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Chromatography–mass spectrometry study of aldol condensation reaction with an organotelluric catalyst

  • Investigation Methods for Physicochemical Systems
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Abstract

This work studies regularities of the aldol condensation reaction between 3,4-dimethoxybenzal-dehyde and 4-bromo-acetophenone with formation of 1-(4-bromophenyl)-3-(3,4-dimethoxyphenyl)-2-propene-1-one catalyzed by di(4-methoxyphenyl)telluroxide. Conditions are found for separation of the reaction mixture components and catalyst using reverse phase high-performance liquid chromatography (RP HPLC) with mass-spectrometric detection by electrospray ionization (ESI). Special features of separation of reaction mixture components and mass spectrometric analysis are discussed.

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Authors and Affiliations

  1. Samara State University, Samara, Russia

    E. V. Eliseeva, N. A. Red’kin & V. P. Gar’kin

  2. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, Leninskii pr. 31, bldg. 4, 119071, Moscow, Russia

    I. S. Pytskii & A. K. Buryak

Authors
  1. E. V. Eliseeva
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  2. N. A. Red’kin
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  3. V. P. Gar’kin
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  4. I. S. Pytskii
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  5. A. K. Buryak
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Corresponding authors

Correspondence to E. V. Eliseeva or A. K. Buryak.

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Eliseeva, E.V., Red’kin, N.A., Gar’kin, V.P. et al. Chromatography–mass spectrometry study of aldol condensation reaction with an organotelluric catalyst. Prot Met Phys Chem Surf 51, 1050–1057 (2015). https://doi.org/10.1134/S2070205115060088

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  • DOI: https://doi.org/10.1134/S2070205115060088

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