Abstract
We put forward a theoretical framework to calculate pair distribution functions in the nematic liquid crystals formed by sphere-cylinders that self-assemble in linear chain structures. For a nematically ordered system, one can distinguish between the spatial correlations in the plane perpendicular to the crystalline axis, and in the direction parallel to the latter. Following this separation, we show that the RDFs in the parallel case can be described using a superposition of a chain model and Onsager distribution, whereas the RDFs in the perpendicular case turn out to be that of the soft disks. Based on this concept, we show how the spatial correlations in the system are influenced by the nematic order parameter. We conclude that even if the nematic ordering is high in the system, the imperfection of the crystal is strongly reflected in the pair distributions.
Graphical abstract
Similar content being viewed by others
References
A. Khan, Curr. Opin. Colloid Interface Sci. 1, 614 (1996).
P. van der Schoot, M.E. Cates, Langmuir 10, 670 (1994).
D.M. Kuntz, L.M. Walker, Soft Matter 4, 286 (2008).
R. Mezzenga, J. Jung, J. Adamcik, Langmuir 26, 10401 (2010).
Chiu Fan Lee, Phys. Rev. E 80, 031902 (2009).
A. Ciferri, Liq. Cryst. 34, 693 (2007).
A. Aggeli, M. Bell, L.M. Carrick, C.W.G. Fishwick, R. Harding, P.J. Mawer, S.E. Radford, A.E. Strong, N. Boden, J. Am. Chem. Soc. 125, 9619 (2003).
H.-D. Dörfler, Adv. Colloid Interface Sci. 98, 285 (2002).
M. Nakata, G. Zanchetta, B.D. Chapman, C.D. Jones, J.O. Cross, R. Pindak, T. Bellini, N.A. Clark, Science 318, 1276 (2007).
C. Maffeo, B. Luan, A. Aksimentiev, Nucl. Acids Res. 40, 3812 (2012).
C. Robinson, Tetrahedron 13, 219 (1961).
F. Livolant, A.M. Levelut, J. Doucet, J.P. Benoit, Nature 339, 724 (1989).
K. Merchant, R.L. Rill, Biophys. J. 73, 3154 (1997).
F. Tombolato, A. Ferrarini, J. Chem. Phys. 122, 054908 (2005).
N.B. Wilding, J. Phys.: Condens. Matter 9, 585 (1996).
S. Bonazzi, M. Capobianco, M.M. De Morais, A. Garbesi, G. Gottarelli, M.G. Ponzi Bossi, G.P. Spada, L. Tondelli, J. Am. Chem. Soc. 113, 5809 (1991).
H.-S. Park, S.-W. Kang, L. Tortora, Yu. Nastishin, D. Finotello, S. Kumar, O.D. Lavrentovich, J. Phys. Chem. B 112, 16307 (2008).
F. Chami, M.R. Wilson, J. Am. Chem. Soc. 132, 7794 (2010).
J. Lydon, Liq. Cryst. 38, 1663 (2011).
P.K. Maiti, Y. Lansac, M.A. Glaser, N.A. Clark, Liq. Cryst. 29, 619 (2002).
R.G. Edwards, J.R. Henderson, R.L. Pinning, Mol. Phys. 86, 567 (1995).
J.R. Henderson, J. Chem. Phys. 113, 5965 (2000).
J.P.F. Lagerwall, C. Schutz, M. Salajkova, J.-H.J.H. Noh, J.H. Park, G. Scalia, L. Bergstrom, NPG Asia Mater 6, e80 (2014).
C. De Michele, T. Bellini, F. Sciortino, Macromolecules 45, 1090 (2012).
S. Kantorovich, E. Pyanzina, C. De Michele, F. Sciortino, Soft Matter 9, 4412 (2013).
K.T. Nguyen, F. Sciortino, C. De Michele, Langmuir 30, 4814 (2014).
C. De Michele, J. Comput. Phys. 229, 3276 (2010).
C. De Michele, L. Rovigatti, T. Bellini, F. Sciortino, Soft Matter 8, 8388 (2012).
K.T. Nguyen, A. Battisti, D. Ancora, F. Sciortino, C. De Michele, Soft Matter 11, 2934 (2015).
L. Onsager, Ann. N.Y. Acad. Sci. 51, 627 (1949).
E. Pyanzina, S. Kantorovich, J.J. Cerda, A. Ivanov, C. Holm, Mol. Phys. 107, 571 (2009).
S. Bravo Yuste, A. Santos, Phys. Rev. A 43, 5418 (1991).
S. Bravo Yuste, A. Santos, J. Chem. Phys. 99, 2020 (1993).
A. Arnold, O. Lenz, S. Kesselheim, R. Weeber, F. Fahrenberger, D. Roehm, P. Kosovan, C. Holm, in Meshfree Methods for Partial Differential Equations VI, edited by Michael Griebel, Marc Alexander Schweitzer, Vol. 89 of Lecture Notes in Computational Science and Engineering (Springer Berlin Heidelberg, 2013) pp. 1--23.
J.D. Weeks, D. Chandler, H.C. Andersen, J. Chem. Phys. 54, 5237 (1971).
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Pyanzina, E.S., Kantorovich, S.S. & De Michele, C. Nematic phase characterisation of the self-assembling sphere-cylinders based on the theoretically calculated RDFs. Eur. Phys. J. E 38, 81 (2015). https://doi.org/10.1140/epje/i2015-15081-8
Received:
Accepted:
Published:
DOI: https://doi.org/10.1140/epje/i2015-15081-8