Abstract
Protic oligomeric cationic ionic liquids of the oligo(ether urethane) type are synthesized via the reaction of an isocyanate prepolymer based on oligo(oxy ethylene)glycol with M = 1000 with hexamethylene-diisocyanate followed by blocking of the terminal isocyanate groups with the use of amine derivatives of imidazole, pyridine, and 3-methylpyridine and neutralization of heterocycles with ethanesulfonic acid and p-toluenesulfonic acid. The structures and properties of the synthesized oligomeric ionic liquids substantially depend on the structures of the ionic groups. They are amorphous at room temperature, but ethanesulfonate imidazolium and pyridinium oligomeric ionic liquids form a low melting crystalline phase. The proton conductivities of the oligomeric ionic liquids are determined by the type of cation in the temperature range 80–120°C under anhydrous conditions and vary within five orders of magnitude. The resulting compounds are thermally stable up to 200–270°C.
Similar content being viewed by others
References
D. Mecerreyes, Prog. Polym. Sci. 36(12), 1629 (2011).
J. Yuan, D. Meccerreyes, and M. Antonietti, Prog. Polym. Sci. 38(7), 1009 (2013).
A. S. Shaplov, E. I. Lozinskaya, and Y. S. Vygodskii, Polymer Ionic Liquids (PILs): Synthesis, Design and Application in Electrochemistry as Ion Conducting Materials, Ed. by A. A. J. Torriero and M. Shiddiky, (Nova Science Publ. Inc, New York, 2011), p. 203.
B. Kerscher, A. -K. Appel, R. Thomann, and R. Mulhaupt, Macromolecules 46(11), 4395 (2013).
M. R. Imam, M. Peterca, U. Edlund, et al., J. Polym. Sci., Part A: Polym. Chem. 47(16), 4165 (2009).
A. S. Shaplov, D. O. Ponkratov, P. S. Vlasov, et al., Polym. Sci., Ser. B 55(3–4), 122 (2013).
S. M. Mezhikovskii, A. E. Arinshtein, and R. Ya. Deberdeev, Oligomeric State of Compound (Nauka, Moscow, 2005) [in Russian].
J. P. Hallett and T. Welton, Chem. Rev. 111(5), 3508 (2011).
J. L. Bideau, L. Viau, and A. Vioux, Chem. Soc. Rev. 40(2), 907 (2011).
T. L. Greaves and C. J. Drummond, Chem. Rev. 108(1), 206 (2008).
K. Xu and C. A. Angell, Electrochim. Acta 40(13–14), 2401 (1995).
H. Ohno and K. Ito, Polymer 36(4), 891 (1995).
K. Ito and H. Ohno, Solid State Ionics 79, 300 (1995).
K. Ito, N. Nishina, and H. Ohno, J. Mater. Chem. 7(8), 1357 (1997).
K. Ito, Y. Tominaga, and H. Ohno, Electrochim. Acta 42(10), 1561 (1997).
Y. Nakai, K. Ito, and H. Ohno, Solid State Ionics 113–115, 199 (1998).
Yu. S. Lipatov, A. E. Fainerman, V. A. Shrubovich, and B. B. Shevchenko, Dokl. AN USSR. B, No. 10, 41 (1984).
Yu. S. Lipatov, A. E. Fainerman, B. B. Shevchenko, and V. A. Shrubovich, Vysokomol. Soedin., Ser. A 29(3), 562 (1987).
Yu. S. Lipatov, B. B. Shevchenko, and A. E. Fainerman, Dokl. Akad. Nauk SSSR 306(2), 360 (1989).
Yu. S. Lipatov, V. V. Shevchenko, and A. E. Feinerman, Ukr. Polym. J. 2(2), 85 (1993).
K. -I. Kato, K. Ito-Akita, and H. J. Ohno, Solid State Electrochem. 4(3), 141 (2000).
Y. Tominaga, T. Mizumo, and H. Ohno, Polym. Adv. Technol. 11(8–12), 524 (2000).
M. Yoshizawa and H. Ohno, Electrochim. Acta 46(10–11), 1723 (2001).
M. Wang, Y. Lin, and X. Zhou, Mater. Chem. Phys. 107(1), 61 (2008).
J. J. R. Stalgren, V. Pamedytyte, R. Makuska, et al., Polym. Int. 52(3), 399 (2003).
X. Zhang, L. Hong, and Z. Liu, Mater. Res. Soc. Symp. Proc. 923, 0923-V05–08 (2006).
E. Stathatos, V. Jovanovski, B. Orel, et al., J. Phys. Chem. C 111(17), 6528 (2007).
V. Jovanovski, B. Orel, R. Jese, et al., J. Phys. Chem. B 109(30), 14387 (2005).
J. Tan, D. Ma, X. Sun, et al., Dalton Trans. 42(13), 4337 (2013).
J. -H. Jeon, K. Tanaka, and Y. Chujo, RSC Adv 3(7), 2422 (2013).
K. Tanaka, F. Ishiguro, and Y. Chujo, J. Am. Chem. Soc. 13(50), 17649 (2010).
K. Tanaka and Y. Chujo, Polym. J. 45(3), 247 (2013).
E. Schwab and S. Mecking, J. Polym. Sci., Part A: Polym. Chem. 43(19), 4609 (2005).
M. Tamaki, T. Taguchi, and Y. Kitajyo, J. Polym. Sci., Part A: Polym. Chem. 47(24), 7032 (2009).
F. Schüler, B. Kerscher, F. Beckert, et al., Angew. Chem., Int. Ed. 52(1), 455 (2013).
C. Chen and X. Fang, J. Appl. Polym. Sci. 117(6), 3539 (2010).
Y. Du, Q. Chen, L. Shen, et al., J. Appl. Polym. Sci. 121(5), 2927 (2011).
M. R. Imam, M. Peterca, U. Edlund, et al., J. Polym. Sci., Part A: Polym. Chem. 47(16), 4165 (2009).
M. A. Castriciano, N. Leone, P. Cardiano, et al., J. Mater. Chem. 1(31), 4746 (2013).
Y. Wang, J. Luo, and L. Zuliang, J. Org. Chem. 739, 1 (2013).
Y. Liu, C. Leng, B. Chisholm, et al., Langmuir 29(9), 2897 (2013).
D.-W. Seo, S. Sarker, D. N. N. Chandra, et al., Electrochim. Acta 55(4), 1483 (2010).
B. A. Dombrow, Polyurethanes (Reinhold Publ.Corp., New York, 1957).
M. Michau and M. Barboiu, J. Mater. Chem. 19(34), 6124 (2009).
L. J. Bellamy, The Infrared Spectra of Complex Molecules (Springer, Netherlands, 1980).
E. Pretsch, F. Büllmann, and K. Affolter, Structure Determination of Organic Compounds: Tables of Spectral Data (Springer, Heidelberg, 2000).
R. Marcilla, J. A. Blazquez, J. Rodriguez, et al., J. Polym. Sci., Part A: Polym. Chem. 42(1), 208 (2004).
J. D. Menczel and R. B. Prime, Thermal Analysis of Polymers. Fundamentals and Applications (Wiley, New York, 2009).
A. Kyritsis, P. Pissis, and J. Grammatikakis, J. Polym. Sci., Part B: Polym. Phys. 33(12), 1737 (1995).
Author information
Authors and Affiliations
Corresponding author
Additional information
Original Russian Text © V.V. Shevchenko, A.V. Stryutsky, N.S. Klymenko, M.A. Gumennaya, A.A. Fomenko, V.V. Trachevsky, V.V. Davydenko, V.N. Bliznyuk, A.V. Dorokhin, 2014, published in Russian in Vysokomolekulyarnye Soedineniya, Ser. B, 2014, Vol. 56, No. 5, pp. 480–489.
Rights and permissions
About this article
Cite this article
Shevchenko, V.V., Stryutsky, A.V., Klymenko, N.S. et al. Protic cationic oligomeric ionic liquids of the urethane type. Polym. Sci. Ser. B 56, 583–592 (2014). https://doi.org/10.1134/S156009041405011X
Received:
Revised:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S156009041405011X