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Some Aspects of Cu(0)-Mediated Radical Polymerization

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Abstract

Certain quantitative parameters characterizing the Cu(0)-mediated SET polymerization of methyl acrylate, that is, the kinetic orders of the polymerization rate with respect to the concentration of the monomer and initiator and the rate constants of initiation under various conditions, are determined. A method for the separate determination of Cu(I) and Cu(II) ions during polymerization is developed. A new effective form of the catalyst, a copper mirror, is proposed, which makes it possible to multiply the specific rate of polymerization and decrease the residual copper content in the polymer.

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Notes

  1. Complete dissolution of Ag2O is required, otherwise, at the second stage, instead of covering the walls of the vessel, copper will precipitate.

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Funding

The study was carried out under the project Modern Problems of Chemistry and Physical Chemistry of Macromolecular Compounds (State Budget no. АААА-А16-116031050014-6).

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Authors and Affiliations

  1. Faculty of Chemistry, Moscow State University, 119992, Moscow, Russia

    M. Yu. Zaremskii, E. A. Bukin, K. O. Mineeva & S. B. Zezin

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  1. M. Yu. Zaremskii
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  2. E. A. Bukin
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  3. K. O. Mineeva
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  4. S. B. Zezin
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Correspondence to M. Yu. Zaremskii.

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Zaremskii, M.Y., Bukin, E.A., Mineeva, K.O. et al. Some Aspects of Cu(0)-Mediated Radical Polymerization. Polym. Sci. Ser. B 62, 583–596 (2020). https://doi.org/10.1134/S1560090420060123

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