Abstract
A mathematical model describing the destruction of catalyst particles during operation in an industrial fluidized-bed reactor with allowance for the crushing and abrasion of particles is proposed. Differences between the mechanical properties of IM-2201 and KDI catalysts used in the dehydrogenation of iso-butane to iso-butylene at PAO Nizhnekamskneftekhim are established. Using KDI catalyst with modification of the cyclone group and retention of the equilibrium distribution of particles according to size in a reactor is shown to provide a more than a 2.5-fold reduction in catalyst consumption.
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Rangelova, J., Mörl, L., Heinrich, S., and Dalichau, J., Chem. Eng. Technol., 2002, vol. 25, no. 6, pp. 639–646.
McMillan, J., Briens, C., Berruti, F., and Chan, E., Chem. Eng. Sci., 2007, vol. 62, no. 14, pp. 3809–3820.
Chen, Z., Grace, J.R., and Jim Lim, C., Fuel, 2008, vol. 87, no. 7, pp. 1360–1371.
Jiang, X., Zhou, L., Liu, J., and Han, X., Powder Technol., 2009, vol. 195, no. 1, pp. 44–49.
Choi, J.-H., Moon, Y.-S., Yi, C.-K., and Kim, S.D., J. Taiwan Inst. Chem. Eng., 2010, vol. 41, no. 6, pp. 656–660.
Pougatch, K., Salcudean, M., and McMillan, J., Chem. Eng. Sci., 2010, vol. 65, no. 16, pp. 4829–4843.
Thon, A., Püttmann, A., Hartge, E.-U., Heinrich, S., Warther, J., Patience, G.S., and Bockrath, R.E., Powder Technol., 2011, vol. 214, no. 1, pp. 21–30.
Al-Zahrani, A.A., Powder Technol., 2000, vol. 107, nos. 1–2, pp. 54–59.
Heinrich, S., Peglow, M., and Mörl, L., Chem. Eng. J., 2002, vol. 86, nos. 1–2, pp. 223–231.
Il’in, V.M., Veklov, V.A., Pavlova, I.N., Kas’yanova, L.Z., Bazhenov, Yu.P., and Saifullina, A.A., Katal. Prom-sti, 2005, no. 4, pp. 47–51.
Egorova, S.R., Kataev, A.N., Bekmukhamedov, G.E., Lamberov, A.A., Gil’mullin, R.R., Khaidarov, R.A., Nesterov, O.N., and Gil’manov, Kh.Kh., Catal. Ind., 2009, vol. 1, no. 4, pp. 313–321.
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Original Russian Text © A.N. Kataev, A.G. Egorov, S.R. Egorova, A.A. Lamberov, 2015, published in Kataliz v Promyshlennosti.
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Kataev, A.N., Egorov, A.G., Egorova, S.R. et al. Mathematical modeling of changes in the fractional composition of dehydrogenation catalysts in a fluidized-bed reactor. Catal. Ind. 7, 221–226 (2015). https://doi.org/10.1134/S2070050415030071
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DOI: https://doi.org/10.1134/S2070050415030071