Skip to main content
Log in

Synthesis and Study of Poly(ether-amide)s Containing Aromatic and Aliphatic Ether-Amine Segment and Isophthalic Acid

  • Synthesis
  • Published:
Polymer Science, Series B Aims and scope Submit manuscript

Abstract

The paper describes some physical properties of poly(ether-amide)s (PEAs) prepared by solution polycondensation reaction of ether-amines such as 2,7-bis(4-aminophenoxy) naphthalene, 2,2-bis[4-(4-aminophenoxy)phenyl] propane, 1,4-bis(4-aminophenoxy methyl) cyclohexane and isophthalic acid. Resulting PEAs are high yield and have inherent viscosity ranging between 0.68–0.75 dL/g. The etheramines containing wholly, semi aromatic and aliphatic-aromatic segments were prepared by using two steps reaction. FTIR, 1H NMR, and elemental analyses were used for characterization of synthetic ether-amines and poly(ether-amide)s. PEAs films were prepared by solution casting technique then their thermal stability and mechanical properties were measured. TGA in nitrogen atmosphere shows that the PEAs are thermally stability, so 10% weight will be lost in the range of 335–358°C. Tensile strength and elongation at break of the PEA films ranged from 71.1–65.0 MPa and 6.48–8.41%, respectively.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. J. Lin and D. Sherrington, “Recent Developments in the Synthesis, Thermostability and Liquid Crystal Properties of Aromatic Polyamides”, in Polymer Synthesis. Advances in Polymer Science (Springer, Berlin, Heidelberg, 1994), Vol. 111, pp. 177–219.

    CAS  Google Scholar 

  2. P. E. Cassidy, Thermally Stable Polymers: Synthesis and Properties (Marcel Dekker, New York, 1980), pp. 110–116.

    Google Scholar 

  3. H. H Yang, Aromatic High-Strength Fibers (Wiley and Sons, New York, 1989).

    Google Scholar 

  4. R. B. Seymour and C. E. Carraher, Polymer Chemistry: an Introduction (Marcel Dekker, New York, 1981).

    Google Scholar 

  5. K. Faghihi, A. Raeisi, and H. Ardeshir Geravi, Fibers Polym. 18, 1 (2017).

    Article  CAS  Google Scholar 

  6. C.-P. Yang and J.-H. Lin, J. Polym. Sci., Part A: Polym. Chem. 34, 341 (1996).

    Article  CAS  Google Scholar 

  7. S. Mehdipour-Ataei and H. Heidari, Macromol. Symp. 193, 159 (2003).

    Article  CAS  Google Scholar 

  8. S.-H. Hsiao and K.-H. Lin, Polymer 45, 7877 (2004).

    Article  CAS  Google Scholar 

  9. H. S. Lee and S. Y. Kim, Macromol. Rapid Commun. 23, 665 (2002).

    Article  CAS  Google Scholar 

  10. A. Shockravi, S. Mehdipour-Ataei, E. Abouzari-Lotf, and A. Yousefi, Eur. Polym. J. 42, 133 (2006).

    Article  CAS  Google Scholar 

  11. K. Faghihi, M. Hajibeygi, and M. Shabanian, Macromol. Res. 17, 739 (2009).

    Article  CAS  Google Scholar 

  12. K. Faghihi, M. Hajibeygi, and M. Shabanian, J. Macromol. Sci., Part A: Pure Appl. Chem. 47, 144 (2010).

    Article  CAS  Google Scholar 

  13. C. D. Diakoumakos and J. A. Mikroyannidis, Polymer 35, 1986 (1994).

    Article  CAS  Google Scholar 

  14. K. Faghihi, M. Hajibeygi, and M. Shabanian, Macromol. Res. 18, 421 (2010).

    Article  CAS  Google Scholar 

  15. K. Faghihi, M. Shabanian, and M. Hajibeygi, Macromol. Res. 17, 912 (2009).

    Article  CAS  Google Scholar 

  16. S. Mallakpour and E. Kowsari, Polym. Bull. 53, 169 (2005).

    Article  CAS  Google Scholar 

  17. M. Shabanian, K. Faghihi, A. Raeisi, M. Varvanifarahani, H. A. Khonakdar, and U. Wagenknecht, J. Therm. Anal. Calorim. 117, 293 (2014).

    Article  CAS  Google Scholar 

  18. N. Yamazaki and F. Higashi, J. Polym. Sci., Part C: Polym. Lett. 12, 185 (1974).

    CAS  Google Scholar 

  19. N. Yamazaki, M. Matsumoto, and F. Higashi, J. Polym. Sci., Polym. Chem. Ed. 13, 1373 (1975).

    Article  CAS  Google Scholar 

  20. I. K. Varma, R. Kumar, and A. B. Bhattacharyya, J. Appl. Polym. Sci. 40, 531 (1990).

    Article  CAS  Google Scholar 

  21. C. T. Vijayakumar, R. Surender, K. Rajakumar, and S. Alam, J. Therm. Anal. Calorim. 103, 693 (2011).

    Article  CAS  Google Scholar 

  22. S. Maji and S. Banerjee, J. Membr. Sci. 349, 145 (2010).

    Article  CAS  Google Scholar 

  23. A. Mirsamieia, K. Faghihia, and M. Shabanian, Polym. Adv. Technol. 28, 779 (2017).

    Article  CAS  Google Scholar 

  24. D. H. Wang, J. J. Wie, K. M. Lee, T. J. White, and L.-S. Tan, Macromolecules 47, 659 (2014).

    Article  CAS  Google Scholar 

  25. P. C. P. Watts, P. K. Fearon, W. K. Hsu, N. C. Billingham, H. W. Kroto, and D. R. M. Walton, J. Mater. Chem. 13, 491 (2003).

    Article  CAS  Google Scholar 

  26. H. A. Shawky, J. Membr. Sci. 339, 209 (2009).

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Khalil Faghihi.

Additional information

The article is published in the original.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Mirsamiei, A., Faghihi, K. & Nanbedeh, S. Synthesis and Study of Poly(ether-amide)s Containing Aromatic and Aliphatic Ether-Amine Segment and Isophthalic Acid. Polym. Sci. Ser. B 60, 273–282 (2018). https://doi.org/10.1134/S1560090418030156

Download citation

  • Received:

  • Revised:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1560090418030156

Navigation