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Analysis of Curing Rates of Adhesive Compositions Based on Methyl Methacrylate or Styrene and Macroinitiators, Obtained by Radically Initiated Polymerization with the Participation of Metallocenes

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Abstract

Reaction mixtures have been proposed as a basis of adhesive composition for gluing items made of poly(methyl methacrylate) or polystyrene. This composition consists of respective monomers and macroinitiators formed during radically initiated polymerization in the presence of metallocenes. An evaluation of the macroinitiators activity was carried out in postpolymerization of styrene and methyl methacrylate processes (the poly(methyl methacrylate) and polystyrene macroinitiators were considered, they were obtained in two different ways: the first one is during the polymerization with benzoyl peroxide or azobisisobutyronitrile and ferrocene or titanocene dichloride, and the second one is macroinitiators obtained in situ under the influence of UV radiation and in the presence of ferrocene or titanocene dichloride). The optimal methods of preparation and recipe of adhesive compositions were determined from the point of view of the fastest curing rate.

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REFERENCES

  1. COSMO SL-650.110. Acryl Adhesive: Technical Data Sheet (Weiss Chemie + Technik GmbH& Co. KG, Haiger, 2015).

  2. K. A. Tereshchenko, N. V. Ulitin, A. O. Burakova, A. K. Frizen, S. V. Kolesov, D. A. Shiyan, and N. E. Temnikova, “Application prospects of radical-coordination polymerization for production of polymethylmethacrylate as acrylic adhesive component,” Klei, Germetiki, Tekhnol., No. 3, 27–35 (2017) [in Russian].

  3. S. V. Kolesov, I. I. Nasibullin, A. K. Frizen, N. N. Sigaeva, and E. G. Galkin, “Regularities of postpolymerization in a vinyl monomer-metallocene-radical initiator system,” Polym. Sci., Ser. B 57 (2), 71–76 (2015).

    CAS  Google Scholar 

  4. N. N. Sigaeva, A. K. Friesen, I. I. Nasibullin, S. V. Kolesov, and N. L. Ermolaev, “Metallocene catalysis in the complex-radical polymerization of methyl methacrylate,” Kinet. Catal. 53 (4), 470–476 (2012).

    Article  CAS  Google Scholar 

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ACKNOWLEDGMENTS

The research was carried out within the framework of the state task during 2017–2019 (Initiative Scientific Project no. 10.5548.2017/8.9).

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Authors and Affiliations

  1. Kazan National Research Technological University, 420015, Kazan, Russia

    D. A. Shiyan, K. A. Tereshchenko, N. V. Ulitin & A. V. Takhautdinova

  2. Ufa Institute of Chemistry—Subdivision of the Ufa Federal Research Centre of the Russian Academy of Sciences, 450054, Ufa, Russia

    S. V. Kolesov

Authors
  1. D. A. Shiyan
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  2. K. A. Tereshchenko
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  3. N. V. Ulitin
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  4. A. V. Takhautdinova
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  5. S. V. Kolesov
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Corresponding author

Correspondence to N. V. Ulitin.

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1The article was translated by the authors.

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Shiyan, D.A., Tereshchenko, K.A., Ulitin, N.V. et al. Analysis of Curing Rates of Adhesive Compositions Based on Methyl Methacrylate or Styrene and Macroinitiators, Obtained by Radically Initiated Polymerization with the Participation of Metallocenes. Polym. Sci. Ser. D 11, 387–392 (2018). https://doi.org/10.1134/S1995421218040202

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  • DOI: https://doi.org/10.1134/S1995421218040202

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