doi.org/10.1088/0034-4885/80/1/016601

    Article  Google Scholar 

  26. K. Kim, Memory technologies for mobile era, in 2005 IEEE Asian Solid-State Circuits Conference ASSCC 2005 (2005), p. 7–11. https://doi.org/10.1109/ASSCC.2005.251776

  27. A. Spessot, H. Oh, 1T–1C dynamic random access memory status, challenges, and prospects. IEEE Trans. Electron Devices 67, 1382–1393 (2020)

    Article  ADS  Google Scholar 

  28. S.K. Kim, M. Popovici, Future of dynamic random-access memory as main memory. MRS Bull (2020). https://doi.org/10.1557/mrs.2018.95

    Article  Google Scholar 

  29. K. Kim, Technology for sub-50nm DRAM and NAND flash manufacturing. Tech. Dig. Int. Electron Devices Meet. IEDM 2005, 323–326 (2005)

    Google Scholar 

  30. Y. Li, Q. Qian, X. Zhu, Y. Li, M. Zhang, Recent advances in organic-based materials for resistive memory applications. InfoMat 2, 1–39 (2020). https://doi.org/10.1002/inf2.12120

    Article  ADS  Google Scholar 

  31. M.M. MLN, Investigations on dielectric relaxations, memory and thermistor applications in a liquid crystal nematogen. Liq. Cryst. 70, 1–8 (2022)

    Google Scholar 

  32. M.L.N. Madhu Mohan, Dielectric relaxations in a liquid crystal along with thermistor application. Eur. Phys. J. E 45, 1–9 (2022)

    Article  Google Scholar 

  33. D. Andrienko, Introduction to liquid crystals. J. Mol. Liq. 267, 520–541 (2018)

    Article  Google Scholar 

  34. P.J. Collings, J.W. Goodby, Introduction to Liquid Crystals: Chemistry and Physics (CRC Press, 2019)

    Book  Google Scholar 

  35. N. Kumar, S. Chaudhary, P. Upadhyay, A.K. Dwivedi, D. Kumar, Even–odd effect of the homologous series of nCHBT liquid crystal molecules under the influence of an electric field: a theoretical approach. Pramana J. Phys. 94, 106 (2020)

    Article  ADS  Google Scholar 

  36. V.N. Vijayakumar, M.L.N.M. Mohan, Dielectric relaxations in nematic phase of hydrogen bonded liquid crystal homologous series. Ferroelectrics 413, 156–169 (2011)

    Article  ADS  Google Scholar 

  37. S.V. Shiyanovskii, O.D. Lavrentovich, Dielectric relaxation and memory effects in nematic liquid crystals. Liq. Cryst. 37, 737–745 (2010)

    Article  Google Scholar 

  38. J. Li, S. Gauza, S.T. Wu, Temperature effect on liquid crystal refractive indices. J. Appl. Phys. 96, 19–24 (2004)

    Article  ADS  Google Scholar 

  39. S. Marčelja, End-chain ordering in nematic liquid crystals. Solid State Commun. 13, 759–762 (1973)

    Article  ADS  Google Scholar 

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Contributions

VPJ was contributed to conceptualization, writing—original draft, experimentation, and data recording. SM was contributed to conceptualization, data interpretation, and analysis. MLNMM was contributed to conceptualization, data interpretation, and analysis.

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Correspondence to S. Moorthi.

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Janaki, V.P., Moorthi, S. & Mohan, M.L.N.M. Dynamic memory tuned by frequency in a homologous thermotropic liquid crystal. Eur. Phys. J. E 46, 38 (2023). https://doi.org/10.1140/epje/s10189-023-00300-y

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