Skip to main content
SpringerLink
Log in

Colloidal forming of chemically bonded calcium phosphate composites

  • Published:
Inorganic Materials: Applied Research Aims and scope

Abstract

On the basis of mixtures of Ca3(PO4)2(α-TCP)/CaO and α-TCP/CaMPO4 powders (M = Na, K), self-hardening pastes are prepared whose treatment with solutions of sodium bicarbonate and calcium chloride results in the production of chemically bonded composites containing the phases of hydroxyapatite (HA) and calcium carbonate, as well as TCP and HA. The resulting materials can be used both as relatively dense composites (up to 75%) for osteoplasty and in the casting of settable ceramic slurries in plastic molds of special geometry for obtaining osteoconductive macroporous ceramics.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Barinov, S.M., Calcium phosphate-based ceramic and composite materials for medicine, Russ. Chem. Rev., 2010, vol. 79, no. 1, pp. 13–29.

    Article  CAS  Google Scholar 

  2. Putlyaev, V.I. and Safronova, T.V., A new generation of calcium phosphate biomaterials: the role of phase and chemical compositions, Glass Ceram., 2006, vol. 63, no. 3, pp. 99–102.

    Article  CAS  Google Scholar 

  3. Dorozhkin, S.V., Calcium orthophosphate cements for biomedical application, J. Mater. Sci., 2008, vol. 43, pp. 3028–3057.

    Article  CAS  Google Scholar 

  4. Ievlev, V.M., Putlyaev, V.I., Safronova, T.V., and Evdokimov, P.V., Additive technologies for making highly permeable inorganic materials with tailored morphological architectonics for medicine, Inorg. Mater., 2015, vol. 51, no. 13, pp. 1295–1313.

    Article  Google Scholar 

  5. Sigmund, W.M., Bell, N.S., and Bergstrom, L., Novel powder-processing methods for advanced ceramics, J. Am. Ceram. Soc., 2000, vol. 83, no. 7, pp. 1557–1574.

    Article  CAS  Google Scholar 

  6. Lewis, J.A., Colloidal processing of ceramics, J. Am. Ceram. Soc., 2000, vol. 83, no. 10, pp. 2341–2359.

    Article  CAS  Google Scholar 

  7. Evdokimov, P.V., Putlyaev, V.I., Ievlev, V.M., Klimashina, E.S., and Safronova, T.V., Osteoconductive ceramics with a specified system of interconnected pores based on double calcium alkali metal phosphates, Dokl. Chem., 2015, vol. 460, no. 2, pp. 61–65.

    Article  CAS  Google Scholar 

  8. Filippov, Ya.Yu., Larionov, D.S., Putlyaev, V.I., Sokolov, A.V., Koval’kov, V.K., Agakhi, K.A., Selezneva, I.I., and Nikonova, Yu.A., Reaction-associated resorbable phosphate materials: production and testing in vitro, Glass Ceram., 2013, vol. 70, no. 7, pp. 306–310.

    Article  CAS  Google Scholar 

  9. Hsu, C.-K., The preparation of biphasic porous calcium phosphate by the mixture of Ca(H2PO4) · 2H2O and CaCO3, Mater. Chem. Phys., 2003, vol. 80, pp. 409–420.

    Article  CAS  Google Scholar 

  10. Tas, A.C., Porous, biphasic CaCO3-calcium phosphate biomedical cement scaffolds from calcite (CaCO3) powder, Int. J. Appl. Ceram. Technol., 2007, vol. 4, no. 2, pp. 152–163.

    CAS  Google Scholar 

  11. Cahyanto, A., Toita, R., Tsuru, K., and Ishikawa, K., Effect of particle size on carbonate apatite cement properties consisting of calcite (or vaterite) and dicalcium phosphate anhydrous, Key Eng. Mater., 2015, vol. 631, pp. 128–133.

    Article  Google Scholar 

  12. Evdokimov, P.V., Putlyaev, V.I., Ivanov, V.K., Garshev, A.P., Shatalova, T.B., Orlov, N.K., Klimashina, E.S., and Safronova, T.V., Phase equilibria in the tricalcium phosphate-mixed calcium sodium (potassium) phosphate systems, Russ. J. Inorg. Chem., 2014, vol. 59, no. 11, pp. 1219–1227.

    Article  CAS  Google Scholar 

  13. Filippov, Ya.Yu., Larionov, D.S., Putlyaev, V.I., Kolyagin, Yu.G., Georgievskii, D.V., Agakhi, K.A., Koval’kov, V.K., and Sokolov, A.V., Kinetic features of formation of reactive-linked phosphate biomaterials, Nanosist.: Fiz., Khim., Matem., 2013, vol. 4, no. 1, pp. 54–65.

    Google Scholar 

  14. Filippov, Ya.Yu., Reaction-linked composites based on calcium phosphates for regeneration of bone tissue, Cand. Sci. (Chem.) Dissertation, Moscow, 2013.

    Google Scholar 

  15. Evdokimov, P.V., Biphosphates Ca(3–x)M2x(PO4)2 (M = Na, K) as the basis for macroporous bioceramics with specific architecture, Cand. Sci. (Chem.) Dissertation, Moscow, 2015.

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Moscow State University, Moscow, 119899, Russia

    V. I. Putlyaev, T. V. Safronova, Ya. Yu. Filippov & P. V. Evdokimov

Authors
  1. V. I. Putlyaev
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. T. V. Safronova
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Ya. Yu. Filippov
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. P. V. Evdokimov
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to V. I. Putlyaev.

Additional information

Original Russian Text © V.I. Putlyaev, T.V. Safronova, Ya.Yu. Filippov, P.V. Evdokimov, 2016, published in Materialovedenie, 2016, No. 6, pp. 39–45.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Putlyaev, V.I., Safronova, T.V., Filippov, Y.Y. et al. Colloidal forming of chemically bonded calcium phosphate composites. Inorg. Mater. Appl. Res. 8, 153–158 (2017). https://doi.org/10.1134/S2075113317010312

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S2075113317010312

Keywords

Search

Navigation