Skip to main content
SpringerLink
Log in

Improving the Adhesive Properties of Adhesives Based on a Mixture of Nitrile Butadiene and Chlorinated Rubbers with Metal Chelates

  • Published:
Polymer Science, Series D Aims and scope Submit manuscript

Abstract

This article discusses the development of cold curing adhesives based on nitrile butadiene rubbers (NBRs) containing chlorinated polymers and metal chelates as enhancers and the strengthening mechanism of adhesive joints upon application of such components. The influence of the solvent nature on the adhesive strength of adhesive joints has been analyzed using thermodynamic approach, the reasonability of application of ethyl acetate has been demonstrated. A synergistic effect on adhesive properties of adhesives and their stability has been detected upon combined use of copper chelate and chlorinated natural rubber in adhesives based on nitrile butadiene rubbers. Optimum ratios in the polymer base of adhesives based on NBR/chlorinated natural rubber and concentration of copper chelate have been determined that improve the adhesive strength between rubber substrates by 2–2.5 times in comparison with adhesives based on NBRs.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1.
Fig. 2.
Fig. 3.
Fig. 4.
Fig. 5.
Fig. 6.

Similar content being viewed by others

REFERENCES

  1. E. N. Kablov, “Innovations of the All-Russian Institute of Aviation Materials (VIAM) as part of implementing the Strategic Directions of Development of Materials and Technologies of Their Processing for the Period up to 2030,” Aviats. Mater. Tekhnol., No. 1, 3–33 (2015). https://doi.org/10.18577/2071-9140-2015-0-1-3-33

  2. A. P. Petrova and G. V. Malysheva, Glues, Adhesive Binders, and Adhesive Prepregs: Textbook (Vseross. Inst. Aviats. Mater., Moscow, 2017) [in Russian].

    Google Scholar 

  3. I. A. Sharova and A. P. Petrova, “A review of the materials of the international conference on adhesives and sealants WAC-2012,” Tr. Vseross. Inst. Aviats. Mater., No. 8 (2013).

  4. E. N. Kablov, V. T. Minakov, and L. I. Anikhovskaya, “Adhesives and materials on their basis for the repair of aircraft structures,” in Aviation Materials and Technologies (Vseross. Inst. Aviats. Mater., Moscow, 2002), No. 1, pp. 61–65 [in Russian].

  5. Yu. A. Treger, K. A. Morozov, G. S. Dasaeva, and A. K. Frolkova, “Chloroprene rubber: Application and preparation,” Fine Chem. Technol., 13 (4), 26–38 (2018).

  6. S. V. Kotova, S. I. Mikhailov, and A. A. Fomina, “Features of today’s nitrile-butadiene rubber market,” Int. Polym. Sci. Technol. 40 (7), 11–13 (2013).

  7. E. G. Milyushkina, L. R. Lyusova, T. V. Monakhova, A. G. Faleev, and A. V. Petrogradskii, “Chelates of metals as adhesion promotors in adhesive compositions based on butadiene-nitrile rubber,” Polym. Sci., Ser. D 11 (3), 284–287 (2018).

  8. S. Kotova, N. Buhtiyarova, and S. Mikhailov, “Improved properties of nitrile butadiene rubber,” Rubber World 248 (5), 18–20 (2013).

  9. A. A. Zuev, L. R. Lusova, and N. P. Boreiko, “Chlorinated isoprene rubbers in adhesive composites,” Int. Polym. Sci. Technol. 44 (5), 25–28 (2017).

  10. S. G. Karpova, E. G. Milyushkina, L. R. Lusova, Yu. A. Naumova, and A. A. Popov, “Influence of the solvent on the formation of CNR/BNR polymer blends,” Russ. J. Phys. Chem. B 12 (2), 285–292 (2018).

  11. O. A. Dulina, A. D. Tarasenko, A. M. Bukanov, and A. A. Il’in, “The influence of the method of rubber isolation from latex on the properties of elastomeric materials based on nitrile butadiene rubbers,” Fine Chem. Technol. 12 (4), 85–90 (2017).

  12. Big Rubberman’s Handbook, Part 2: Rubber and Rubber Products, Ed. by S. V. Reznichenko and Yu. L. Morozov (OOO Izd. tsentr Tekhinform Mezhdunar. Akad. Inf., Moscow, 2012) [in Russian].

  13. V. N. Papkov, et al., Butadiene-Nitrile Rubbers. Synthesis and Properties (Voronezh. Gos. Univ. Inzh. Tekhnol., Voronezh, 2014) [in Russian].

    Google Scholar 

  14. L. R. Lyusova, V. A. Glagolev, V. I. Bukin, A. G. Smirnova, S. V. Kotova, and M. M. Smirnova, RF Patent No. 2383573 (March 10, 2010).

  15. Y. A. Shlyapnikov, S. G. Kiryushkin, and A. P. Mar’in, Antioxidative Stabilization of Polymers (CRC Press, London, 1996).

    Google Scholar 

  16. S. G. Karpova, Y. A. Naumova, V. V. Akimova, L. R. Lyusova, and A. A. Popov, “The effect of the solvent on the molecular dynamics and structure in blended composites of polyurethane and a copolymer of styrene with acrylonitrile,” Int. Polym. Sci. Technol. 42 (1), T15–T19 (2015).

  17. L. I. Belen’kii, New Trends in Thiophene Chemistry (Nauka, Moscow, 1976) [in Russian].

    Google Scholar 

  18. S. H. Sargsyan and K. S. Margaryan, “Polymer chelates of Fe, Co, and Ni based on 5-ethynyl-2H-tetrazole,” Russ. J. Gen. Chem. 84 (7), 1385–1388 (2014).

Download references

CONFLICT OF INTEREST

The authors declare that they have no conflicts of interest.

Author information

Authors and Affiliations

  1. All-Russian Scientific Research Institute of Aviation Materials, 105005, Moscow, Russia

    A. K. Alekhin

  2. MIREA—Russian Technological University, 119454, Moscow, Russia

    L. R. Lyusova, Yu. A. Naumova & S. V. Kotova

  3. N.M. Emanuel Institute of Biochemical Physics, Russian Academy of Sciences, 119334, Moscow, Russia

    T. V. Monakhova

Authors
  1. A. K. Alekhin
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. L. R. Lyusova
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Yu. A. Naumova
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. S. V. Kotova
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. T. V. Monakhova
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Yu. A. Naumova.

Additional information

Translated by I. Moshkin

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Alekhin, A.K., Lyusova, L.R., Naumova, Y.A. et al. Improving the Adhesive Properties of Adhesives Based on a Mixture of Nitrile Butadiene and Chlorinated Rubbers with Metal Chelates. Polym. Sci. Ser. D 13, 26–30 (2020). https://doi.org/10.1134/S1995421220010025

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1995421220010025

Keywords:

Search

Navigation