Skip to main content
Log in

Dissociative Excitation of Odd Triplet Levels of a Nickel Atom by Collisions of Electrons with Nickel Dibromide Molecules

  • ELEMENTARY PHYSICOCHEMICAL PROCESSES
  • Published:
Russian Journal of Physical Chemistry B Aims and scope Submit manuscript

Abstract

The dissociative excitation of the odd triplet levels of a nickel atom by the collisions of electrons with nickel dibromide molecules is investigated using extended crossing beams and recording the optical signal of the excited atoms. In all, 50 excitation cross-sections of Ni I spectral lines are measured at an electron energy of 100 eV. Nine optical excitation functions (OEFs) are recorded in a range of electron energies of 0–100 eV. The obtained data on the dissociative excitation cross-sections of the spectral lines are used for the calculation of the excitation cross-sections of the energy levels as well as the contribution from the cascade transitions. The possible channels of dissociative excitation which manifest themselves in the region of low electron energies (E < 22 eV) are discussed.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1.
Fig. 2.

Similar content being viewed by others

REFERENCES

  1. Yu. M. Smirnov, Russ. J. Phys. Chem. B 4, 8 (2010).

    Article  Google Scholar 

  2. Yu. M. Smirnov, SOP Trans. Phys. Chem. 1 (3), 1 (2014). https://doi.org/10.15764/PCHE.2014.03.001

    Article  Google Scholar 

  3. Yu. M. Smirnov, J. Phys. B: At. Mol. Opt. Phys. 48, 165204 (2015).

    Article  CAS  Google Scholar 

  4. Yu. M. Smirnov, J. Phys. B: At. Mol. Opt. Phys. 49, 175204 (2016).

    Article  CAS  Google Scholar 

  5. E. I. Nepiipov and L. L. Shimon, Ukr. Fiz. Zh. 18, 539 (1973).

    CAS  Google Scholar 

  6. A. N. Kuchenev, E. A. Samsonova, and Yu. M. Smirnov, Avtometriya, No. 5, 109 (1990).

    Google Scholar 

  7. C. E. Wicks and F. E. Block, Thermodynamic Properties of 65 Elements—Their Oxides, Halides, Carbides, and Nitrides (US Dept. of Interior, Washington, DC, 1961), pp. 66, 100, 142.

    Google Scholar 

  8. L. V. Gurvich, G. V. Karachentsev, and V. N. Kondrat’ev, Energy of Chemical Bond Cleavage; Ionization Potentials and Affinity to the Electron (Nauka, Moscow, 1974), p. 314 [in Russian].

    Google Scholar 

  9. U. Litzen, J. W. Brault, and A. P. Thorne, Phys. Scr. 47, 628 (1993).

    Article  CAS  Google Scholar 

  10. K. S. Krasnov, N. V. Filippenko, V. A. Bobkova, N. L. Lebedeva, E. V. Morozov, T. I. Ustinova, and G. A. Romanova, Molecular Constants of Inorganic Compounds, The Handbook (Khimiya, Leningrad, 1979), p. 140 [in Russian].

    Google Scholar 

  11. W. M. Huo and Y.-K. Kim, IEEE Trans. Plasma Sci. 27, 1225 (1999).

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Yu. M. Smirnov.

Additional information

Translated by E. Boltukhina

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Smirnov, Y.M. Dissociative Excitation of Odd Triplet Levels of a Nickel Atom by Collisions of Electrons with Nickel Dibromide Molecules. Russ. J. Phys. Chem. B 13, 438–444 (2019). https://doi.org/10.1134/S1990793119030114

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1990793119030114

Keywords:

Navigation