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Oxidative Cracking of Propane in a Plug-Flow Laboratory Reactor

  • KINETICS AND MECHANISM OF CHEMICAL REACTIONS, CATALYSIS
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Abstract

This paper presents the results of experiments on the oxidative cracking of propane at a pressure of 1 to 2 atm and moderate temperatures (T ≤ 1000 K) in a laboratory-scale reactor. Nitrogen and methane are used as the diluent gases. Kinetic models are analyzed to describe the studied process. The necessity of taking into account heterogeneous reactions on the reactor surface is shown. The introduction of additional stages in the kinetic model, which take into account heterogeneous reactions on the reactor surface, makes it possible to obtain an almost quantitative agreement between the calculations and experimental results.

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Funding

The study was financially supported by the Russian Foundation for Basic Research and the Science Committee of the Republic of Armenia as part of scientific project no. 20-53-05001.

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Authors and Affiliations

  1. Semenov Federal Research Center of Chemical Physics, Russian Academy of Sciences, Moscow, Russia

    A. S. Palankoeva, A. A. Belyaev & V. S. Arutyunov

  2. Moscow State University, Moscow, Russia

    A. S. Palankoeva & V. S. Arutyunov

  3. Institute of Problems of Chemical Physics, Russian Academy of Sciences, Chernogolovka, Russia

    V. S. Arutyunov

Authors
  1. A. S. Palankoeva
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  2. A. A. Belyaev
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  3. V. S. Arutyunov
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Correspondence to A. S. Palankoeva.

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Palankoeva, A.S., Belyaev, A.A. & Arutyunov, V.S. Oxidative Cracking of Propane in a Plug-Flow Laboratory Reactor. Russ. J. Phys. Chem. B 16, 399–406 (2022). https://doi.org/10.1134/S1990793122030204

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  • DOI: https://doi.org/10.1134/S1990793122030204

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