Skip to main content
SpringerLink
Log in

Infrared Absorption Spectra of Some Na-Borosilicate Glasses Containing AgBr and Cu2O (Photochromic Glasses) in Addition to One of Transition Metal Oxide

  • Original Paper
  • Published:
Silicon Aims and scope Submit manuscript

Abstract

Infrared absorption spectroscopy measurements for a number of Na-borosilicate glasses containing AgBr and Cu2O were carried out in order to elucidate the structure of these glasses and the forms in which the transition metal ions exist in it. The raw materials used were of chemically pure grade and were finely pulverized. The temperature of the melting was 1,450 °C for 2 h and the samples were then annealed at 480 °C. The prepared glasses studied were then heat treated at 600 °C for 1 h and cooled inside the furnace. The absorption measurements in the Infrared region of the spectrum were recorded in range of (4,000–400) cm−1 using a Jacso FT-IR 300E Infrared spectrophotometer for all glasses studied. The experimental results obtained showed characteristic variations of the position and intensity of the absorption bands with the glass composition. The effect of the different transition metal oxides on the deformation of the groups present was investigated.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Barker AS, Sievers AI (1975) J Mod Phys 47:1

    Article  Google Scholar 

  2. Condrate AR Sr (1972) In: Pye LD, Stevens HJ, LaCourse WC (eds) Introduction to glass science. Plenum Publishing Corporation, New York, NY

    Google Scholar 

  3. Furukawa T, White WB (1980) 12th international congress on glass. Albuquerque, New Mexico

  4. Efimov AM (1999) J Non-Cryst Solids 235:95

    Article  Google Scholar 

  5. Kamitsos EI, Varsamis CPE, Vegeri A (2001) In: Proceeding of the international glass congress, Edinburgh, Scotland, Invited paper, I:234–246

  6. Kamitsos EI (2003) J Phys Chem Glasses 44:79

    CAS  Google Scholar 

  7. Exarhos GI (1986) In: Walrafen GE, Revesz AG (eds) Structure and bonding in non-crystalline solids. Plenum, New York, NY, p 203

    Google Scholar 

  8. Bamford CR (1977) Colour generation and control in glass, Glass science & technology. Elsevier Scientific Publishing Company, Amsterdam

    Google Scholar 

  9. Khalil MM (2007) J Appl Phys A 86:505

    Google Scholar 

  10. El-Badry KhM, Afifi MS, Moustaffa FA, El-Sayedkh A (1984) Egypt J Phys 15(1):143

    CAS  Google Scholar 

  11. El-Badry KhM, Afifi MS, Moustaffa FA, Khalil EM (1983) CGCRI Bull (Indian) 30:11

    CAS  Google Scholar 

  12. Sharaf NA, Condrate AR Sr, Ahmed AA (1991) J Mater Lett 11(3):4

    Article  Google Scholar 

  13. Rulmont A, Tarte P, Khorari S, Almou M (1996) Eur J Solid State Inorg Chem T 33:537

    CAS  Google Scholar 

  14. Khalil MI, ElBatal FH, Nada N, Desouky SA (2003) Indian J Pure Appl Phys 41:651

    CAS  Google Scholar 

  15. ElBatal FH, Nada N, Desouky SA, Khalil MI (2004) Indian J Pure Appl Phys 42:711

    CAS  Google Scholar 

  16. El-Egili (2003) J Phys B 325:340

    Article  CAS  Google Scholar 

  17. Raluca CL, Ioan A (2007) J Non-Cryst Solids 353:2020–2024

    Article  Google Scholar 

  18. Wan J, Cheng J, Lu P (2008) J Wuhan Univ Technol Mater Sci Ed 23(3)

  19. Crozier D, Douglas RW (1965) Study of sodium silicate glasses in the Infrared by means of thin films. Phys Chem Glasses 6(6):240–245

    CAS  Google Scholar 

  20. El-Batal HA, Khalil EMA, Hamdy TM (2009) Ceram Int 35:1195

    Article  CAS  Google Scholar 

  21. Azooz MA, AbouAiad THM, El-Batal FH, El-Tabii GT (2008) Indian J Pure Appl Phys 46:880

    CAS  Google Scholar 

  22. El-Batal FH, El Kheshen A (2008) Mater Chem Phys 110:352

    Article  CAS  Google Scholar 

  23. Tarte P (1962) Spectrochim Acta 18:467

    Article  CAS  Google Scholar 

  24. Condrate R (1972) Introduction to glass science. Plenum, New York, NY, p 101

    Google Scholar 

  25. El-Batal FH, Marzouk SY (2009) J Mater Sci 49:3061

    Article  Google Scholar 

  26. Ferraro JR, Manghnani MH (1972) Infrared absorption spectra of sodium silicate glasses at high pressures. J Four Appl Phys 43(11):4595–4599

    CAS  Google Scholar 

  27. Husung DR, Doremus HR (1990) Rensselaer polytechnic institute. Troy, New York 12180–3590 J Mater Res 5:10

  28. Efimov AM (2003) J Non-Cryst Solids 93:334

    Google Scholar 

  29. Scholze H (1966) Glass Ind 47(11):622

    Google Scholar 

  30. Dunken H, Doremus RH (1987) J Non-Cryst Solids 92:61

    Article  CAS  Google Scholar 

  31. Navara G (2005) J Non-Cryst Solids 351:1796

    Article  Google Scholar 

  32. Khalifa FA, El-Hadi ZA, Ghoneim NA, Moustaffa FA, Hassan NA (1987) CGCRI Bull 34:3

    Google Scholar 

  33. Navara G (2007) J Non-Cryst Solids 353:555

    Article  Google Scholar 

  34. Sallem AA, Kellner R, Grasserbaver M (1994) Glass Technol 35:135

    Google Scholar 

  35. Moustaffa FA, Ghoneim NA, El-Hadi ZA, Ezz El-Din FM, Hasan NA (1985) CGCRI Bull 32:1

    Google Scholar 

  36. Efimov AM (1996) J Non-Cryst Solids 203:1

    Article  CAS  Google Scholar 

  37. Kamitsos EI, Karakassided MA, Chryssikos GD (1986) Phys Chem Glasses 90:4528

    Article  CAS  Google Scholar 

  38. Krogh-Moe J (1962) J Phys Chem Glasses 3:95

    Google Scholar 

  39. Krogh-Moe J (1965) J Phys Chem Glasses 6:46

    CAS  Google Scholar 

  40. Kamitsos EI, Patsis AP, Karakasides MA, Chryssikos GD (1990) J Non-Cryst Solids 126:52

    Article  CAS  Google Scholar 

  41. El-Batal FH, Khalil MM, Nada N, Desouky SA (2003) Mater Chem Phys 82:375–387

    Article  CAS  Google Scholar 

  42. Frey K, Funck E (1972) ZTS Naturfarh 27:101

    CAS  Google Scholar 

  43. Kamitsos EI, Karakassides MA (1989) J Phys Chem Glasses 30:229

    CAS  Google Scholar 

  44. Julien M, Balkanski M (1989) J Mater Sci Eng B3:307

    CAS  Google Scholar 

  45. Borrelli NF, Su GJ (1968) Infrared spectra of glass network formers and their interpretations. Mater Res Bull 3(2):181–192

    Article  CAS  Google Scholar 

  46. Bell RJ, Bird ME, Dean P (1968) Proc Phys Soc Lond UK 1:299

    CAS  Google Scholar 

  47. Gaskell PH (1967) The vibrational spectra of silicates: Part I. Phys Chem Glasses 8(2):69–80

    CAS  Google Scholar 

  48. Bock J, Su GJ (1970) Interpretation of the infrared spectra of fused silica. J Four Am Ceram Soc 53(2):69–73

    Article  CAS  Google Scholar 

  49. Blackman M (1957) Proc Phys Soc 70:827

    Article  Google Scholar 

  50. Bienenstock A, Burley G (1963) Thermal expansion of silver iodide. J Four Phys Chem Solids 24:1271–1278

    Article  CAS  Google Scholar 

  51. Weyl WA (1959) Coloured glasses. Monograph, Reprinted by Dawson’s of Pall Mall, London

  52. Bates T (1962) In: Modern aspects of the vitreous state. Mackenzie JD (ed) Butterworths, London, 2:5

  53. Zachariazen WH (1932) J Am Chem Soc 54:3841

    Article  Google Scholar 

  54. Rao BV (1963) J Phys Chem Glasses 4:22

    Google Scholar 

  55. Rao BV (1964) J Am Ceram Soc 47:155

    Article  Google Scholar 

  56. Yafaew NR, YablokovYuV (1962) Sov Phys Solids State 4:6

    Google Scholar 

  57. Morinaga K, Yoshida H, Takebe H (1994) J Am Ceram Soc 77(12):3113

    Article  CAS  Google Scholar 

  58. Jen JS, Kalinowski MR (1979) J Non Cryst Solids

Download references

Author information

Authors and Affiliations

  1. Glass Research Department, National Research Center, Dokki-Cairo, Egypt

    Fatma Hatem ElBatal, Amira Mohamed Fayad & Fouad Abbass Moustafa

  2. Chemistry Department, Faculty of Science, Ain-Shams University, Cairo, Egypt

    Ebtisam Ahmed Saad

Authors
  1. Ebtisam Ahmed Saad
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Fatma Hatem ElBatal
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Amira Mohamed Fayad
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Fouad Abbass Moustafa
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Amira Mohamed Fayad.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Saad, E.A., ElBatal, F.H., Fayad, A.M. et al. Infrared Absorption Spectra of Some Na-Borosilicate Glasses Containing AgBr and Cu2O (Photochromic Glasses) in Addition to One of Transition Metal Oxide. Silicon 3, 85–95 (2011). https://doi.org/10.1007/s12633-011-9081-z

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s12633-011-9081-z

Keywords

Search

Navigation