Abstract
A new method for the preparation of ionic phosphite ligands is developed. A first example of the use of this type of ligands in the hydroformylation catalyzed by rhodium complexes and conducted in organic solvents, an ionic liquid (IL), and supercritical carbon dioxide (SC-CO2) is described. It is shown that conducting the reaction in ionic liquid/supercritical carbon dioxide biphasic system may aid in increasing its rate.
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Original Russian Text © S.E. Lyubimov, E.A. Rastorguev, V.A. Davankov, 2013, published in Sverkhkriticheskie Flyuidy: Teoriya i Praktika, 2013, Vol. 8, No. 3, pp. 12–18.
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Lyubimov, S.E., Rastorguev, E.A. & Davankov, V.A. The use of a new ionic phosphite ligand in the hydroformylation catalyzed by rhodium complexes: Effect of reaction media. Russ. J. Phys. Chem. B 8, 953–957 (2014). https://doi.org/10.1134/S1990793114070094
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DOI: https://doi.org/10.1134/S1990793114070094