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Approbation of the Cell Model of a Cation-Exchange Membrane on 1 : 1 Electrolytes

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Abstract

Using the algebraic formula derived earlier to determine the electroosmotic permeability of an ion-exchange membrane at a given constant current density, experimental results obtained by the authors for an extrusion perfluorinated membrane and aqueous solutions of the 1 : 1 electrolytes HCl, NaCl, KCl, LiCl, and CsCl have been analyzed. A cell model has been successfully tested using experimental data on the electrical conductivity and electroosmotic permeability of the MF-4SC cation-exchange membrane at given current density and concentration of these electrolytes. A good agreement between the theoretical and experimental data has been obtained, and the physicochemical parameters of the cell model have been determined.

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Funding

This work was supported by the Russian Foundation for Basic Research, project nos. 17-08-01287 and 19-08-00925 for the theoretical and data processing part and the experimental part, respectively.

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Authors and Affiliations

  1. National University of Oil and Gas “Gubkin University”, 119991, Moscow, Russia

    A. N. Filippov

  2. Kuban State University, 350040, Krasnodar, Russia

    S. A. Shkirskaya

Authors
  1. A. N. Filippov
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  2. S. A. Shkirskaya
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Correspondence to A. N. Filippov.

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The authors declare that they have no conflict of interest.

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Translated by S. Zatonsky

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Filippov, A.N., Shkirskaya, S.A. Approbation of the Cell Model of a Cation-Exchange Membrane on 1 : 1 Electrolytes. Membr. Membr. Technol. 1, 278–285 (2019). https://doi.org/10.1134/S2517751619050020

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  • DOI: https://doi.org/10.1134/S2517751619050020

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