Skip to main content
SpringerLink
Log in

Radical Bonding Thermoplastics and Materials with Low Surface Energy Using Acrylate Compositions

  • Published:
Polymer Science, Series D Aims and scope Submit manuscript

Abstract

Fundamental studies of radical generation with the participation of trialkylboranes combined with oxygen and organoelemental peroxides were performed. It was shown that a complex process of bonding polymer materials with a low-energy surface occurs predominantly under the action of trialkylborane deblocked from an amine complex and oxygen solved in the adhesive composition. The process of curing the adhesive composition occurs in time both in the volume and on the surface of a substrate, and oxygen is consumed in the first minutes after mixing.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. M. F. Sonneshein, S. P. Webb, P. E. Kastl, et al., Macromolecules 37, 7974–7978 (2004).

    Article  Google Scholar 

  2. H. Okamura, A. Sudo, and T. Endo, Polym. Chem., Part A 47, 6163–6167 (2009).

    Article  CAS  Google Scholar 

  3. M. Zi, Z. Zheng, S. Liu, et al., Int. J. Adhes. Adhes. 31, 36–42 (2011).

    Article  Google Scholar 

  4. M. F. Sonnenshein, S. P. Webb, O. D. Redwine, et al., Macromolecules 39, 2507–2513 (2006).

    Article  Google Scholar 

  5. G. S. Kolesnikov and L. S. Fedorova, Bull. Acad. Sci. USSR., Div. Chem. Sci. 6, 251–252 (1957).

    Article  Google Scholar 

  6. G. S. Kolesnikov and N. V. Klimentova, Bull. Acad. Sci. USSR., Div. Chem. Sci. 6, 666–667 (1957).

    Article  Google Scholar 

  7. G. S. Kolesnikov and L. S. Fedorova, Bull. Acad. Sci. USSR., Div. Chem. Sci. 7, 883 (1958).

    Article  Google Scholar 

  8. J. Furukawa, T. Tsuruta, T. Imada, and H. Furutani, Macromol. Chem. 31 (2), 122–139 (1959).

    Article  Google Scholar 

  9. A. G. Davies and B. R. Roberts, Chem. Commun. (London) 10, 298–299 (1966).

    Article  Google Scholar 

  10. A. G. Davies and B. R. Roberts, J. Chem. Soc. B, 17–22 (1967).

    Google Scholar 

  11. A. G. Davies, K. U. Ingold, B. R. Roberts, and R. Tudor, J. Chem. Soc. B, 698–712 (1971).

    Google Scholar 

  12. Ya. A. Aleksandrov, Transition Regions of Organoelemental Films (Nauka, Moscow, 1978).

    Google Scholar 

  13. Yu. A. Aleksandrov, Organometallic Compounds and Radicals: Collection of Papers, Ed. by M. I. Kabachnik (Nauka, Moscow, 1985), pp. 72–85 [in Russian].

  14. M. Yu. Zaremskii, D. V. Budanov, S. A. Romanov, A. V. Plutalova, E. S. Garina, V. B. Golubev, S. Yu. Erdyakov, M. E. Gurskii, and Yu. N. Bubnov, Polym. Sci., Ser. B 53, 1–79 (2011).

    Article  Google Scholar 

  15. M. Yu. Zaremskii, E. S. Garina, M. E. Gurskii, and Yu. N. Bubnov, Polym. Sci., Ser. B 55, 304–326 (2013).

    Article  Google Scholar 

  16. P. B. Brindley, “Organometallic peroxides,” in Peroxides, (Wiley, New York, 1983), Chap. 23, pp. 807–826.

    Chapter  Google Scholar 

  17. C. Ollivier and P. Renaund, Chem. Rev. 101, 3415–3434 (2001).

    Article  CAS  Google Scholar 

  18. Yu. A. Aleksandrov, G. N. Figurova, V. A. Dodonov, and G. A. Razuvaev, Dokl. Akad. Nauk SSSR 195, 1091–1093 (1970).

    CAS  Google Scholar 

  19. G. I. Makin, V. P. Maslennikov, and Yu. A. Aleksandrov, Zh. Obshch. Khim. 44, 1278–1281 (1974).

    CAS  Google Scholar 

  20. V. N. Alyasov, V. P. Maslennikov, and Yu. A. Aleksandrov, Radical Reactions of Organometallic Compounds (Gorky State Univ., Gorky, 1986), pp. 64–79 [in Russian].

    Google Scholar 

  21. T. C. M. Chung, W. Janvikul, and H. L. Lu, J. Am. Chem. Soc. 118 (3), 705–706 (1996).

    Article  CAS  Google Scholar 

  22. T. C. M. Chung, Polym. News 28 (8), 238 (2003).

    CAS  Google Scholar 

  23. G. V. Korolev and A. P. Marchenko, Russ. Chem. Rev. 69, 409–434 (2000).

    Article  CAS  Google Scholar 

  24. G. A. Razuvaev, M. A. Lopatin, and V. A. Dodonov, Zh. Obshch. Khim. 48 (11), 2494–2500 (1978).

    CAS  Google Scholar 

  25. V. A. Dodonov, D. F. Grishin, V. K. Cherkasov, and G. A. Razuvayev, Polym. Sci. U.S.S.R. 24, 493 (1982).

    Article  Google Scholar 

  26. G. A. Razuvaev, V. A. Dodonov, V. G. Tsvetkov, et al., Vysokomol. Soedin. B 30 (2), 146–150 (1988).

    CAS  Google Scholar 

  27. I. N. Aksenova, Candidate’s Dissertation in Chemistry (Gorky, 1987).

    Google Scholar 

  28. L. L. Semenycheva, Candidate’s Dissertation in Chemistry (Gorky, 1989).

    Google Scholar 

  29. Z. V. Orlova, Candidate’s Dissertation in Chemistry (Dzerzhinsk, 1983).

    Google Scholar 

  30. Yu. V. Zharov, Candidate’s Dissertation in Chemistry (Gorky, 1989).

    Google Scholar 

  31. V. A. Dodonov, O. S. Morozov, D. F. Grishin, and E. G. Lyutin, Dokl. Akad. Nauk SSSR 255, 1123–1127 (1980).

    CAS  Google Scholar 

  32. V. A. Dodonov, D. F. Grishin, O. S. Morozov, and V. K. Cherkasov, Zh. Obshch. Khim. 52 (1), 71–78 (1981).

    Google Scholar 

  33. V. A. Dodonov, S. S. Lomakin, and M. V. Gulenova, Klei, Germetiki, Tekhnol., No. 11, 29–33 (2013).

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Lobachevsky State University of Nizhny Novgorod, Nizhny Novgorod, 603950, Russia

    V. A. Dodonov & T. I. Starostina

Authors
  1. V. A. Dodonov
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. T. I. Starostina
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to V. A. Dodonov.

Additional information

Original Russian Text © V.A. Dodonov, T.I. Starostina, 2017, published in Klei, Germetiki, Tekhnologii, 2017, No. 1, pp. 5–12.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Dodonov, V.A., Starostina, T.I. Radical Bonding Thermoplastics and Materials with Low Surface Energy Using Acrylate Compositions. Polym. Sci. Ser. D 11, 60–66 (2018). https://doi.org/10.1134/S1995421218010069

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1995421218010069

Keywords

Search

Navigation