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Synthesis and thermophysical studies of polyanilines

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Abstract

Aniline was polymerized under different experimental conditions such as interfacial polymerization, rapid mixing in hydrochloric acid medium and classical bulk polymerization method using p-toluene sulphonic acid. The resulting polyanilines were characterized by infrared, X-ray diffraction, conductance and scanning electron microscopic analysis. The main emphasis of the paper is to study the thermal response of the synthesized polyanilines by thermogravimetric analysis and differential scanning calorimetry (DSC). The DSC data were utilized further to calculate the specific heat capacities of the synthesized polyanilines as a function of temperature.

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References

  1. Stejskal J and Gilbert R G 2002 Pure Appl. Chem. 74 857

    Article  CAS  Google Scholar 

  2. Chiang J C and MacDiarmid A G 1986 Synth. Met. 13 193

    Article  CAS  Google Scholar 

  3. MacDiarmid A G, Yang L S, Huang W S and Humphrey B D 1987 Synth. Met. 18 393

    Article  CAS  Google Scholar 

  4. McCall R P, Ginder J M, Leng J M, Coplin K A, Ye H J, Epstein A J et al 1991 Synth. Met. 41 1329

    Article  CAS  Google Scholar 

  5. Trivedi D C and Dhawan S K 1993 Synth. Met. 59 267

    Article  CAS  Google Scholar 

  6. Makeiff D A and Huber T 2006 Synth. Met. 156 497

    Article  CAS  Google Scholar 

  7. Dutta D, Sarma T K, Chowdhury D and Chattopadhyay A 2005 J. Colloid Interface Sci. 283 153

    Article  CAS  Google Scholar 

  8. Drelinkiewicz A, Waksmundzka-Gora A, Sobczak J W and Stejskal J 2007 Appl. Catal. A: Gen. 333 219

    Article  CAS  Google Scholar 

  9. Zhao C, Xing S, Yu Y, Zhang W and Wang C 2007 Microelectron. J. 38 316

    Article  CAS  Google Scholar 

  10. Willner I, Willner B and Katz E 2007 Bioelectrochemistry 70 2

    Article  CAS  Google Scholar 

  11. Blinova N V, Stejskal J, Trchova M, Ciric-Marjanovic G and Sapurina I 2007 J. Phys. Chem. B 111 2440

    Article  CAS  Google Scholar 

  12. Sun L J, Liu X X, Lau K K T, Chen L and Gu W M 2008 Electrochim. Acta. 53 3036

    Article  CAS  Google Scholar 

  13. Bessiere A, Duhamel C, Badot J C, Lucas V and Certiat M C 2004 Electrochim. Acta 49 2051

    Article  CAS  Google Scholar 

  14. Halvorson C, Cao Y, Moses D and Heeger A J 1993 Synth. Met. 57 3941

    Article  CAS  Google Scholar 

  15. Wang H L, MacDiarmid A G, Wang Y Z, Gebier D D and Epstein A J 1996 Synth. Met. 78 33

    Article  CAS  Google Scholar 

  16. Kaneto K, Kaneko M, Min Y and MacDiarmid A G 1995 Synth. Met. 71 2211

    Article  CAS  Google Scholar 

  17. Soto-Oviedo M A, Araujo O A, Faez R, Rezende M C and DePaoli M A 2006 Synth. Met. 156 1249

    Article  CAS  Google Scholar 

  18. Kalendova A, Vesely D and Stejskal J 2008 Progr. Org. Coat. 62 105

    Article  CAS  Google Scholar 

  19. Stejskal J, Kratochvıl P and Jenkins A D 1996 Polymer 37 367

    Article  CAS  Google Scholar 

  20. Christina O B, Xinwei H, Wyatt N and Richard B K 2017 Chem. Soc. Rev. 46 1510

    Article  Google Scholar 

  21. Ali E 2010 Nanostructured conductive polymers (Chichester, UK: John Wiley & Sons Ltd.) p 19

  22. Hari Singh N 2001 Handbook of advanced electronic and photonic materials and devices (London, UK: Academic Press) p 1

  23. Haines P J 1995 Thermal methods of analysis (London, UK: Springer Science)

  24. Shirsath N B, Gupta G R, Gite V V and Meshram J S 2017 Bull. Mater. Sci. 41 63

    Article  Google Scholar 

  25. Zulkhairi Z, Nurul F A H, Mubaraq H V S, Shafiqul Islam A K M, Uda H and Ahmad M N 2015 J. Nanomater. 2015 218204

    Google Scholar 

  26. Jiahua Z, Suying W, Lei Z, Yuanbing M, Jongeun R, Neel H et al 2011 J. Mater. Chem. 21 3952

    Article  Google Scholar 

  27. Arora M and Gupta S K 2008 ICOPVS

  28. Saini P, Arora M, Arya S K and Tawale J S 2014 Indian J. Pure Appl. Phys. 52 175

    CAS  Google Scholar 

  29. Agrawalla R K, Paul S, Sahoo P K, Chakraborty A K and Mitra A K 2015 J. Appl. Polym. Sci. 132 41692

    Google Scholar 

  30. Agrawalla R K, Meriga V, Paul R, Chakraborty A K and Mitra A K 2016 EXPRESS Polym. Lett. 9 780

    Article  Google Scholar 

  31. Venkanna M, Sreeramulu V, Sivaprakash S, Caroline C and Dhanak V R 2015 J. Appl. Polym. Sci. 132 42766

    Google Scholar 

  32. Burns J A and Verall R E 1974 Thermochim. Acta. 9 277

    Article  CAS  Google Scholar 

  33. Dortmund Data Bank. http://www.ddbst.com/en/EED/PCP/HCP_C4577.php

  34. Preeti A T, Yadav S M and Gupta G R 2014 Polym. Bull. 71 1349

    Article  Google Scholar 

  35. Kumar D and Chandra R 2001 Indian J. Eng. Mater. Sci. 8 209

    CAS  Google Scholar 

  36. Jiaxing H and Richard B K 2004 J. Am. Chem. Soc. 126 851

    Article  Google Scholar 

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Acknowledgements

We gratefully thank Professor K J Patil, Ex. Professor, Shivaji University, Kolhapur for knowledge sharing and technical writing. The authors are also thankful to the management and Principal Dr K S Wani for the financial support of the project from Shram Sadhana Research Promotion Scheme No. COET/SSRPS/1626/019/13 dated 6 Sept, 2013 started in SSBTs COET Bambhori, Jalgaon (M.S.), India to increase the research activity in the institute. Also many thanks to the North Maharashtra University, Jalgaon and Shivaji University, Kolhapur for providing characterization facility.

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Authors and Affiliations

  1. SSTs College of Engineering and Technology, Bambhori, Jalgaon, 425001, India

    K S Patil, P H Zope & U T Patil

  2. School of Chemical Sciences, North Maharashtra University, Jalgaon, 425001, India

    P D Patil

  3. Swarnandhra College of Engineering and Technology, Narsapur, 534275, India

    R S Dubey

  4. Institute of Chemical Technology, Matunga, Mumbai, 400019, India

    G R Gupta

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  1. K S Patil
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Correspondence to G R Gupta.

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Patil, K.S., Zope, P.H., Patil, U.T. et al. Synthesis and thermophysical studies of polyanilines. Bull Mater Sci 42, 24 (2019). https://doi.org/10.1007/s12034-018-1705-0

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  • DOI: https://doi.org/10.1007/s12034-018-1705-0

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