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Application of selective two-dimensional exchange NMR spectroscopy to the study of molecular dynamic processes

  • Structure of Chemical Compounds. Spectroscopy
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Abstract

A vector model of the multiplet-selective excitation of spin systems by a three-pulse sequence is considered, and, on this basis, a new two-dimensional exchange NMR spectroscopy technique is suggested. This technique provides means to investigate intramolecular and intermolecular chemical and spin exchanges by observing the dynamic behavior of the multiplet pattern of a nucleus that is scalarwise coupled with the unobservable nucleus undergoing exchange.

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Authors and Affiliations

  1. Institute of Physical and Organic Chemistry, Southern Federal University, pr. Stachki 194/2, Rostov-on-Don, 344090, Russia

    G. S. Borodkin & Yu. E. Chernysh

  2. Kuban State University, Stavropol’skaya ul. 149, Krasnodar, 360040, Russia

    V. A. Volynkin & V. T. Panyushkin

Authors
  1. G. S. Borodkin
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  2. Yu. E. Chernysh
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  3. V. A. Volynkin
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  4. V. T. Panyushkin
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Corresponding author

Correspondence to Yu. E. Chernysh.

Additional information

Original Russian Text © G.S. Borodkin, Yu.E. Chernysh, V.A. Volynkin, V.T. Panyushkin, 2015, published in Khimicheskaya Fizika, 2015, Vol. 34, No. 4, pp. 6–19.

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Borodkin, G.S., Chernysh, Y.E., Volynkin, V.A. et al. Application of selective two-dimensional exchange NMR spectroscopy to the study of molecular dynamic processes. Russ. J. Phys. Chem. B 9, 172–184 (2015). https://doi.org/10.1134/S1990793115020190

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  • DOI: https://doi.org/10.1134/S1990793115020190

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