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Role of Spectral Line Profile in Laser IR Analysis of Multicomponent Gas Mixtures

  • STRUCTURE OF CHEMICAL COMPOUNDS, QUANTUM CHEMISTRY, AND SPECTROSCOPY
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Abstract

Topical issues of the quantitative analysis of multicomponent gas mixtures with use of laser absorption infrared technologies are addressed. It is shown that a number of questions exist regarding the detection of pollutants using these technologies, and these concern not only the position of the center of the analytical line of the detected substance but also the shape of its profile, especially in case of strong intermolecular interactions under conditions of open atmosphere. A number of examples show various aspects of the influence of the error of the spectroscopic model embedded in the solution of the inverse problem (the width and shape of the laser spectral line and gas absorption lines) on the determination of gas concentrations. The parameters of the sensitivity and selectivity of laser gas analysis that support making the optimal choice of laser radiation frequencies for studying specific gas mixtures are discussed. The importance of the high monochromaticity of laser lines, the smooth tuning of the radiation frequency over a wide spectral range, and the adequate simulation of the IR spectra of multicomponent gas mixtures are demonstrated.

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ACKNOWLEDGMENTS

The contribution of S.V. Ivanov in the part of infrared laser gas analyzers and absorption line shapes was supported by the Ministry of Science and Higher Education of the Russian Federation within State Assignment for Federal Research Center Crystallography and Photonics, Russian Academy of Sciences.

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Authors and Affiliations

  1. National Research Center Kurchatov Institute, Moscow, Russia

    Sh. Sh. Nabiev, A. S. Lagutin & L. A. Palkina

  2. Federal Research Center Crystallography and Photonics, Russian Academy of Sciences, Moscow, Russia

    S. V. Ivanov

  3. Moscow Institute of Physics and Technology, Moscow, Russia

    S. V. Malashevich

  4. Semenov Institute of Chemical Physics, Russian Academy of Sciences, Moscow, Russia

    O. A. Ol’khov & M. G. Golubkov

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  1. Sh. Sh. Nabiev
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  2. S. V. Ivanov
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  3. A. S. Lagutin
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  4. L. A. Palkina
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  5. S. V. Malashevich
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  6. O. A. Ol’khov
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  7. M. G. Golubkov
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Correspondence to Sh. Sh. Nabiev.

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This study was carried out within State Assignment of the Ministry of Science and Higher Education of the Russian Federation (topic 0082-2019-0017, registration no. AAAA-A19-119010990034-5).

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Translated by O. Kadkin

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Nabiev, S.S., Ivanov, S.V., Lagutin, A.S. et al. Role of Spectral Line Profile in Laser IR Analysis of Multicomponent Gas Mixtures. Russ. J. Phys. Chem. B 13, 727–738 (2019). https://doi.org/10.1134/S1990793119050191

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