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Polymerization of Tricyclononenes

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Abstract

The expansion of the range of available and reactive monomers allowing preparation of novel polymeric materials, is an actual task of polymer chemistry. This mini-review is devoted to the polymerization of tricyclo [4.2.1.02,5]non-7-enes (tricyclononenes) and tricyclo[4.2.1.02,5]nona-3,7-dienes (tricyclonona-dienes)–norbornene type monomers containing norbornene and cyclobutane or cyclobutene fragments in the molecules. Their synthesis is carried out using available cyclopentadiene or quadricyclane, which is a product of norbornadiene photo-isomerization. The features of ring-opening metathesis and addition polymerization of tricyclononenes with participation of double bond in the norbornene fragment are highlighted. Examples of the polymerization of a wide range of tricyclononenes with F-, Si-, O-, and N-containing substituents have demonstrated that they are noticeably more active monomers than norbornenes with the same substituents. The main successes have been achieved in the synthesis of F- and Si-substituted polytricyclononenes, which are promising materials for lithography and membrane gas separation.

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ACKNOWLWDGMENTS

This work was conducted within the framework of State Assignment for the Institute of Petrochemical Synthesis, Russian Academy of Sciences.

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Authors and Affiliations

  1. A.V. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, 119991 , Moscow, Russia

    E. Sh. Finkelshtein, P. P. Chapala & M. L. Gringolts

  2. Thomas Swan and Co. Ltd., Rotary Way, DH8 7ND, Consett, UK

    Yu. V. Rogan

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  1. E. Sh. Finkelshtein
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  2. P. P. Chapala
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  3. M. L. Gringolts
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  4. Yu. V. Rogan
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Correspondence to E. Sh. Finkelshtein or P. P. Chapala.

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Finkelshtein, E.S., Chapala, P.P., Gringolts, M.L. et al. Polymerization of Tricyclononenes. Polym. Sci. Ser. C 61, 17–30 (2019). https://doi.org/10.1134/S1811238219010077

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  • DOI: https://doi.org/10.1134/S1811238219010077

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