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Synthesis and physicochemical properties of copolymers of aniline and 3,4-ethylenedioxythiophene

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Abstract

Copolymers of various compositions have been synthesized via copolymerization of aniline with 3,4-ethylenedioxythiophene in the presence of a poly(4-styrenesulfonic acid) matrix, and a mechanism of copolymerization has been suggested. It has been shown that the synthesized copolymers are included in non-stoichiometric interpolyelectrolyte complexes with matrices stabilized by salt bonds and nonionic interactions. The copolymers of aniline and ethylenedioxythiophene possess electrical conductivity and can enter into redox and acid-base reactions.

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Authors and Affiliations

  1. Faculty of Chemistry, Moscow State University, Moscow, 119991, Russia

    A. V. Kubarkov, O. A. Pyshkina & V. G. Sergeyev

Authors
  1. A. V. Kubarkov
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  2. O. A. Pyshkina
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  3. V. G. Sergeyev
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Correspondence to A. V. Kubarkov.

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Original Russian Text © A.V. Kubarkov, O.A. Pyshkina, V.G. Sergeyev, 2014, published in Russian in Vysokomolekulyarnye Soedineniya, Ser. B, 2014, Vol. 56, No. 3, pp. 334–342.

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Kubarkov, A.V., Pyshkina, O.A. & Sergeyev, V.G. Synthesis and physicochemical properties of copolymers of aniline and 3,4-ethylenedioxythiophene. Polym. Sci. Ser. B 56, 360–368 (2014). https://doi.org/10.1134/S1560090414030117

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  • DOI: https://doi.org/10.1134/S1560090414030117

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