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Investigation of Inhibitory Effects of Chitosan on Pitting and Electrochemical Corrosion Behavior Caused by Sigma Phase in Duplex Stainless Steels (DSS)

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Abstract

In this study, as a result of the heat treatment parameters applied to 2205 duplex stainless steel (DSS), the sigma phase formed in the microstructure and changes in the corrosion behavior of DSS due to this sigma phase were investigated in solutions with and without inhibitor. 1 g L–1 chitosan (CS) solution was used as an inhibitor. To investigate the effect of the inhibitor on the corrosion behavior, a pitting corrosion test was performed in the inhibitor and noninhibitor FeCl3 solution in accordance with the ASTM G48 standard. In addition, electrochemical corrosion experiments were carried out in a 3.5% NaCl corrosion solution with and without inhibitor, to investigate the effect of the inhibitor on electrochemical corrosion conditions. The effects of the inhibitor on DSS were examined by the stereo microscope, optic microscope (OM), scanning electron microscope (SEM), Fourier transform infrared spectroscopy (FTIR) analysis. Weight loss and surface coverage measurements were performed to determine inhibitor efficiency. Phase analyzes of DSS samples were determined by X-ray diffraction (XRD) and energy-dispersive X-ray spectroscopy (EDX) analysis. As a result of the study, it has been determined that CS plays an effective inhibitor for DSS material, even in the presence of the sigma phase.

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REFERENCES

  1. Gunn, R.N., Duplex Stainless Steels, Microstructure, Properties and Applications, Cambridge: Abington Publ., 1997.

    Book  Google Scholar 

  2. Shamanth, V. and Ravishankar, K.S., Results Phys., 2015, vol. 5, p. 297.

    Article  Google Scholar 

  3. Kisasoz, A., Karaaslan, A., and Bayrak, Y., Met. Sci. Heat Treat., 2017, vol. 58, p. 11.

    Article  CAS  Google Scholar 

  4. Calliari, I., Pellizzari, M., Zanellato, M., and Ramous, E., J. Mater. Sci., 2011, vol. 46, p. 6916.

    Article  CAS  Google Scholar 

  5. Dos Santos, D.C. and Magnabosco, R., Metall. Mater. Trans. A, 2016, vol. 47, p. 1554.

    Article  CAS  Google Scholar 

  6. Lo, K.H., Shek, C.H., and Lai, J.K.L., Mater. Sci. Eng., R, 2009, vol. 65, p. 39.

    Article  CAS  Google Scholar 

  7. Deng, B., Wang, Z., Jiang, Y., Sun, T., Xu, J., and Li, J., Corros. Sci., 2009, vol. 51, p. 2969.

    Article  CAS  Google Scholar 

  8. Kisasoz, A., Gurel, S., and Karaaslan, A., Met. Sci. Heat Treat., 2016, vol. 57, p. 8.

    Article  CAS  Google Scholar 

  9. Alvarez-Armas, I., Recent Pat. Mech. Eng., 2008, vol. 1, p. 51.

    Article  CAS  Google Scholar 

  10. Dai, N., Wu, J., Sun, Y., Tang, Y., Liu, Y., Li, J., and Jiang, Y., J. Electrochem. Soc., 2019, vol. 166, p. 454.

    Article  CAS  Google Scholar 

  11. Silva, R., Baroni, L.F.S., Kugelmeier, C.L., Silva, M.B.R., Kuri, S.E., and Rovere, C.A.D., Corros. Sci., 2017, vol. 116, p. 66.

    Article  CAS  Google Scholar 

  12. Silva, R., Baroni, L.F.S., Silva, M.B.R., Afonso, C.R.M., Kuri, S.E., and Rovere, C.A.D., Mater. Charact., 2016, vol. 114, p. 211.

    Article  CAS  Google Scholar 

  13. Sahu, J.K., Krupp, U., Ghosh, R.N., and Christ, H.J., Mater. Sci. Eng., A, 2009, vol. 508, p. 1.

    Article  CAS  Google Scholar 

  14. Kisasoz, A., Ozer, G., and Karaaslan, A., Mater. Res. Express, 2019, vol. 6, p. 11.

    Article  Google Scholar 

  15. Elmer, J.W., Palmer, T.A., and Specht, E.D., Metall. Mater. Trans. A, 2007, vol. 38, p. 464.

    Article  CAS  Google Scholar 

  16. Ferro, P., Fabrizi, A., and Nilsson, J.-O., Res. Rep. Met., 2017, vol. 1, p. 6.

    Google Scholar 

  17. Badji, R., Kherrouba, N., Mehdi, B., Chetini, B., Bouaddallah, M., Kahloun, C., and Bacroix, B., Mater. Chem. Phys., 2014, vol. 148, p. 664.

    Article  CAS  Google Scholar 

  18. Calliari, I., Ramous, E., Rebuffi, G., and Straffelini, G., Metall. Ital., 2008, vol. 100, p. 5.

    Google Scholar 

  19. Chen, T.H. and Yang, J.R., Mater. Sci. Eng., A, 2001, vol. 311, p. 28.

    Article  Google Scholar 

  20. Duprez, L., De Cooman, B.C., and Akdut, N., Steel Res., 2015, vol. 72, p. 311.

    Article  Google Scholar 

  21. Escriba, D.M., Materna-Morris, E., Plaut, R.L., and Padilha, A.F., Mater. Charact., 2009, vol. 60, p. 1214.

    Article  CAS  Google Scholar 

  22. Ghosh, S.K. and Mondal, S., Mater. Charact., 2008, vol. 59, p. 1776.

    Article  CAS  Google Scholar 

  23. Yalciner, G., Ozer, G., Kisasoz, A., and Karaaslan, A., Mater. Res. Express, 2019, vol. 6, p. 12.

    Google Scholar 

  24. Liu, X., Zhang, C., Li, J., Chen, W., Zheng, Y., Li, H., and Han, P., Steel Res. Int., 2017, vol. 88, p. 1.

    Google Scholar 

  25. Zheng, J., Hu, X., Pan, C., Fu, S., Lin, P., and Chou, K., Mater. Corros., 2018, vol. 69, p. 572.

    Article  CAS  Google Scholar 

  26. Haghdadi, N., Laleh, M., Kosari, A., Moayed, M.H., Cizek, P., Hodgson, P.D., and Beladi, H., Mater. Lett., 2019, vol. 238, p. 26.

    Article  CAS  Google Scholar 

  27. Kisasoz, A., Mater. Test., 2018, vol. 60, p. 5.

    Article  CAS  Google Scholar 

  28. Yan, X., Zou, C., and Qin, Y., Starch/Staerke, 2014, vol. 66, p. 968.

  29. Abd El Aal, E.E., Zakria, W., Diab, A., and Abd El Haleem, S.M., J. Chem. Technol. Biotechnol., 1999, vol. 74, p. 1061.

    Article  CAS  Google Scholar 

  30. Lo, I.-H. and Tsai, W.-T., Corros. Sci., 2007, vol. 49, p. 1847.

    Article  CAS  Google Scholar 

  31. Ho, M.Y., Geddes, J., Barmatov, E., Crawford, L., and Hughes, T., Corros. Sci., 2018, vol. 137, p. 43.

    Article  CAS  Google Scholar 

  32. Carneiro, J., Tedim, J., and Ferreira, M.G.S., Prog. Org. Coat., 2015, vol. 89, p. 348.

    Article  CAS  Google Scholar 

  33. Umoren, S.A., Banera, M.J., Garcia, T.A., Gervasi, C.A., and Mirifica, M.V., Cellulose, 2013, vol. 20, p. 2529.

    Article  CAS  Google Scholar 

  34. Fayomi, O.S.I., Akande, I.G., and Popoola, A.P.I., J. Bio- Tribo-Corros., 2018, vol. 4, p. 72.

  35. Mahdy, G.A.E., Atta, A.M., Lohedan, H.A., and Ezzat, A.O., Int. J. Electrochem. Sci., 2015, vol. 10, p. 5812.

    Google Scholar 

  36. Kong, P., Feng, H., Chen, N., Lu, Y., Li, S., and Wang, P., RSC Adv., 2019, vol. 9, p. 9211.

    Article  CAS  Google Scholar 

  37. Mouaden, K.E.L., Chauhan, D.S., Quraishi, M.A., and Bazzi, L., Sustainable Chem. Pharm., 2020, vol. 15, p. 1.

    Google Scholar 

  38. Li, H., Li, H., Liu, Y., and Huang, X., J. Korean Chem. Soc., 2015, vol. 59, p. 142.

    Article  CAS  Google Scholar 

  39. Zhang, T., Zhao, Y., Dong, B., and Li, X., Corros. Eng., Sci. Technol., 2020, vol. 7, p. 1.

    Google Scholar 

  40. Yang, S.F., Wen, Y., Yi, P., Xiao, K., and Dong, C.F., Int. J. Miner., Metall. Mater., 2017, vol. 24, p. 1260.

    Article  CAS  Google Scholar 

  41. Hammood, A.S., Mahdi, M.A.S., Thair, L., and Haddad, H., Mater. Res. Express, 2019, vol. 6, p. 1.

    Article  CAS  Google Scholar 

  42. Gupta, N.K., Joshi, P.G., Srivastava, V., and Quraishi, M.A., Int. J. Biol. Macromol., 2018, vol. 106, p. 704.

    Article  CAS  Google Scholar 

  43. ASTM G48-11: Standard Test Methods for Pitting and Crevice Corrosion Resistance of Stainless Steels and Related Alloys by Use of Ferric Chloride Solution, West Conshohocken, PA: ASTM Int., 2015.

  44. Zeng, Q., Zhang, J., Cheng, H., Chen, L., and Qi, Z., RSC Adv., 2017, vol. 7, p. 48526.

    Article  CAS  Google Scholar 

  45. Kadapparambil, S., Yadav, K., Ramachandran, M., and Selvam, V., Corros. Rev., 2017, vol. 35, p. 1.

    Article  CAS  Google Scholar 

  46. Ardakani, E.K., Kowsari, E., and Ehsani, A., Colloids Surf., A., 2020, vol. 586, p. 1.

    Google Scholar 

  47. Fajobi, M.A., Fayomi, O.S.I., Akande, I.G., and Odunlami, O.A., J. Bio- Tribo-Corros., 2019, vol. 5, p. 79.

  48. Gupta, N.K., Verma, C., Quraishi, M.A., and Mukherjee, A.K., J. Mol. Liq., 2016, vol. 215, p. 47.

    Article  CAS  Google Scholar 

  49. Ahmed, R.A., Farghali, R.A., and Fekry, A.M., Int. J. Elecrochem. Sci., 2012, vol. 7, p. 7270.

    CAS  Google Scholar 

  50. Fayomi, O.S.I. and Popoola, A.O.I., Silicon, 2014, vol. 6, p. 137.

    Article  CAS  Google Scholar 

  51. Yu, Z., Liu, Y., Liang, L., Shao, L., Li, X., Zeng, H., Feng, X., and Cao, K., Chem. Phys. Lett., 2019, vol. 735, p. 1.

    Article  CAS  Google Scholar 

  52. Rosalbino, F., Scavino, G., and Ubertalli, G., Mater. Corros., 2020, vol. 71, p. 2021.

    Article  CAS  Google Scholar 

  53. Luo, H., Su, H., Ying, G., Dong, C., and Li, X., Appl. Surf. Sci., 2017, vol. 425, p. 628.

    Article  CAS  Google Scholar 

  54. Sharifi, Z., Pakshir, M., and Mohamadi, S., J. Mater. Eng. Perform., 2015, vol. 24, p. 664.

    Article  CAS  Google Scholar 

  55. Rabizadeh, T. and Asl, S.K., Mater. Corros., 2019, vol. 70, p. 38.

    Google Scholar 

  56. Wan, K., Feng, P., Hou, B., and Li, Y., RSC Adv., 2016, vol. 81, p. 3419.

    Google Scholar 

  57. Li, D., Zhang, P., Guo, X., Zhao, X., and Xu, Y., RSC Adv., 2019, vol. 9, p. 0997.

  58. Yongqiang, W., Hao, S., Na, L., Yanhao, X., and Hemin, J., Int. J. Electrochem. Sci., 2018, vol. 13, p. 868.

    Google Scholar 

  59. He, L., Guo, Y.J., Wu, X.Y., Jiang, Y.M., and Li, J., J. Iron Steel Res. Int., 2016, vol. 23, p. 357.

    Article  Google Scholar 

  60. Obot, I.B., Obi-Egbedi, N.O., Umoren, S.A., and Ebenso, E.E., Chem. Eng. Commun., 2011, vol. 198, p. 711.

    Article  CAS  Google Scholar 

  61. Khadom, A.A., Musa, A.Y., Kadlum, A.A.H., Mohamad, A.B., and Takriff, M.S., Port. Electrochim. Acta, 2010, vol. 28, p. 221.

    Article  CAS  Google Scholar 

  62. Kazazi, M., Afshar, A., and Sajjadnejad, M., Int. J. Iron Steel Soc. Iran, 2013, vol. 10, p. 14.

    Google Scholar 

  63. Khan, Z.H., Aziz, A., Hasan, R., and Al-Mamun, R., Anti-Corros. Methods Mater., 2016, vol. 63, p. 308.

    Article  CAS  Google Scholar 

  64. Rajkumar, I.M., Asaithambi, D., Chidambaram, R.R., and Rajkumar, P., Synth. Commun., 2020, vol. 1, p. 1.

    Google Scholar 

  65. Queiroz, M.F., Melo, K.R.T., Sabry, D.A., Sassaki, G.L., and Rocha, H.A.O., Mar. Drugs, 2015, vol. 13, p. 141.

    Article  CAS  Google Scholar 

  66. Yasmeen, S., Kabiraz, M.K., Saha, B., Quadir, R., Gafur, A., and Masum, S., Int. Res. J. Pure Appl. Chem., 2016, vol. 10, p. 1.

    Article  CAS  Google Scholar 

  67. Souza, N.L.G.D., Salles, T.F., Brandao, H.M., Edwards, H.G.M., and Oliveira, L.F.C., J. Braz. Chem. Soc., 2015, vol. 26, p. 1247.

    CAS  Google Scholar 

  68. Prabakaran, M., Kim, S.H., Hemapriya, V., Gopiraman, M., Kim, I.S., and Chung, I.M., RSC Adv., 2013, vol. 1, p. 1.

    Google Scholar 

  69. Shainy, K.M., Ammal, P.R., Unni, K.N, Benjamin, S., and Joseph, A., J. Bio- Tribo-Corros., 2016, vol. 6, p. 2.

  70. Yadav, M., Kumar, S., Purkait, T., Olasunkanmi, L.O., Bahadur, I., and Ebenso, E.E., J. Mol. Liq., 2016, vol. 213, p. 122.

    Article  CAS  Google Scholar 

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ACKNOWLEDGMENTS

The author would like to thank Assoc. Prof. Dr. Alptekin Kısasöz for his valuable contributions.

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  1. Aluminium Test Training and Research Center (ALUTEAM), Fatih Sultan Mehmet Vakif University, Halic Campus, TR 34445, Istanbul, Turkey

    Gökhan ÖZER

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ÖZER, G. Investigation of Inhibitory Effects of Chitosan on Pitting and Electrochemical Corrosion Behavior Caused by Sigma Phase in Duplex Stainless Steels (DSS). Prot Met Phys Chem Surf 58, 176–189 (2022). https://doi.org/10.1134/S2070205122010154

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